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(-)-Diisopinocampheyl chloroborane

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(-)-Diisopinocampheyl chloroborane Basic information

Product Name:
(-)-Diisopinocampheyl chloroborane
Synonyms:
  • (-)-b-chlorodiisopinocampherylborane
  • (-)-diisopinocampheylchloroborane,(-)-dpc,inheptanes
  • (-)-diisopinocampheylchloroborane,(-)-dpc,inhexanes
  • (-)-BETA-CHLORODIISOPINOCAMPHEYLBORANE
  • (-)-B-DIISOPINOCAMPHEYL-CHLOROBORANE
  • (-)-B-CHLORODIISOPINOCAMPHENYLBORANE
  • (-)-B-CHLORODIISOPINOCAMPHEYLBORANE
  • (-)-DIP-CHLORIDE
CAS:
85116-37-6
MF:
C20H34BCl
MW:
320.75
EINECS:
237-458-8
Product Categories:
  • Asymmetric Synthesis
  • Chiral Catalysts, Ligands, and Reagents
  • Asymmetric Synthesis
  • B (Classes of Boron Compounds)
  • Boranes
  • Reduction
  • Synthetic Organic Chemistry
Mol File:
85116-37-6.mol
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(-)-Diisopinocampheyl chloroborane Chemical Properties

Melting point:
52-56 °C(lit.)
Boiling point:
66-69°C
Density 
0.954 g/mL at 25 °C
refractive index 
-51 ° (C=neat)
Flash point:
82 °F
storage temp. 
Inert atmosphere,2-8°C
form 
clear liquid
color 
Colorless to Almost colorless
BRN 
5937756
CAS DataBase Reference
85116-37-6(CAS DataBase Reference)
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Safety Information

Hazard Codes 
C,F+,N,F
Risk Statements 
34-20/22-12-10-67-65-62-51/53-48/20-50/53-11-37
Safety Statements 
9-16-29-33-36/37-61-62-45-36/37/39-26
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
F 
10-21
HazardClass 
3/8
PackingGroup 
II
HS Code 
29319090

MSDS

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(-)-Diisopinocampheyl chloroborane Usage And Synthesis

Chemical Properties

solutio

Uses

Both (+)- and (-)-DIP-chloride are used for asymmetric reduction of prochiral ketones and for the preparation of β-amino alcohols.

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