ChemicalBook > CAS DataBase List > 3-Chlorosulfonyl-propionic acid methyl ester

3-Chlorosulfonyl-propionic acid methyl ester

Product Name
3-Chlorosulfonyl-propionic acid methyl ester
CAS No.
15441-07-3
Chemical Name
3-Chlorosulfonyl-propionic acid methyl ester
Synonyms
METHYL 3-​(CHLOROSULFONYL)​Methyl 3-chlorosulfonylpropionate;3-Methoxy-3-oxopropanesulfonyl chloride;3-Chlorosulfonyl-propionic acid methyl ester;Propanoic acid, 3-(chlorosulfonyl)-, methyl ester
CBNumber
CB01113220
Molecular Formula
C4H7ClO4S
Formula Weight
186.61
MOL File
15441-07-3.mol
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3-Chlorosulfonyl-propionic acid methyl ester Property

Boiling point:
110-113 °C(Press: 4 Torr)
Density 
1.430±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
Appearance
Colorless to light yellow Liquid
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Safety

RIDADR 
UN3265
HazardClass 
8
HS Code 
2915907098
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

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N-Bromosuccinimide Price

Matrix Scientific
Product number
098821
Product name
Methyl 3-(chlorosulfonyl)propanoate
Purity
95+%
Packaging
250mg
Price
$152
Updated
2021/12/16
AK Scientific
Product number
7749AA
Product name
Methyl3-(chlorosulfonyl)propanoate
Packaging
5g
Price
$208
Updated
2021/12/16
AK Scientific
Product number
7749AA
Product name
Methyl3-(chlorosulfonyl)propanoate
Packaging
10g
Price
$303
Updated
2021/12/16
Matrix Scientific
Product number
098821
Product name
Methyl 3-(chlorosulfonyl)propanoate
Purity
95+%
Packaging
1g
Price
$336
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0000478
Product name
3-CHLOROSULFONYL-PROPIONIC ACID METHYL ESTER
Purity
95.00%
Packaging
1G
Price
$527
Updated
2021/12/16
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3-Chlorosulfonyl-propionic acid methyl ester Chemical Properties,Usage,Production

Synthesis

2935-90-2

15441-07-3

Methyl 3-mercaptopropionate (6.5 g, 54 mmol) was dissolved in dichloromethane under cooling conditions in an ice bath, and chlorine was slowly passed through until the reaction solution took on a light green color. After continuing to pass the chlorine gas for 0.5 h, the reaction was purged with nitrogen to remove unreacted chlorine gas. The reaction mixture was extracted with dichloromethane, the organic phases were combined and washed with saturated brine, dried over anhydrous sodium sulfate, filtered and concentrated under reduced pressure to give methyl 3-(chlorosulfonyl)propionate (9.7 g, 96% yield).

References

[1] Patent: TW2017/36341, 2017, A. Location in patent: Paragraph 0173-0175
[2] Patent: US2017/183318, 2017, A1. Location in patent: Paragraph 0201; 0202
[3] Patent: US2012/71466, 2012, A1. Location in patent: Page/Page column 13
[4] Patent: EP2439202, 2012, A1. Location in patent: Page/Page column 17

3-Chlorosulfonyl-propionic acid methyl ester Preparation Products And Raw materials

Raw materials

Preparation Products

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15441-07-3, 3-Chlorosulfonyl-propionic acid methyl esterRelated Search:


  • 3-Chlorosulfonyl-propionic acid methyl ester
  • Methyl 3-chlorosulfonylpropionate
  • 3-Methoxy-3-oxopropanesulfonyl chloride
  • Propanoic acid, 3-(chlorosulfonyl)-, methyl ester
  • (CHLOROSULFONYL)&#8203
  • METHYL 3-&#8203
  • 15441-07-3