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ChemicalBook > CAS DataBase List > Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II)

Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II)

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Product Name
Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II)
CAS No.
374067-50-2
Chemical Name
Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II)
Synonyms
(R)-Ru(OAc)2(DM-BINAP);Ru(OAc)2[(R)-xylbinap];RU[(R)-DM-BINAP](OCOH3)2;Ru(OCOCH3)2((S)-dm-binap);Ru[( R)-DM-BINAP](OCOCH3)2;(R)-Ru(OAc)2(DM-BINAP);Diacetato[(R)-2,2μ-bis[di(3,5-xylyl)phosphino]-1,1μ-binaphtyl]ruthenium(II);Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II);Ru(OAc)2[(R)-xylbinap]/Diacetato{(R)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II);Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II),Ru(OAc)2[(R)-xylbinap]
CBNumber
CB01181065
Molecular Formula
C56H56O4P2Ru
Formula Weight
956.08
MOL File
374067-50-2.mol
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Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II) Property

Melting point:
>100°C
storage temp. 
2-8°C
Water Solubility 
Insoluble in water
form 
Powder
color 
dark brown
Sensitive 
air sensitive
InChIKey
HDUAMHMUQGCXCT-UHFFFAOYSA-N
SMILES
CC1=O[Ru+2]23(O=C(C)[O-]2)(P(C2C=C(C)C=C(C)C=2)(C2C=C(C)C=C(C)C=2)C2=CC=C4C=CC=CC4=C2C2=C4C=CC=CC4=CC=C2P3(C2C=C(C)C=C(C)C=2)C2C=C(C)C=C(C)C=2)[O-]1
CAS DataBase Reference
374067-50-2
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Safety

WGK Germany 
3
HS Code 
2843.90.0000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H228Flammable solid

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P321Specific treatment (see … on this label).

P322Specific measures (see …on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P363Wash contaminated clothing before reuse.

P370+P378In case of fire: Use … for extinction.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
R0170
Product name
Ru(OAc)2[(R)-xylbinap]
Packaging
200MG
Price
$64
Updated
2025/07/31
TCI Chemical
Product number
R0170
Product name
Ru(OAc)2[(R)-xylbinap]
Packaging
1G
Price
$193
Updated
2025/07/31
Strem Chemicals
Product number
44-0164
Product name
Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II) Ru(OAc)2[(R)-xylbinap]
Packaging
250mg
Price
$64
Updated
2024/03/01
Strem Chemicals
Product number
44-0164
Product name
Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II) Ru(OAc)2[(R)-xylbinap]
Packaging
1g
Price
$190
Updated
2024/03/01
Sigma-Aldrich
Product number
692158
Product name
(R)-Ru(OAc)2(DM-BINAP)
Packaging
250mg
Price
$89
Updated
2023/06/20
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Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II) Chemical Properties,Usage,Production

Reactions

Catalyst system used for asymmetric hydrogenation.

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II) Suppliers

China 35 India 2 Japan 2 Switzerland 1 United States 4 Global 44
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View Lastest Price from Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II) manufacturers

XINXIANG RUNYU MATERIAL CO., LTD.
Product
Ru(OAc)2[(R)-xylbinap] 374067-50-2
Price
US $0.00-0.00/G
Min. Order
100G
Purity
98%
Supply Ability
10kg
Release date
2025-03-17
Career Henan Chemical Co
Product
Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II) 374067-50-2
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1kg,5kg,100kg
Release date
2019-08-08

374067-50-2, Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II)Related Search:


  • Ru(OAc)2[(R)-xylbinap]
  • Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II)
  • (R)-Ru(OAc)2(DM-BINAP)
  • Diacetato[(R)-2,2μ-bis[di(3,5-xylyl)phosphino]-1,1μ-binaphtyl]ruthenium(II)
  • Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II) Ru(OAc)2[(R)-xylbinap]
  • Ru(OCOCH3)2((S)-dm-binap)
  • RU[(R)-DM-BINAP](OCOH3)2
  • Ru[( R)-DM-BINAP](OCOCH3)2
  • Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II),Ru(OAc)2[(R)-xylbinap]
  • (<i>R</i>)-Ru(OAc)<sub>2</sub>(DM-BINAP)
  • Ru(OAc)2[(R)-xylbinap]/Diacetato{(R)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II)
  • 374067-50-2
  • Ru