(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%

Reaction

Product Name: (S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
CAS No.: 145214-59-1
Chemical Name: (S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
Synonyms: SL-A108-2;(S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis(di-2-furylphosphine);(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(di-2-furylphosphine);(S)-2,2'-Bis(di-2-furylphosphino)-6,6'-dimethoxy-1,1'- biphenyl;(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl;(S)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(di-2-furylphosphine);(S)-(-)-2,2''-Bis(di-2-furanylphosphino)-6,6''-dimethoxy-1,1''-biphenyl;(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%;(S)-(-)-2,2''-BIS(DI-2-FURANYLPHOSPHINO)-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%;[2-[2-[bis(furan-2-yl)phosphanyl]-6-methoxyphenyl]phenyl]-bis(furan-2-yl)phosphane
CBNumber: CB01180987
Molecular Formula: C30H24O6P2
Formula Weight: 542.46
MOL File: 145214-59-1.mol

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(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Property

Boiling point:: 587.5±50.0 °C(Predicted)
storage temp.: 2-8°C, protect from light, stored under nitrogen
form: Powder
color: off-white
Stability:: store cold
InChI: InChI=1S/C30H24O6P2/c1-31-21-9-3-11-23(37(25-13-5-17-33-25)26-14-6-18-34-26)29(21)30-22(32-2)10-4-12-24(30)38(27-15-7-19-35-27)28-16-8-20-36-28/h3-20H,1-2H3
InChIKey: ABGYJVGTLXSMBM-UHFFFAOYSA-N
SMILES: C1C=CC(P(C2OC=CC=2)C2OC=CC=2)=C(C2C(P(C3OC=CC=3)C3OC=CC=3)=CC=CC=2OC)C=1OC
CAS DataBase Reference: 145214-59-1

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Safety

WGK Germany: 3
HS Code: 29321900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 29515
Product name: (S)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(di-2-furylphosphine)
Purity: ≥97%, optical purity ee: ≥99%
Packaging: 1g
Price: $659
Updated: 2023/06/20

Strem Chemicals

Product number: 15-0113
Product name: (S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Packaging: 100mg
Price: $96
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0113
Product name: (S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Packaging: 500mg
Price: $355
Updated: 2024/03/01

Sigma-Aldrich

Product number: 29515
Product name: (S)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(di-2-furylphosphine)
Purity: ≥97%, optical purity ee: ≥99%
Packaging: 100mg
Price: $101
Updated: 2023/01/07

Sigma-Aldrich

Product number: 29515
Product name: (S)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(di-2-furylphosphine)
Purity: ≥97%, optical purity ee: ≥99%
Packaging: 500mg
Price: $479
Updated: 2023/01/07

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(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Chemical Properties,Usage,Production

Reaction

In many respects the catalytic profile of the MeO-BIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions.
Stereocontrol in palladium-catalyzed propargylic substitutions: kinetc resolution to give enantioenriched 1,5-enynes and propargyl acetates.
Study of enantioselective catalysis of nitroso-Diels-Alder reaction on solid support.

Chemical Properties

White powder

Uses

Atropisomeric MeOBIPHEP ligands

General Description

sold in collaboration with Solvias AG

(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Suppliers

China 22 Switzerland 1 United States 4 Global 27

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145214-59-1, (S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%Related Search:

Calcium carbonate Tungsten Methanol Mercury Barium hydroxide Potassium carbonate Tri-tert-butylphosphine Pyrrole Nitric acid Dimethyl sulfoxide Silicon dioxide

(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%

(S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis(di-2-furylphosphine)

(S)-2-Furyl-MeOBIPHEP, SL-A108-2, (S)-(-)-2,2μ-Bis(di-2-furylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl

(S)-(-)-2,2''-BIS(DI-2-FURANYLPHOSPHINO)-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%

(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl

SL-A108-2

(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(di-2-furylphosphine) >=97%, optical purity ee: >=99%

[2-[2-[bis(furan-2-yl)phosphanyl]-6-methoxyphenyl]phenyl]-bis(furan-2-yl)phosphane

Phosphine, 1,1'-[(1S)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-di-2-furanyl-

(S)-2,2'-Bis(di-2-furylphosphino)-6,6'-dimethoxy-1,1'- biphenyl

(S)-(-)-2,2''-Bis(di-2-furanylphosphino)-6,6''-dimethoxy-1,1''-biphenyl

(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(di-2-furylphosphine)

(<i>S</i>)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(di-2-furylphosphine)

145214-59-1

C30H24O6P2

Chiral Phosphine

MeOBIPHEP Series