1,1'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE Chemical Properties

Melting point:

134-136°C

storage temp. 

Inert atmosphere,Room Temperature

form 

Powder

color 

orange

InChI

InChI=1S/2C17H22P.Fe/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h2*15-16H,1-6,9-12H2;/q2*-1;+2

InChIKey

OYQDKNYBVNMMJN-UHFFFAOYSA-N

SMILES

P(C1CCCCC1)(C1CCCCC1)[C-]12C3=C4C5=C1[Fe+2]16782345C2C1=C6[C-]7(P(C1CCCCC1)C1CCCCC1)C8=2

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

22-24-26-36/37

WGK Germany 

3

TSCA 

No

HS Code 

2931499090

1,1'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE Usage And Synthesis

Reaction

1. Ligand for palladium-catalyzed synthesis of oxindoles by amide ɑ-arylation.
2. Ligand for palladium-catalyzed alkoxycarbonylation of aryl chlorides.
3. Ligand for ruthenium-catalyzed alcohol-allene C-C coupling reaction via hydrohydroxyalkylation of 1,1-disubstituted allenes employing alcohols.
4. Ligand for nickel-catalyzed cross-coupling reaction of arylboronic acids with aryl carbonates.
5. Ligand for palladium-catalyzed regiodivergent hydroesterification of aryl olefins with phenyl formate to form linear structured phenyl arylpropanoates.
6. Ligand for palladium-catalyzed direct borylation of benzyl alcohol and its analogues in the absence of bases.

1,1'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE(146960-90-9)Related Product Information

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