ChemicalBook > CAS DataBase List > Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)
Reaction- Product Name
- Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)
- CAS No.
- 199684-47-4
- Chemical Name
- Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)
- Synonyms
- (R)-[(RuCl(BINAP))2(μ-Cl)3[NH2Me2];(R)-[(RuCl(BINAP))2(mu-Cl)3[NH2Me2];[NH2ME2][(RUCL((R)-BINAP))2(Μ-CL)3];[NH2Me2][{RuCl((R)-binap)}2(mu-Cl)3];-binaphthyl]diruthenate(II),[NH2Me2][{RuCl((R);Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II);Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2μ-bis(diphenylphosphino)-1,1μ-binaphthyl]diruthenate(II);DIMETHYLAMMONIUM DICHLOROTRI(Μ-CHLORO)BIS[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]DIRUTHENATE(II),[NH2ME2][{RUCL((R);Dimethylammonium dichlorotri(chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-binap)}2(Cl)3];DiMethylaMMoniuM dichlorotri(Mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-binap)}2(μ-Cl)3]
- CBNumber
- CB01181085
- Molecular Formula
- C90H76Cl5NP4Ru2
- Formula Weight
- 1674.89
- MOL File
- 199684-47-4.mol
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Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Property
- Melting point:
- >100°C
- storage temp.
- 2-8°C
- form
- Powder
- color
- orange
- Sensitive
- air sensitive
- CAS DataBase Reference
- 199684-47-4
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Safety
- WGK Germany
- 3
- HS Code
- 2843.90.0000
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 692433
- Product name
- (R)-[(RuCl(BINAP))2(μ-Cl)3[NH2Me2]
- Packaging
- 100mg
- Price
- $36.8
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 692433
- Product name
- (R)-[(RuCl(BINAP))2(μ-Cl)3[NH2Me2]
- Packaging
- 500mg
- Price
- $123
- Updated
- 2023/06/20
TCI Chemical
- Product number
- N1015
- Product name
- [NH2Me2][(RuCl((R)-binap))2(μ-Cl)3]
- Packaging
- 200mg
- Price
- $43
- Updated
- 2024/03/01
TCI Chemical
- Product number
- N1015
- Product name
- [NH2Me2][(RuCl((R)-binap))2(μ-Cl)3]
- Packaging
- 1g
- Price
- $140
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 44-0510
- Product name
- Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-binap)}2(μ-Cl)3]
- Packaging
- 250mg
- Price
- $53
- Updated
- 2024/03/01
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Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Chemical Properties,Usage,Production
Reaction
- (R)-BINAP or (R)-Tol-BINAP can be combined with dichloro(1,5-cyclooctadiene)ruthenium to form precursors to NOYORI CATALYST SYSTEMS. These systems exhibit very high catalytic activity and enantioselectivity in the hydrogenation of a wide range of substrates. NOYORI CATALYST SYSTEMS have been shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydroxy, siloxy, carbonyl, ester, amide or thioester.
- Useful ligand in asymmetric Heck processes.
- Ligand employed in palladium-catalyzed asymmetric arylation of ketones.
- Ligand employed in rhodium-catalyzed 1,4-additions to enones.
- Ligand employed in palladium-catalyzed hydroamination of styrene derivatives.
- Ligand employed in silver-catalyzed asymmetric Sakuri-Hosomi allylation and Mukaiyama aldol reaction.
- Ligand employed in rhodium-catalyzed kinetic resolution of enynes.
- Ligand employed in asymmetric rhodium-catalyzed hydroboration of cyclopropenes.
- Ligand employed in silver-catalyzed a-hydroxylation of stannyl enol ethers.
- Ligand employed in palladium-catalyzed synthesis of chiral allenes.
- Ligand for palladium-catalyzed enantioselective hetero Michael addition to form b-amino acid derivatives.
- Ligand employed in rhodium-catalyzed asymmetric rearrangement of alkynyl alkenyl carbinols.
- Ligand employed in rhodium-catalyzed 1,2-addition of aluminium organyl compounds to cyclic enones.
- Ligand employed in iridium-catalyzed transfer hydrogenative allylation of benzylic alcohols.
- Ligand employed in rhodium-catalyzed asymmetric C-Si bond formation by conjugate silyl transfer using a Si-B linkage.
Uses
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Preparation Products And Raw materials
Raw materials
Preparation Products
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