TRI-TERT-BUTYL BORATE
TRI-TERT-BUTYL BORATE Basic information
- Product Name:
- TRI-TERT-BUTYL BORATE
- Synonyms:
-
- Tri(1,1-dimethylethoxy)borane
- Tri-tert-butyl borate,98%
- Tri-tert-butyl borate,Boron tert-butoxide, Tri-tert-butoxyborane
- Tri-tert-butyl borate 98%
- Boric acid,tris(1,1-dimethylethyl) ester
- boricacidtri-tert-butylester
- BORON T-BUTOXIDE
- TRI-TERT-BUTYL BORATE
- CAS:
- 7397-43-5
- MF:
- C12H27BO3
- MW:
- 230.15
- Mol File:
- 7397-43-5.mol
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TRI-TERT-BUTYL BORATE Chemical Properties
- Melting point:
- 18-19 °C (lit.)
- Boiling point:
- 101 °C/74 mmHg (lit.)
- Density
- 0.811 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.389(lit.)
- Flash point:
- 85 °F
- storage temp.
- Flammables area
- form
- Liquid
- Specific Gravity
- 0.811
- color
- Colorless
- Hydrolytic Sensitivity
- 7: reacts slowly with moisture/water
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MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
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TRI-TERT-BUTYL BORATE Usage And Synthesis
Chemical Properties
CLEAR COLOURLESS LIQUID
Uses
Tri-tert-butyl borate can be used as:
- An additive in the synthesis of chiral α-hydroxy esters by reacting dimethylzinc with α-ketoesters using (?)-2-exo-morpholinoisobornane-10-thiol.
- A starting material in the synthesis of boronate of (+)-pinane-2,3-diol.
Synthesis Reference(s)
The Journal of Organic Chemistry, 43, p. 2731, 1978 DOI: 10.1021/jo00407a051
General Description
Tri-tert-butyl borate is an organoborate commonly used to prepare other borate esters. It is also used as a substrate in Rh-catalyzed carbonylation reactions.
TRI-TERT-BUTYL BORATESupplier
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