4-THIOANISOLEMAGNESIUM BROMIDE Chemical Properties

Boiling point:

65 °C

Density 

0.965 g/mL at 25 °C

Flash point:

<1 °F

storage temp. 

2-8°C

form 

Solution

color 

Clear yellow to brown

Safety Information

Hazard Codes 

F,C,F+

Risk Statements 

11-14-19-34-12-37-40

Safety Statements 

16-26-36/37/39-45

RIDADR 

UN 2924 3/PG 2

WGK Germany 

1

HS Code 

29309090

MSDS

• Language:English Provider:SigmaAldrich

4-THIOANISOLEMAGNESIUM BROMIDE Usage And Synthesis

Chemical Properties

Tan liquid

Uses

4-Thioanisolemagnesium bromide can be used to prepare:

• 3,3-Ethylenedioxy-5a-hydroxy-11b-[4-(thiomethoxy)phenyl]-estr-9-en-17-one, a key intermediate for the synthesis of mifepristone analogs.
• (1S)-1,4-Anhydro-2,3,5,6-tetra-O-benzyl-1-C-[4-chloro-3-(4-methylthiobenzyl)-phenyl]-D-glucitol, a key intermediate for the synthesis of aryl?D-glucofuranosides as potent hSGLT2 and hSGLT1 inhibitors.

reaction suitability

reaction type: Grignard Reaction

4-THIOANISOLEMAGNESIUM BROMIDE(18620-04-7)Related Product Information

• 4-METHYLBENZYLMAGNESIUM CHLORIDE
• 4-Fluorophenylmagnesium chloride
• 4-TERT-BUTYLPHENYLMAGNESIUM BROMIDE
• 2-METHOXYPHENYLMAGNESIUM BROMIDE
• DIMETHYLALUMINUM CHLORIDE
• Chloromethane
• 4-ETHYLPHENYLMAGNESIUM BROMIDE
• (TRIMETHYLSILYL)DIAZOMETHANE
• Tricyclohexyl phosphine
• 3-(DIMETHYLAMINO)PROPYL CHLORIDE HYDROCHLORIDE
• (TRIMETHYLSILYL)METHYLLITHIUM
• P-TOLYLMAGNESIUM CHLORIDE
• 4-Methoxyphenylmagnesium bromide
• PHENYLMAGNESIUM BROMIDE
• Methylmagnesium Bromide
• 4-(ETHYLTHIO)PHENYLMAGNESIUM BROMIDE
• 4-THIOANISOLEMAGNESIUM BROMIDE
• 2-THIOANISOLEMAGNESIUM BROMIDE