ChemicalBook > CAS DataBase List > METHYL 2-AMINO-6-FLUORO-3-NITROBENZOATE

METHYL 2-AMINO-6-FLUORO-3-NITROBENZOATE

Product Name: METHYL 2-AMINO-6-FLUORO-3-NITROBENZOATE
CAS No.: 346691-23-4
Chemical Name: METHYL 2-AMINO-6-FLUORO-3-NITROBENZOATE
Synonyms: METHYL 2-AMINO-6-FLUORO-3-NITROBENZOATE;2-Amino-6-fluoro-3-nitro-benzoic acid methyl ester;Benzoic acid, 2-amino-6-fluoro-3-nitro-, methyl ester;2-Amino-6-fluoro-3-nitro-benzoic acid methyl ester (9CI aci)
CBNumber: CB01118634
Molecular Formula: C8H7FN2O4
Formula Weight: 214.15
MOL File: Mol file

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METHYL 2-AMINO-6-FLUORO-3-NITROBENZOATE Property

Boiling point:: 360.9±42.0 °C(Predicted)
Density: 1.470±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
pka: -3.91±0.25(Predicted)
form: crystalline solid
color: Yellow

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Safety

HS Code: 2922498590

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: M332280
Product name: Methyl2-Amino-6-fluoro-3-nitrobenzoate
Packaging: 50mg
Price: $45
Updated: 2021/12/16

TRC

Product number: M332280
Product name: Methyl2-Amino-6-fluoro-3-nitrobenzoate
Packaging: 100mg
Price: $60
Updated: 2021/12/16

TRC

Product number: M332280
Product name: Methyl2-Amino-6-fluoro-3-nitrobenzoate
Packaging: 500mg
Price: $75
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4658-3-18
Product name: Methyl 2-amino-6-fluoro-3-nitrobenzoate
Purity: 97%
Packaging: 1g
Price: $48
Updated: 2021/12/16

Matrix Scientific

Product number: 071414
Product name: Methyl 2-amino-6-fluoro-3-nitrobenzoate
Purity: 98%
Packaging: 1g
Price: $58
Updated: 2021/12/16

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METHYL 2-AMINO-6-FLUORO-3-NITROBENZOATE Chemical Properties,Usage,Production

Synthesis

84832-01-9

346691-23-4

General procedure for the synthesis of methyl 2-amino-6-fluoro-3-nitrobenzoate from methyl 2,6-difluoro-3-nitrobenzoate: Methyl 2,6-difluoro-3-nitrobenzoate (32.55 g, 150 mmol) was dissolved in ethanol (300 mL), followed by the addition of ammonia (13 mL). The reaction mixture was stirred overnight at room temperature. Upon completion of the reaction, the resulting yellow solid product methyl 2-amino-6-fluoro-3-nitrobenzoate (18.31 g, 57% yield) was collected by filtration.

References

[1] Patent: CN104003979, 2016, B. Location in patent: Paragraph 0385; 0388; 0389
[2] Patent: CN103923088, 2016, B. Location in patent: Paragraph 0214; 0216; 0219; 01220
[3] Patent: WO2009/134850, 2009, A1. Location in patent: Page/Page column 16
[4] Bioorganic and Medicinal Chemistry Letters, 2012, vol. 22, # 7, p. 2620 - 2623
[5] Patent: US2010/305133, 2010, A1. Location in patent: Page/Page column 12

METHYL 2-AMINO-6-FLUORO-3-NITROBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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346691-23-4, METHYL 2-AMINO-6-FLUORO-3-NITROBENZOATE Related Search:

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METHYL 2-AMINO-6-FLUORO-3-NITROBENZOATE

2-Amino-6-fluoro-3-nitro-benzoic acid methyl ester

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2-Amino-6-fluoro-3-nitro-benzoic acid methyl ester (9CI aci)

346691-23-4

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