ChemicalBook > CAS DataBase List > Chloromethyltrimethoxysilane

Chloromethyltrimethoxysilane

Product Name
Chloromethyltrimethoxysilane
CAS No.
5926-26-1
Chemical Name
Chloromethyltrimethoxysilane
Synonyms
ND-40;DK833;DK343;DK342;DKSI159;DKFELEX0218;Co-Formula CFS-C261;CHLOROMETHYLTRIMETHOXYSILANE;Chloromethvltrimethoxysilane;chloromethyl-trimethoxy-silan
CBNumber
CB0114833
Molecular Formula
C4H11ClO3Si
Formula Weight
170.67
MOL File
5926-26-1.mol
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Chloromethyltrimethoxysilane Property

Boiling point:
151 °C (lit.)
Density 
1.132 g/mL at 25 °C (lit.)
refractive index 
1.407 [25°C]
Flash point:
26 °F
storage temp. 
Storage temp. 2-8°C
form 
clear liquid
color 
Colorless to Almost colorless
Specific Gravity
1.125
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
InChI
InChI=1S/C4H11ClO3Si/c1-6-9(4-5,7-2)8-3/h4H2,1-3H3
InChIKey
FPOSCXQHGOVVPD-UHFFFAOYSA-N
SMILES
[Si](CCl)(OC)(OC)OC
CAS DataBase Reference
5926-26-1(CAS DataBase Reference)
NIST Chemistry Reference
Silane, chloromethyl-trimethoxy-(5926-26-1)
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Safety

Hazard Codes 
F
Risk Statements 
11
Safety Statements 
16-29-33
RIDADR 
UN 1993 3/PG 2
WGK Germany 
3
RTECS 
VV2625000
TSCA 
No
HazardClass 
3
PackingGroup 
II
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
597201
Product name
Chloromethyltrimethoxysilane
Purity
96%
Packaging
25g
Price
$290
Updated
2023/06/20
TCI Chemical
Product number
C3073
Product name
(Chloromethyl)trimethoxysilane
Purity
>98.0%(GC)
Packaging
5g
Price
$58
Updated
2025/07/31
TCI Chemical
Product number
C3073
Product name
(Chloromethyl)trimethoxysilane
Purity
>98.0%(GC)
Packaging
25g
Price
$173
Updated
2025/07/31
Frontier Specialty Chemicals
Product number
JK118720
Product name
Chloromethyltrimethoxysilane
Purity
96%
Packaging
5g
Price
$60
Updated
2021/12/16
AK Scientific
Product number
J99963
Product name
(Chloromethyl)trimethoxysilane
Packaging
100g
Price
$154
Updated
2021/12/16
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Chloromethyltrimethoxysilane Chemical Properties,Usage,Production

Chemical Properties

Clear transparent liquid

Uses

Chloromethyltrimethoxysilane may be used in the preparation of 1-methyl-1H-benzimidazole (MBI)-modified nanoparticles.{33} Mesoporous monolithic silica gels can also be prepared from Chloromethyltrimethoxysilane. {34}

General Description

Chloromethyltrimethoxysilane (CMTMS) is a trialkoxysilane with chloromethyl as the organofunctional group having hydrophobic characteristics. Chloromethyl is the electron withdrawing group that improves the mechanical properties of the molecule. CMTMS is mainly utilized as a silane based precursor material for the preparation of surface enhancement based coatings and other silane based products.

Synthesis

1558-25-4

149-73-5

5926-26-1

The general procedure for the synthesis of chloromethyltrimethoxysilane from chloromethyltrichlorosilane and trimethyl orthoformate was as follows: 570.2 g (3.1 mol) of chloromethyltrichlorosilane was slowly added dropwise to 1127.8 g (10.64 mol) of trimethyl orthoformate, and the dropwise acceleration was controlled so that the reaction mixture was kept at a slight boiling state. After the dropwise addition was completed, the reaction system was heated to 90°C and the reaction was maintained at this temperature for 5 hours. Upon completion of the reaction, the reaction mixture was purified by distillation, resulting in 449.8 g of the target product chloromethyltrimethoxysilane (Compound 2a). The structure of the product was confirmed by 1H NMR spectrum with the following chemical shifts δ (ppm): 2.77 (single peak, 2H, CH2), 3.58 (single peak, 9H, OCH3).

References

[1] Russian Journal of General Chemistry, 2016, vol. 86, # 8, p. 1859 - 1863
[2] Zh. Obshch. Khim., 2016, vol. 86, # 8, p. 1321 - 1326,6

Chloromethyltrimethoxysilane Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Chloromethyltrimethoxysilane manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
Chloromethyltrimethoxysilane 5926-26-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-10
Career Henan Chemical Co
Product
Chloromethyltrimethoxysilane 5926-26-1
Price
US $2.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
customise
Release date
2018-08-10

5926-26-1, ChloromethyltrimethoxysilaneRelated Search:


  • (trimethoxychloromethyl)silane
  • chloromethyl-trimethoxy-silan
  • CHLOROMETHYLTRIMETHOXYSILANE
  • Silane,(chloromethyl)trimethoxy-
  • ND-40
  • (Trimethoxysilyl)chloromethane
  • Chloro(trimethoxysilyl)methane
  • Co-Formula CFS-C261
  • (Chloromethyl)trimethoxysilane &gt
  • DK343
  • DK833
  • DK342
  • Chloromethvltrimethoxysilane
  • DKFELEX0218
  • DKSI159
  • chloromethyl-trimethoxy-silan,95%
  • 5926-26-1
  • C4H11ClO3Si
  • C4H14ClO3Si
  • H3CO3SiCH2Cl
  • Alkoxy Silanes
  • Alpha Silanes
  • Self Assembly&Contact Printing
  • Self-Assembly Materials
  • Silanes