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2-(Tributylstannyl)furan

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2-(Tributylstannyl)furan Basic information

Product Name:
2-(Tributylstannyl)furan
Synonyms:
  • 2-(TRIBUTYLSTANNYL)FURAN
  • TRIBUTYL(2-FURYL)TIN
  • TRI-N-BUTYL(2-FURYL)TIN
  • Tributyl-(2-furyl)stannane
  • 2-(Tributylstannyl)furane
  • 2-(TRIBUTYLSTANNYL)FURAN 97%
  • (2-Furyl)tributylstannane
  • tributyl-2-furanylStannane
CAS:
118486-94-5
MF:
C16H30OSn
MW:
357.12
Product Categories:
  • Stannanes
  • Organometallic Reagents
  • Classes of Metal Compounds
  • Sn (Tin) Compounds
  • Organotin
  • Organotins
  • Typical Metal Compounds
Mol File:
118486-94-5.mol
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2-(Tributylstannyl)furan Chemical Properties

Boiling point:
90 °C/0.1 mmHg (lit.)
Density 
1.134 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.494(lit.)
Flash point:
>230 °F
storage temp. 
Inert atmosphere,Room Temperature
form 
liquid
Specific Gravity
1.134
Appearance
Colorless to light yellow Liquid
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
InChI
1S/C4H3O.3C4H9.Sn/c1-2-4-5-3-1;3*1-3-4-2;/h1-3H;3*1,3-4H2,2H3;
InChIKey
SANWDQJIWZEKOD-UHFFFAOYSA-N
SMILES
CCCC[Sn](CCCC)(CCCC)c1ccco1
CAS DataBase Reference
118486-94-5(CAS DataBase Reference)
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Safety Information

Hazard Codes 
T,N,Xi
Risk Statements 
21-25-36/38-48/23/25-50/53-36/37/38
Safety Statements 
35-36/37/39-45-60-61-28-26
RIDADR 
UN 2788 6.1/PG 3
WGK Germany 
3
10
TSCA 
No
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29321900
Storage Class
6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications
Acute Tox. 3 Oral
Acute Tox. 4 Dermal
Aquatic Acute 1
Aquatic Chronic 1
Eye Irrit. 2
Repr. 1B
Skin Irrit. 2
STOT RE 1

MSDS

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2-(Tributylstannyl)furan Usage And Synthesis

Uses

It is an agrochemical, organic and pharmaceutical intermediates.

Synthesis

Weigh tributyltin chloride, in 30mL furan reflux stirring 10h. Filtering, filtrate concentrated to the appropriate volume under reduced pressure, add 3mL ~ 5mL petroleum ether, low-temperature standing, to be completely precipitated after filtration, the crude product is recrystallized with dichloromethane - petroleum ether. The crude product was recrystallized by dichloromethane-petroleum ether. After removing the solvent and purified by repeated washing with petroleum ether, colorless viscous liquid 2-(tributylstannyl)furan was obtained.

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