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4-THIOANISOLEMAGNESIUM BROMIDE

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4-THIOANISOLEMAGNESIUM BROMIDE Basic information

Product Name:
4-THIOANISOLEMAGNESIUM BROMIDE
Synonyms:
  • 4-THIOANISOLEMAGNESIUM BROMIDE, 0.5M SOLUT TION IN TETRAHYDROFURAN
  • 4-THIOANISOLEMAGNESIUM BROMIDE
  • 4-thioanisolemagnesium bromide solution
  • 4-Thioanisolemagnesium bromide, 0.5M solution in THF, AcroSeal
  • 4-Thioanisolemagnesium bromide,0.5M solutionin THF
  • 4-ThioanisoleMagnesiuM broMide, 0.5 M solution in THF, J&KSeal
  • 4-(Methylthio)phenylmagnesium bromide
  • magnesium,methylsulfanylbenzene,bromide
CAS:
18620-04-7
MF:
C7H7BrMgS
MW:
227.4
Product Categories:
  • Chemical Synthesis
  • Grignard Reagents
  • Aryl
  • Grignard Reagents
  • Organometallic Reagents
  • Organometallic Reagents
Mol File:
18620-04-7.mol
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4-THIOANISOLEMAGNESIUM BROMIDE Chemical Properties

Boiling point:
65 °C
Density 
0.965 g/mL at 25 °C
Flash point:
<1 °F
storage temp. 
2-8°C
form 
Solution
color 
Clear yellow to brown
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Safety Information

Hazard Codes 
F,C,F+
Risk Statements 
11-14-19-34-12-37-40
Safety Statements 
16-26-36/37/39-45
RIDADR 
UN 2924 3/PG 2
WGK Germany 
1
HS Code 
29309090

MSDS

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4-THIOANISOLEMAGNESIUM BROMIDE Usage And Synthesis

Chemical Properties

Tan liquid

Uses

4-Thioanisolemagnesium bromide can be used to prepare:

  • 3,3-Ethylenedioxy-5a-hydroxy-11b-[4-(thiomethoxy)phenyl]-estr-9-en-17-one, a key intermediate for the synthesis of mifepristone analogs.
  • (1S)-1,4-Anhydro-2,3,5,6-tetra-O-benzyl-1-C-[4-chloro-3-(4-methylthiobenzyl)-phenyl]-D-glucitol, a key intermediate for the synthesis of aryl?D-glucofuranosides as potent hSGLT2 and hSGLT1 inhibitors.

4-THIOANISOLEMAGNESIUM BROMIDESupplier

J & K SCIENTIFIC LTD.
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