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2-Methoxybenzonitrile

Product Name
2-Methoxybenzonitrile
CAS No.
6609-56-9
Chemical Name
2-Methoxybenzonitrile
Synonyms
AKOS 91422;AKOS B005792;O-CYANOANISOLE;2-CYANOANISOLE;o-Anisonitrile;2-Methxybenzonitrile;2-Methoxybenzonitril;2-METHOXYBENZONITRILE;O-METHOXYBENZONITRILE;2-methoxybnezonitrile
CBNumber
CB0126249
Molecular Formula
C8H7NO
Formula Weight
133.15
MOL File
6609-56-9.mol
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2-Methoxybenzonitrile Property

Melting point:
24.5°C
Boiling point:
135 °C12 mm Hg(lit.)
Density 
1.093 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.5465(lit.)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
Water Solubility 
Slightly soluble in water
form 
Liquid
color 
Clear colorless to pale yellow
BRN 
2207134
InChI
InChI=1S/C8H7NO/c1-10-8-5-3-2-4-7(8)6-9/h2-5H,1H3
InChIKey
FSTPMFASNVISBU-UHFFFAOYSA-N
SMILES
C(#N)C1=CC=CC=C1OC
CAS DataBase Reference
6609-56-9(CAS DataBase Reference)
NIST Chemistry Reference
o-Methoxybenzonitrile(6609-56-9)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
RIDADR 
3276
WGK Germany 
3
HazardClass 
6.1
PackingGroup 
III
HS Code 
29269090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
231231
Product name
2-Methoxybenzonitrile
Purity
99%
Packaging
5g
Price
$61.6
Updated
2023/06/20
Sigma-Aldrich
Product number
231231
Product name
2-Methoxybenzonitrile
Purity
99%
Packaging
25g
Price
$132
Updated
2023/06/20
TCI Chemical
Product number
M1280
Product name
2-Methoxybenzonitrile
Purity
>98.0%(GC)
Packaging
5g
Price
$41
Updated
2024/03/01
TCI Chemical
Product number
M1280
Product name
2-Methoxybenzonitrile
Purity
>98.0%(GC)
Packaging
25g
Price
$126
Updated
2024/03/01
Alfa Aesar
Product number
L01293
Product name
2-Methoxybenzonitrile, 98%
Packaging
5g
Price
$36.65
Updated
2024/03/01
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2-Methoxybenzonitrile Chemical Properties,Usage,Production

Chemical Properties

Colorless liquid

Uses

2-Methoxybenzonitrile was used in the synthesis of 5-(4′-methyl [1,1′-biphenyl]-2-yl)-1H-tetrazole.

Preparation

o-Anisidine with sodium nitrite to make a diazonium salt solution, add it to the lead cyanide solution, and then add benzene. Put the mixture for 10-15h and carry out steam distillation, separate the benzene layer from the distillate, dry it with calcium chloride, evaporate the benzene, and distill the residue under reduced pressure, collect 120-122.5°C (1.2kPa fraction) to get 2-Methoxybenzonitrile, yield 64.5-67.3%.

Synthesis Reference(s)

Journal of the American Chemical Society, 77, p. 109, 1955 DOI: 10.1021/ja01606a035
Synthesis, p. 641, 1992
Tetrahedron Letters, 32, p. 1007, 1991 DOI: 10.1016/S0040-4039(00)74473-X

General Description

Surface-enhanced Raman spectra study of 2-methoxybenzonitrile has been reported.

2-Methoxybenzonitrile Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Methoxybenzonitrile Suppliers

Evonik Industries AG.
Tel
--
Fax
--
Email
@evonik.com
Country
Germany
ProdList
351
Advantage
58
HPC Standards GmbH
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Email
chulze@hpc-standards.com
Country
Germany
ProdList
2139
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58
CHEMOS GmbH & Co. KG
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Email
chemos@chemos.de
Country
Germany
ProdList
6727
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58
Alzchem AG
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Email
info@alzchem.com
Country
Germany
ProdList
98
Advantage
58
AlzChem Trostberg GmbH
Tel
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Email
brigitte.weiher@AlzChem.com
Country
Germany
ProdList
98
Advantage
50
ABCR GmbH & CO. KG
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Email
info@abcr.de
Country
Germany
ProdList
6831
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PARAGOS
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Email
info@paragos.com
Country
Germany
ProdList
6371
Advantage
39
Service Chemical Inc.
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Email
sales@chemos-group.com
Country
Germany
ProdList
6350
Advantage
71
AKos Consulting & Solutions GmbH
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Email
akos@akosgmbh.de
Country
Germany
ProdList
6717
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72
Degussa AG
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Fax
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Email
degussa-bk@degussa.com
Country
Germany
ProdList
641
Advantage
64
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View Lastest Price from 2-Methoxybenzonitrile manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
2-Methoxybenzonitrile 6609-56-9
Price
US $8.90/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-22
Hebei Chuanghai Biotechnology Co,.LTD
Product
2-Methoxybenzonitrile 6609-56-9
Price
US $9.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100000kg
Release date
2024-08-23
Hebei Fengjia New Material Co., Ltd
Product
2-Methoxybenzonitrile 6609-56-9
Price
US $4.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10000
Release date
2024-08-08

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