Uses Elements Extraction
ChemicalBook > CAS DataBase List > Salicylaldoxime

Salicylaldoxime

Uses Elements Extraction
Product Name
Salicylaldoxime
CAS No.
94-67-7
Chemical Name
Salicylaldoxime
Synonyms
icyL;doxime;Saldox;Sal-dox;2-(βSalicyladoxime;SALICYLALDOXIME;SalicyladoximeGr;SALICYLADOXIME AR;Salicaldehyde oxime
CBNumber
CB0112910
Molecular Formula
C7H7NO2
Formula Weight
137.14
MOL File
94-67-7.mol
More
Less

Salicylaldoxime Property

Melting point:
57-59 °C 59-61 °C (lit.)
Boiling point:
251.96°C (rough estimate)
Density 
1.2528 (rough estimate)
refractive index 
1.5030 (estimate)
storage temp. 
Sealed in dry,Room Temperature
solubility 
sparingly soluble in water, soluble in ethanol, diethyl ether, acetone, benzene.
pka
pK1:1.37(＋1);pK2:9.18;pK3:12.11 (25°C)
form 
Powder
color 
Bordeaux to purple-red
Odor
Odorless
Water Solubility 
Slightly soluble in water
Merck 
14,8327
BRN 
1859881
InChIKey
ORIHZIZPTZTNCU-VMPITWQZSA-N
CAS DataBase Reference
94-67-7(CAS DataBase Reference)
NIST Chemistry Reference
Benzaldehyde, 2-hydroxy-, oxime(94-67-7)
EPA Substance Registry System
Benzaldehyde, 2-hydroxy-, oxime (94-67-7)
More
Less

Safety

Hazard Codes 
Xn,Xi
Risk Statements 
22-36/37/38
Safety Statements 
26-36
WGK Germany 
3
RTECS 
VN5775000
TSCA 
Yes
HazardClass 
IRRITANT
HS Code 
29280000
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
84172
Product name
Salicylaldoxime
Purity
≥98.0% (NT)
Packaging
100g
Price
$216
Updated
2024/03/01
TCI Chemical
Product number
S0005
Product name
Salicylaldoxime
Purity
>98.0%(GC)
Packaging
25g
Price
$47
Updated
2024/03/01
TCI Chemical
Product number
S0005
Product name
Salicylaldoxime
Purity
>98.0%(GC)
Packaging
500g
Price
$507
Updated
2024/03/01
Alfa Aesar
Product number
A11080
Product name
Salicylaldoxime, 98%
Packaging
25g
Price
$29.65
Updated
2024/03/01
Alfa Aesar
Product number
A11080
Product name
Salicylaldoxime, 98%
Packaging
100g
Price
$102.65
Updated
2024/03/01
More
Less

Salicylaldoxime Chemical Properties,Usage,Production

Uses

Salicylaldoxime is an organic compound described by the formula C6H4CH=NOH-2-OH and it is the oxime of salicylaldehyde. This crystalline, colorless solid is a chelator and sometimes used in the analysis of samples containing transition metal ions, with which it often forms brightly colored coordination complexes.

Elements Extraction

Salicylaldoxime is recognized as a selective precipitant for copper, although it forms water-insoluble chelates with a number of elements. Ingvar Dahl invested the extraction of divalent magnesium, manganese, cobalt, nickel, copper, zinc, cadmium, mercury, and lead with solutions of salicylaldoxime in benzene and the effect of the reagent concentration and particularly the pH of the aqueous phase on the extractability was also studied. The solubility of salicylaldoxime in organic solvents has been utilized in the solvent extraction of carious elements.

Chemical Properties

off-white to light beige crystalline powder

Uses

Salicylaldoxime reacts with several metal ions to give intensively coloured complexes which are insoluble in water. The structure of the copper(II), nickel(II) and palladium(II) complexes is shown in Fig. 14 (structure I), and that of the manganese(II), iron(II), cobalt(II) and zinc(II) complexes in Fig. 14 (structure II). The copper(Il) and palladium(II) salicylaldoxime complexes are of importance from an analytical point of view. The complexes precipitated from aqueous media are easily filterable and washable and are weighed after drying at 100°C. The precipitates are of stoichiometric composition.
The outstanding stabilities of the copper(II) and palladium(II) complexes make the reagent suitable for the selective determination of these metal ions. These two complexes form quantitatively at low pH values where the complexes of other metal ions do not exist.
Besides the gravimetric method, salicylaldoxime is also useful in the volumetric, amperometric and nephelometric determinations of copper and palladium.
Salicylaldoxime gives a black precipitate with VOs~ in media containing sulfuric acid; this is soluble in chloroform to give an orange solution. The reaction is specific for vanadium which can thus be detected by this method in the presence of almost all other metals.
In neutral medium salicylaldoxime reacts with iron(III) to give a red complex which is soluble in water. The reaction is utilized for the detection of micro amounts of iron.

Uses

As a reagent for copper and nickel.

