ChemicalBook > CAS DataBase List > (S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
Reaction- Product Name
- (S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
- CAS No.
- 145214-59-1
- Chemical Name
- (S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
- Synonyms
- SL-A108-2;(S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis(di-2-furylphosphine);(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(di-2-furylphosphine);(S)-2,2'-Bis(di-2-furylphosphino)-6,6'-dimethoxy-1,1'- biphenyl;(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl;(S)-(-)-2,2''-Bis(di-2-furanylphosphino)-6,6''-dimethoxy-1,1''-biphenyl;(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%;(S)-(-)-2,2''-BIS(DI-2-FURANYLPHOSPHINO)-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%;[2-[2-[bis(furan-2-yl)phosphanyl]-6-methoxyphenyl]phenyl]-bis(furan-2-yl)phosphane;Phosphine, 1,1'-[(1S)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-di-2-furanyl-
- CBNumber
- CB01180987
- Molecular Formula
- C30H24O6P2
- Formula Weight
- 542.46
- MOL File
- 145214-59-1.mol
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(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Property
- Boiling point:
- 587.5±50.0 °C(Predicted)
- form
- Powder
- color
- off-white
- Stability:
- store cold
- CAS DataBase Reference
- 145214-59-1
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Safety
- WGK Germany
- 3
- HS Code
- 29321900
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 29515
- Product name
- (S)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(di-2-furylphosphine)
- Purity
- ≥97%, optical purity ee: ≥99%
- Packaging
- 1g
- Price
- $659
- Updated
- 2023/06/20
Strem Chemicals
- Product number
- 15-0113
- Product name
- (S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
- Packaging
- 100mg
- Price
- $96
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-0113
- Product name
- (S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
- Packaging
- 500mg
- Price
- $355
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 29515
- Product name
- (S)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(di-2-furylphosphine)
- Purity
- ≥97%, optical purity ee: ≥99%
- Packaging
- 100mg
- Price
- $101
- Updated
- 2023/01/07
Sigma-Aldrich
- Product number
- 29515
- Product name
- (S)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(di-2-furylphosphine)
- Purity
- ≥97%, optical purity ee: ≥99%
- Packaging
- 500mg
- Price
- $479
- Updated
- 2023/01/07
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(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Chemical Properties,Usage,Production
Reaction
In many respects the catalytic profile of the MeO-BIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions.
Stereocontrol in palladium-catalyzed propargylic substitutions: kinetc resolution to give enantioenriched 1,5-enynes and propargyl acetates.
Study of enantioselective catalysis of nitroso-Diels-Alder reaction on solid support.
Chemical Properties
White powder
Uses
Atropisomeric MeOBIPHEP ligands
General Description
sold in collaboration with Solvias AG
(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Preparation Products And Raw materials
Raw materials
Preparation Products
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(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Suppliers
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