(+)-Diisopropyl L-tartrate CAS#: 2217-15-4

(+)-Diisopropyl L-tartrate Basic information

Product Name:

(+)-Diisopropyl L-tartrate

Synonyms:

2,3-dihydroxy-(R-(R*,R*))-butanedioicacid,bis(1-methylethyl)ester
2,3-dihydroxy-R-R*,R*-butanedioicacid,bis1-methylethylester
2,3-dihydroxy-succinicaciddiisopropylester
Lg-tartaricaciddiisopropylester
Lg-threaricaciddiisopropylester
(2R,3R)-(+)-diisopropyltartrate
(R,R)-2,3-dihydroxy-succinicaciddiisopropylester
L(+)-DIISOPROPYL TARTRATE

CAS:

2217-15-4

MF:

C10H18O6

MW:

234.25

EINECS:

218-709-0

Product Categories:

Asymmetric Synthesis
Chiral Building Blocks
Esters (Chiral)
Synthetic Organic Chemistry
CHIRAL CHEMICALS
Hydroxy Acids & Deriv.
Chiral Compound
chiral
API intermediates

Mol File:

2217-15-4.mol

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(+)-Diisopropyl L-tartrate Chemical Properties

alpha: 17.25 º (neat)
Boiling point:: 152 °C/12 mmHg (lit.)
Density: 1.114 g/mL at 25 °C (lit.)
refractive index: n20/D 1.439(lit.)
Flash point:: 229 °F
storage temp.: Refrigerator
solubility: Chloroform (Slightly), Methanol (Slightly)
form: Viscous Liquid
pka: 11.70±0.20(Predicted)
Specific Gravity: 1.121.114
color: Clear colorless
optical activity: [α]24/D +17°, neat
Sensitive: Hygroscopic
BRN: 1727863
InChI: 1S/C10H18O6/c1-5(2)15-9(13)7(11)8(12)10(14)16-6(3)4/h5-8,11-12H,1-4H3/t7-,8-/m1/s1
InChIKey: XEBCWEDRGPSHQH-HTQZYQBOSA-N
SMILES: CC(C)OC(=O)[C@H](O)[C@@H](O)C(=O)OC(C)C
CAS DataBase Reference: 2217-15-4(CAS DataBase Reference)
NIST Chemistry Reference: (+)-Diisopropyl tartrate(2217-15-4)

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Safety Information

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 24/25-36-26
WGK Germany: 3
RTECS: WW8100000
HS Code: 29181300
Storage Class: 10 - Combustible liquids
Toxicity: mouse,LD50,oral,6300uL/kg (6.3mL/kg),Journal of Pharmacology and Experimental Therapeutics. Vol. 93, Pg. 26, 1948.

MSDS

Language:English Provider:(+)-Diisopropyl L-tartrate
Language:English Provider:SigmaAldrich
Language:English Provider:ACROS
Language:English Provider:ALFA

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(+)-Diisopropyl L-tartrate Usage And Synthesis

Chemical Properties

Colorless to light yellow liqui

Uses

(+)-Diisopropyl L-Tartrate is a reagent for kinetic resolution of racemic allylic alcohols and α-furfuryl amides by enantioselective epoxidation.

Uses

Both D- and L-forms are reagents for kinetic resolution of racemic allylic alcohols and α-furfuryl amides by enantioselective epoxidation.

(+)-Diisopropyl L-tartrateSupplier

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