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Ammonium ferric sulfate dodecahydrate

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Ammonium ferric sulfate dodecahydrate Basic information

Product Name:
Ammonium ferric sulfate dodecahydrate
Synonyms:
  • Ironammoniumsulfate
  • ironammoniumsulfatedodecahydrate
  • Sulfuricacid,ammoniumiron(3+)salt(2:1:1),dodecahydrate
  • ALUM IRON
  • AMMONIUM IRON(+3)SULFATE 12-WATER
  • AMMONIUM IRON(III) SULFATE-12-HYDRATE
  • AMMONIUM IRON(III) SULFATE 12-WATER
  • AMMONIUM IRON(III)SULFATE-12- HYDRATE R. G., REAG. ACS,
CAS:
7783-83-7
MF:
FeH7NO5S
MW:
188.96
EINECS:
616-517-5
Mol File:
7783-83-7.mol
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Ammonium ferric sulfate dodecahydrate Chemical Properties

Melting point:
39-41 °C(lit.)
Boiling point:
230 °C
Density 
1.71
storage temp. 
Store below +15°C.
solubility 
H2O: 1 m at 20 °C, complete, yellow-brown to red brown
form 
Solid
Specific Gravity
1.71
color 
slightly violet
PH
1.8 (100g/l, H2O, 20℃)
Odor
Odorless
PH Range
1
Water Solubility 
1240 g/L (25 ºC)
Merck 
14,521
Exposure limits
ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3
LogP
-1.031 (est)
CAS DataBase Reference
7783-83-7(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/38-36/37/38
Safety Statements 
26-36/37-24/25-36
WGK Germany 
3
RTECS 
WS5900000
3
TSCA 
Yes
PackingGroup 
III
HS Code 
28333000

MSDS

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Ammonium ferric sulfate dodecahydrate Usage And Synthesis

Chemical Properties

slightly grey-purple adhering crystals or powder

Uses

Medicine, analytical chemistry, textile dyeing (mordant).

Uses

Ammonium ferric sulfate dodecahydrate may be used as a catalyst to synthesize:

  • Isoamyl acetate from acetic acid and isoamyl alcohol.
  • 2-Amino-5-(5-nitro-2-thienyl)-1,3,4-thiadiazole from 5-nitrothiophene-2-carboxaldehyde thiosemicarbazone via oxidative cyclization.

Definition

Ferric alum: One of the alums,K2SO4.Fe2(SO4)3.24H2O, in which thealuminium ion Al3+ is replaced bythe iron(III) (ferric) ion Fe3+.

Purification Methods

Crystallise it from aqueous ethanol.

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