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ChemicalBook >  Product Catalog >  Chemical Reagents >  Organic reagents >  Phosphine ligand >  (R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-CF3-PH2)P

(R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-CF3-PH2)P

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(R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-CF3-PH2)P Basic information

Product Name:
(R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-CF3-PH2)P
Synonyms:
  • (R)-1-{(R)-2-[2-(Diphenylphosphino)phenyl]-ferrocenyl}ethylbis[3,5-bis-(trifluor
  • (R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethylbis(di-3,5-trifluoromethylphenyl)phosphine,min.97%
  • (r)-1-{(r)-2-[2-(diphenylphosphino)phenyl]-ferrocenyl}ethylbis[3,5-bis-(trifluoromethyl)phenyl]phosphine
  • (r,r)-1-{1-[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]ethyl}-2-[2-(diphenylphosphino)phenyl]ferrocene (acc to cas)
  • (R)-(-)-1-[(R)-2-(2'DIPHENYLPHOSPHINOPHENYL)FERROCANYL]ETHYLDI(BIS-3,5-TRIFLUOROMETHYLPHENYL)PHOSPHINE
  • (R)-1-[(R)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-FERROCENYL]ETHYLBIS[3,5-BIS-(TRIFLUOROMETHYL)PHENYL]PHOSPHINE
  • (R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-CF3-PH2)P
  • (R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-TRIFLUOROMETHYLPHENYL)PHOSPHINE
CAS:
387868-06-6
MF:
C46H32F12FeP210*
MW:
930.52
Product Categories:
  • Walphos Series
  • Chiral Phosphine
  • Ferrocene Series
Mol File:
387868-06-6.mol
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Safety Information

Risk Statements 
36/37/38
Safety Statements 
24/25
WGK Germany 
3
HS Code 
29319090

MSDS

  • Language:English Provider:ACROS
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(R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-CF3-PH2)P Usage And Synthesis

Chemical Properties

Orange powder

Uses

Walphos SL-W001-1, in the presence of a ruthenium catalyst may be used as a ligand in the following processes:

  • Asymmetric hydrogenation of IPCA-D, a cinnamic acid derivative.
  • Addition of 3,5-difluorophenylketimine to 4-methoxyphenylboronic acid to form the corresponding tertiary substituted cyclic sulfamate derivative with high enantioselctivity.2

General Description

The product is an air-stable and non-hygroscopic Solvias chiral phosphine ligand.

(R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-CF3-PH2)PSupplier

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