Basic information Safety Supplier Related

ISOBORNYL THIOCYANOACETATE

Basic information Safety Supplier Related

ISOBORNYL THIOCYANOACETATE Basic information

Product Name:
ISOBORNYL THIOCYANOACETATE
Synonyms:
  • isoborneol,thiocyanatoacetate
  • Isobornylester kyseliny thiokyanatooctove
  • isobornylesterkyselinythiokyanatooctove
  • isobornylthiocyanatoacetate,technical
  • Thanisol
  • thanite(herculespowder)
  • thiocyanato-,1,7,7-trimethylbicyclo(2,2,1)hept-2-ylester,exo-aceticaci
  • thiocyanato-,1,7,7-trimethylbicyclo(2.2.1)hept-2-ylester,exo-aceticaci
CAS:
115-31-1
MF:
C13H19NO2S
MW:
253.36
EINECS:
204-081-5
Mol File:
115-31-1.mol
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ISOBORNYL THIOCYANOACETATE Chemical Properties

Boiling point:
bp0.06 95°
Density 
d425 1.1465
refractive index 
nD25 1.512
Flash point:
82°C (180°F)
EPA Substance Registry System
Isobornyl thiocyanatoacetate (115-31-1)
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Safety Information

Hazard Codes 
Xn,N
Risk Statements 
22-50/53
Safety Statements 
24/25-60-61
Hazardous Substances Data
115-31-1(Hazardous Substances Data)
Toxicity
guinea pig,LD50,oral,551mg/kg (551mg/kg),Farm Chemicals Handbook. Vol. -, Pg. C300, 1991.
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ISOBORNYL THIOCYANOACETATE Usage And Synthesis

Chemical Properties

Yellow oily liquid; terpene-like odor. Very soluble in alcohol, benzene, chloroform, and ether; practically insoluble in water. Combustible.

Originator

Bornate,Wyeth,US,1946

Uses

Insecticide, especially in cattle sprays.

Definition

The technical grade contains 82% or more of isobornyl thiocyanoacetate, also other terpenes and derivatives.

Manufacturing Process

200 g of camphene and 150 g of chloroacetic acid were heated 16 hours at 125°C, cooled to room temperature and the resulting product washed with water. In this way, 177 g of isobornyl monochloroacetate, analyzing 12.8%, by weight, chlorine was recovered. 174 g of the isobornyl monochloroacetate was dissolved in 300 cc of ethyl alcohol, 100 g of potassium thiocyanate added to this solution and the mixture refluxed for a period of 8 hours. 276 g of a product was recovered, which analyzed as follows: chlorine, 0.2% by wt. and sulfur, 10.9% by wt. This analysis shows the product to be principally isobornyl thiocyanoacetate.

Therapeutic Function

Pediculicide

Hazard

Toxic by ingestion, strong irritant.

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