Tri-tert-butylphosphine
Tri-tert-butylphosphine Basic information
- Product Name:
- Tri-tert-butylphosphine
- Synonyms:
-
- Tri-t-butylphosphine, 99% (10 wt% in hexanes) (Sure/Seal bottle)
- Tri-t-butylphosphosphin
- Tri-tert-butyL
- Phosphine, tris(1,1-dimethylethyl)-
- TRI-TERT-BUTYL-PHOSPHANE
- TRI-TERT-BUTYLPHOSPHINE
- TRI-T-BUTYLPHOSPHINE
- tris(1,1-dimethylethyl)phosphine
- CAS:
- 13716-12-6
- MF:
- C12H27P
- MW:
- 202.32
- EINECS:
- 237-266-4
- Product Categories:
-
- Phosphines
- Ligand
- API intermediates
- Mitsunobu Reaction
- Phosphine Ligands
- Phosphines (Mitsunobu Reaction)
- pharmacetical
- Synthetic Organic Chemistry
- Basic Phosphine LigandsCatalysis and Inorganic Chemistry
- Catalysis and Inorganic Chemistry
- Cross-Coupling
- Phosphine Ligands
- Phosphorus Compounds
- organophosphorus ligand
- organophosphine ligand
- OLED materials,pharm chemical,electronic
- Achiral Phosphine
- Alkyl Phosphine
- Mol File:
- 13716-12-6.mol
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Tri-tert-butylphosphine Chemical Properties
- Melting point:
- 30-35 °C(lit.)
- Boiling point:
- 102-103 °C13 mm Hg(lit.)
- Density
- 0.861 g/mL at 25 °C
- Flash point:
- 1 °F
- storage temp.
- Flammables area
- form
- solid
- Specific Gravity
- 0.68
- Water Solubility
- insoluble
- Sensitive
- Air & Moisture Sensitive
- Hydrolytic Sensitivity
- 9: reacts extremely rapidly with atmospheric moisture - may be pyrophoric - glove box or sealed system required
- BRN
- 1738613
- InChIKey
- BWHDROKFUHTORW-UHFFFAOYSA-N
- CAS DataBase Reference
- 13716-12-6(CAS DataBase Reference)
- NIST Chemistry Reference
- Tri-tert-butylphosphine(13716-12-6)
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Safety Information
- Hazard Codes
- F,C
- Risk Statements
- 17-34-67-65-63-48/20-11
- Safety Statements
- 26-45-62-36/37/39-25-43-27-16
- RIDADR
- UN 2846 4.2/PG 1
- WGK Germany
- 3
- F
- 10-19-23
- HazardClass
- 4.2
- PackingGroup
- I
- HS Code
- 29319090
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
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Tri-tert-butylphosphine Usage And Synthesis
Reaction
Useful as a ligand in a variety of palladium-catalyzed C-N, C-O and C-C bond-forming reactions under mild conditions.
Chemical Properties
Colorless to light yellow liqui
Uses
Tri-tert-butylphosphine is used primarily in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.
Uses
Valuable ligand for several coupling reactions. This product is offered as the THF solution for more convenient handling.
Tri-tert-butylphosphine Preparation Products And Raw materials
Raw materials
Ethyl acetateDiethyl etherTetrahydrofuranDichloromethaneHexaneMagnesiumPhosphorus trichlorideCuprous chlorideTERT-BUTYLLITHIUM2-Chloro-2-methylpropaneLithium bromide
Preparation Products
Tri-tert-butylphosphineSupplier
Meryer (Shanghai) Chemical Technology Co., Ltd. Gold
- Tel
- 4006608290; 18621169109
- market03@meryer.com
Puyang Huicheng Electronic Material Co. Ltd. Gold
- Tel
- 0393-0393-8910800 15238090375
- info@huichengchem.com
Nanjin Cynthia chemicals Technology Co.,Ltd Gold
- Tel
- 0550-5618439 15951861180
- cynthiachem@163.com
Xinxiang Runyu Material Co., Ltd. Gold
- Tel
- 166-166-37336996 15690792173
- chenxi.song@runvmat.com
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
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Tri-tert-butylphosphine(13716-12-6)Related Product Information
- BIS-Tris
- tert-Butanol
- Tetrabutylammonium bromide
- BUFFER SOLUTION PH = 6,00 (20 °C) (POTASSIUM DIHYDROGEN PHOSPHATE/SODIUM HYDROXIDE)
- tert-Butyl peroxyacetate
- Tricine
- Tris(hydroxymethyl)aminomethane
- 1,3,5-Tri-tert-butylbenzene
- Tributylphosphine
- tert-Butyl acetate
- T-BUTYLPHOSPHINE
- TRI-TERT-BUTYLPHOSPHONIUM TETRAPHENYLBORATE
- Tri-tert-butylphosphine tetrafluoroborate
- TRI-N-OCTYLPHOSPHINE
- TRI-TERT-BUTYL 1 4 7 10-TETRAAZACYCLODOD
- TRI-T-BUTYL 1 4 7 10-TETRAAZACYCLODODECA
- Triphenylene
- Hexafluoroacetone trihydrate