Salicylaldoxime Preparation Products And Raw materials

Raw materials

Salicylaldehyde

Preparation Products

ETHYL 3-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOLE-4-CARBOXYLATE 3-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOLE-4-CARBOXYLIC ACID 3-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOL-4-AMINE 4-BROMO-3-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOLE 3-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOLE-4-CARBOXAMIDE (3-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOL-4-YL)METHANOL 1-PHENYL-3-(TRIFLUOROMETHYL)PYRAZOLE 3-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOLE-4-CARBONITRILE 3-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOLE-5-CARBOXYLIC ACID (3-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOL-4-YL)METHANAMINE 2-Cyanophenol 3-(TRIFLUOROMETHYL)-1-PHENYL-1H-PYRAZOLE-4-CARBALDEHYDE
More
Less

Salicylaldoxime Suppliers

Austria 1 Belgium 1 China 159 Europe 3 Germany 3 India 19 Japan 3 Russia 1 South Korea 1 Switzerland 2 United Kingdom 14 United States 29 Global 236
Avonchem/Chromos Express Ltd.
Tel
--
Fax
--
Email
info@avonchem.co.uk
Country
United Kingdom
ProdList
1189
Advantage
50
Apin Chemicals Limited (UK)
Tel
--
Fax
--
Email
info@apinchemicals.com
Country
United Kingdom
ProdList
6184
Advantage
60
CMS Chemicals Limited
Tel
--
Fax
--
Email
cms.marketing@cms-chemicals.com
Country
United Kingdom
ProdList
3708
Advantage
60
Leancare Ltd.
Tel
--
Fax
--
Email
enquiry@leancare.co.uk
Country
United Kingdom
ProdList
6446
Advantage
42
CARBONE SCIENTIFIC CO.,LTD
Tel
--
Fax
--
Email
sales@carbonesci.com
Country
United Kingdom
ProdList
6666
Advantage
30
Eurolabs Limited
Tel
--
Fax
--
Country
United Kingdom
ProdList
6309
Advantage
46
MOLEKULA Ltd.
Tel
--
Fax
--
Email
kevinbanks@molekula.com
Country
United Kingdom
ProdList
6140
Advantage
66
Apollo Scientific Ltd.
Tel
--
Fax
--
Email
sales@apolloscientific.co.uk
Country
United Kingdom
ProdList
6084
Advantage
88
ARIAC - Armenian Institute of Applied Chemistry
Tel
--
Fax
--
Email
ariac@web.am
Country
United Kingdom
ProdList
2466
Advantage
46
Mole Chemical Corporation
Tel
--
Fax
--
Country
United Kingdom
ProdList
1444
Advantage
46
MDA Chemicals Ltd.
Tel
--
Fax
--
Email
sheila@mda-chem.co.uk
Country
United Kingdom
ProdList
1961
Advantage
30
Fluorochem Ltd.
Tel
--
Fax
--
Email
enquiries@fluorochem.co.uk
Country
United Kingdom
ProdList
6401
Advantage
74
Apin Chemicals Ltd.
Tel
--
Fax
--
Email
info@apinchemicals.com
Country
United Kingdom
ProdList
6807
Advantage
42
VWR International
Tel
--
Fax
--
Email
solutions@vwr.com
Country
United Kingdom
ProdList
6548
Advantage
82
More
Less

View Lastest Price from Salicylaldoxime manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Salicylaldoxime 94-67-7
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
1000KG
Release date
2024-08-14
Hebei Fengjia New Material Co., Ltd
Product
Salicylaldoxime 94-67-7
Price
US $7.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10000
Release date
2024-08-08
Hebei Weibang Biotechnology Co., Ltd
Product
Salicylaldoxime 94-67-7
Price
US $8.90/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2021-08-13

94-67-7, SalicylaldoximeRelated Search:

Salicylaldehyde Salicylic acid Sodium salicylate Benzyl salicylate AMMONIUM SALICYLATE Methyl salicylate SALICYLALDEHYDE AZINE Salicylhydrazide 2,4-DIHYDROXYBENZALDEHYDE OXIME Benzoximate 2,3-DIMETHOXYBENZALDOXIME 3,5-DIBROMOSALICYLALDOXIME FORMOXIME Benzaldoxime 2,4-DIHYDROXYACETOPHENONE OXIME 2,3,4-TRIMETHOXYBENZALDEHYDE OXIME N-HYDROXY-2,4-DIMETHOXY-BENZAMIDINE OXIME

  • LABOTEST-BB LT00000132
  • SALICYLALDEHYDE OXIME
  • SALICYLALDOXIME
  • 2-HYDROXYBENZALDEHYDE OXIME
  • SALICYLALDOXIME / 2-HYDROXYBENZALDEHYDE OXIME
  • SalicylaldoxiMe, 98% 100GR
  • SalicylaldoxiMe, 98% 25GR
  • SalicylaldoxiMe >=98.0% (NT)
  • (E)-2-hydroxybenzaldehyde oxiMe
  • doxime
  • icyL
  • SALICYLALDOXIME R. G.
  • SALICYLALDOXIME, REAGENT GRADE
  • SalicyladoximeGr
  • Salicylaldoxime,98+%
  • Benzaldehyde,2-hydroxy-,oxime
  • o-Hydroxybenzaldehyde oxime
  • o-hydroxybenzaldehydeoxime
  • o-Hydroxybenzaldoxime
  • Saldox
  • Sal-dox
  • Salicaldehyde oxime
  • Salicylaldehydoxime
  • (2-Hydroxyphenylmethylene)azanol
  • 2-hydroxy-benzaldehydoxime
  • 2-Hydroxybenzaldoxime
  • Salicyladoxime
  • 2-Hydroxy-benzaldehyde oxime Salicylaldoxime
  • Salicylaldo94-67-7xime
  • Salicylaldoxime &gt
  • Salicylaldoxime, GR 98%+
  • SALICYLADOXIME AR
  • 2-(&#x3B2
  • -D-glucopyranosyloxy)benzaldehyde
  • 94-67-7
  • 94-67-6
  • HOC6H4CHNOH
  • 2HOC6H4CHNOH
  • C7F7NO2
  • Building Blocks
  • Oximes
  • Nitrogen Compounds
  • Organic Building Blocks
  • Aromatic Hydrazides, Hydrazines, Hydrazones and Oximes