4-tert-Butylcyclohexanol
Synthesis- Product Name
- 4-tert-Butylcyclohexanol
- CAS No.
- 98-52-2
- Chemical Name
- 4-tert-Butylcyclohexanol
- Synonyms
- PATCHONE;Cyclohexanol, 4-(1,1-dimethylethyl)-;4-T-BUTYLCYCLOHEXANOL;Padaryl;usafdo-20;USAF do-20;PTB-Cyclohexanol;patchouli hexanol;4-tert-Butylcyclohex;P-T-BUTYLCYCLOHEXANOL
- CBNumber
- CB0105660
- Molecular Formula
- C10H20O
- Formula Weight
- 156.27
- MOL File
- 98-52-2.mol
4-tert-Butylcyclohexanol Property
- Melting point:
- 62-70 °C(lit.)
- Boiling point:
- 110-115 °C15 mm Hg(lit.)
- Density
- 2.591
- vapor pressure
- 6-201.38Pa at 25-65℃
- refractive index
- 1.447
- Flash point:
- 221 °F
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- soluble in Methanol
- form
- Powder or Granules
- pka
- 15.32±0.40(Predicted)
- color
- White
- Odor
- at 100.00 %. woody musty patchouli camphor mint leather
- Odor Type
- woody
- Water Solubility
- <1 g/L (20 ºC)
- BRN
- 1902277
- InChIKey
- CCOQPGVQAWPUPE-UHFFFAOYSA-N
- LogP
- 3.23 at 20℃
- CAS DataBase Reference
- 98-52-2(CAS DataBase Reference)
- NIST Chemistry Reference
- Cyclohexanol, 4-(1,1-dimethylethyl)-(98-52-2)
- EPA Substance Registry System
- Cyclohexanol, 4-(1,1-dimethylethyl)- (98-52-2)
Safety
- Risk Statements
- 23/25-33-50/53
- Safety Statements
- 24/25-61-60-45-28-20/21
- RIDADR
- 3256
- WGK Germany
- 1
- RTECS
- GV8750000
- HS Code
- 29061900
- Toxicity
- The acute oral LD50 in rats was reported as 4-2 g/kg (3-62-4-87 g/kg)(Denine, 1973). The acute dermal LD50 in rabbits was reported as > 5 g/kg (Denine, 1973).
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- B92001
- Product name
- 4-tert-Butylcyclohexanol, mixture of cis and trans
- Purity
- 98%
- Packaging
- 100g
- Price
- $83
- Updated
- 2023/01/07
- Product number
- B0383
- Product name
- 4-tert-Butylcyclohexanol (cis- and trans- mixture)
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $34
- Updated
- 2024/03/01
- Product number
- B0383
- Product name
- 4-tert-Butylcyclohexanol (cis- and trans- mixture)
- Purity
- >98.0%(GC)
- Packaging
- 500g
- Price
- $142
- Updated
- 2024/03/01
- Product number
- D118005
- Product name
- 4-(1,1-Dimethylethyl)cyclohexanol
- Packaging
- 50g
- Price
- $55
- Updated
- 2021/12/16
- Product number
- FB14746
- Product name
- 4-tert-Butylcyclohexanol, mixture of?cis?and?trans
- Packaging
- 100g
- Price
- $60
- Updated
- 2021/12/16
4-tert-Butylcyclohexanol Chemical Properties,Usage,Production
Synthesis
Phenol and isobutylene carry out tert-butylation reaction in the presence of aluminum trichloride, and catalytic hydrogenation with Rays Nickel W7, two kinds of geometric structures can be obtained, in which the trans structure accounts for more than 70%.
Chemical Properties
white powder or granules
Occurrence
Has apparently not been reported to occur in nature.
Uses
4-tert-Butylcyclohexanol (mixture of cis and trans) can be used as a reactant to synthesize tris(4,4′-di-tert-butyl-2,2′-bipyridine)(trans-4-tert-butylcyclohexanolato)deca-μ-oxido-heptaoxidoheptavanadium oxide cluster complex by reacting with [V8O20(C18H24N2)4]. It can also be used as a reactant in competitive Oppenauer oxidation experiments in the presence of zeolite BEA as a stereoselective catalyst. Only cis-isomer is selectively converted to the corresponding ketone, whereas trans-isomer remains unchanged.
Preparation
From 4-terf-butylphenol by hydrogenation(Arctander, 1969).
Synthesis Reference(s)
The Journal of Organic Chemistry, 45, p. 2724, 1980 DOI: 10.1021/jo01301a040
Synthesis, p. 171, 1977 DOI: 10.1055/s-1977-24307
4-tert-Butylcyclohexanol Preparation Products And Raw materials
Raw materials
Preparation Products
4-tert-Butylcyclohexanol Suppliers
- Tel
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- Fax
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- indukern@indukern.es
- Country
- Spain
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- 297
- Advantage
- 58
- Tel
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- nfo@ventos.com
- Country
- Spain
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View Lastest Price from 4-tert-Butylcyclohexanol manufacturers
- Product
- 4-tert-Butylcyclohexanol 98-52-2
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99.%
- Supply Ability
- 10 ton
- Release date
- 2024-08-21
- Product
- 4-t-BUTYLCYCLOHEXANOL 98-52-2
- Price
- US $5.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 10000
- Release date
- 2024-08-08
- Product
- 4-tert-Butylcyclohexanol 98-52-2
- Price
- US $10.00/PCS
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100 mt
- Release date
- 2021-04-07