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Ruthenium carbonyl

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Ruthenium carbonyl Basic information

Product Name:
Ruthenium carbonyl
Synonyms:
  • dodecacarbonyltri-rutheniutriangulo
  • Ru3(CO)12
  • TrirutheniuM dodecacarbonyl 99%
  • Trirutheniumdodecarbonyl(DCR)
  • pentaoxonium
  • Ruthenium, dodecacarbonyltri-, triangulo
  • Ruthenium,dodecacarbonyltri-
  • DODECACARBONYLTRIRUTHENIUM
CAS:
15243-33-1
MF:
C12O12Ru3
MW:
639.33
EINECS:
239-287-4
Product Categories:
  • Ru
  • Classes of Metal Compounds
  • Ru (Ruthenium) Compounds
  • Transition Metal Compounds
  • metal carbonyl complexes
Mol File:
15243-33-1.mol
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Ruthenium carbonyl Chemical Properties

Melting point:
150 °C
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Sparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone.
form 
crystal
color 
orange
CAS DataBase Reference
15243-33-1(CAS DataBase Reference)
EPA Substance Registry System
Ruthenium, dodecacarbonyltri-, triangulo (15243-33-1)
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Safety Information

Hazard Codes 
F,Xn
Risk Statements 
11-20-2017/11/20
Safety Statements 
24/25
RIDADR 
1325
WGK Germany 
3
Hazard Note 
Flammable/Harmful
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
II
HS Code 
28439000

MSDS

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Ruthenium carbonyl Usage And Synthesis

Description

Triruthenium dodecacarbonyl is a metal carbonyl complex, classified as an inorganic compound. Its molecular formula is Ru3(CO)12, with a molecular weight of 639.33. It possesses D3h symmetry and a core composed of a Ru equilateral triangle. Each Ru atom is attached to two axial and two equatorial CO ligands. Unlike triiron dodecacarbonyl, this compound does not contain any bridge bonds. It is commonly employed as a precursor for various organoruthenium compounds.

Chemical Properties

The substance appears as orange plates or powder and is soluble in non-polar organic solvents.

Uses

Ruthenium carbonyl is a H-transfer catalyst. It is used in carbonylation catalysis of the allylic amination of unactivated olefins by nitroarenes, reductive carbonylation of mononitro aromatic compounds to carbamates, and as a catalyst for cycloaddition reactions. It is employed as a precursor for the synthesis of Ru nanoparticles. Catalyst used in the intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide, to produce alpha-pyrones. Catalyzes the coupling of silanes with thiols, alcohols and amines with high turnover number (TON) and high turnover frequency (TOF).

Reactions

  1. Catalyst for the conversion of enynes to catechol derivatives.
  2. Catalyst for the intermolecular [2+2+1] cycloaddition of ketones, CO and alkenes or alkynes.
  3. 3-Component couplings.
  4. Reaction of α,β-unsaturated imines with carbon monoxide and alkenes to form β,γ-unsaturated γ-butyroactams.
  5. Ester decarboxylation.
  6. Catalyst for hydroamination and C-H bond activation.
  7. Used in sp3 C-H bond arylation and carbonylation.
  8. Ru/halide catalytic system for C-C bond forming reaction between alkynes and unsaturated carbonyl compounds.
  9. Amination of α-hydroxy amides.

General Description

Atomic number of base material: 44 Ruthenium

Ruthenium carbonylSupplier

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