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4-Bromo-2-methylpyridine

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4-Bromo-2-methylpyridine Basic information

Product Name:
4-Bromo-2-methylpyridine
Synonyms:
  • CHEMBRDG-BB 4014101
  • 2-METHYL-4-BROMOPYRIDINE
  • 4-BROMO-2-METHYLPYRIDINE
  • 4-BROMO-2-METHYL-PYRIDINE HYDROCHLORIDE
  • 4-BROMO-2-METHYL-PYRIDINIUM, CHLORIDE
  • 4-BROMO-2-PICOLINE
  • 4-BROMO-2-PICOLINE HCL
  • 4-BROMO-METHYL-PYRIDINE
CAS:
22282-99-1
MF:
C6H6BrN
MW:
172.02
EINECS:
624-896-3
Product Categories:
  • Building Blocks
  • C5 to C6
  • C6 to C7
  • Chemical Synthesis
  • Halogenated Heterocycles
  • Heterocyclic Building Blocks
  • Halides
  • Heterocycles
  • Pyridine Series
  • pharmacetical
  • Bromopyridines
  • Halopyridines
  • Aromatics
  • Boronic Acid
  • Pyridine
  • Pyridines, Pyrimidines, Purines and Pteredines
  • Heterocyclic Series
  • Pyridines
  • Organohalides
  • Aromatics Compounds
Mol File:
22282-99-1.mol
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4-Bromo-2-methylpyridine Chemical Properties

Boiling point:
76 °C / 14mmHg
Density 
1.450 g/mL at 25 °C
refractive index 
n 20/D 1.556
Flash point:
174 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
Dichloromethane
form 
Pale Yellow Liquid
pka
4.38±0.10(Predicted)
color 
Colorless to Light yellow to Light orange
Water Solubility 
Miscible with dichloromethane. Immiscible with water.
CAS DataBase Reference
22282-99-1(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xn,Xi
Risk Statements 
22-37/38-41-36/37/38-20/21/22
Safety Statements 
26-36/39-36
RIDADR 
NA 1993 / PGIII
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29333990

MSDS

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4-Bromo-2-methylpyridine Usage And Synthesis

Chemical Properties

Light yellow liquid

Uses

4-Bromo-2-methylpyridine is used as a starting material in the preparation of crown-ester-bipyridines and viologens through sodium or nickel reductive coupling, side chain oxidation and esterification. Further, it serves as an important raw material and intermediate in organic synthesis, pharmaceuticals, agrochemicals and in dyes.

Uses

4-Bromo-2-methylpyridine is a starting material used in a synthesis of crown-ester-bipyridines and viologens via sodium or nickel reductive coupling, side chain oxidation and esterification.

Uses

Used in the preparation of phenyloxadiazolyl pyridines as immunomodulating agents.

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