3-Pyridinemethanol,2-methoxy-(9CI)
- Product Name
- 3-Pyridinemethanol,2-methoxy-(9CI)
- CAS No.
- 112197-16-7
- Chemical Name
- 3-Pyridinemethanol,2-methoxy-(9CI)
- Synonyms
- (2-Methoxypyridin-3-yl);2-Methoxypyridine-3-methanol;2-Methoxy-3-pyridinemethanol;3-Pyridinemethanol, 2-methoxy-;(2-Methoxypyridin-3-yl)methanol;(2-Methoxy-3-pyridinyl)methanol;3-Hydroxymethyl-2-methoxypyridine;3-Pyridinemethanol,2-methoxy-(9CI);(2-Methoxypyridin-3-yl)methanol 97%
- CBNumber
- CB01281862
- Molecular Formula
- C7H9NO2
- Formula Weight
- 139.15
- MOL File
- 112197-16-7.mol
3-Pyridinemethanol,2-methoxy-(9CI) Property
- Melting point:
- lowmeltsolid°
- Boiling point:
- 242℃
- Density
- 1.155
- Flash point:
- 100℃
- storage temp.
- Inert atmosphere,Room Temperature
- pka
- 13.20±0.10(Predicted)
- Appearance
- White to off-white Solid
Safety
- RIDADR
- UN2811
- HazardClass
- IRRITANT
- HS Code
- 2933399990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P312Call a POISON CENTER or doctor/physician if you feel unwell.
P403+P233Store in a well-ventilated place. Keep container tightly closed.
N-Bromosuccinimide Price
- Product number
- M226508
- Product name
- (2-Methoxypyridin-3-yl)methanol
- Packaging
- 50mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- M226508
- Product name
- (2-Methoxypyridin-3-yl)methanol
- Packaging
- 100mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- Y15325
- Product name
- (2-Methoxypyridin-3-yl)methanol
- Purity
- 98%
- Packaging
- 1g
- Price
- $20
- Updated
- 2021/12/16
- Product number
- 048540
- Product name
- (2-Methoxy-3-pyridinyl)methanol
- Purity
- >95%
- Packaging
- 500mg
- Price
- $29
- Updated
- 2021/12/16
- Product number
- 048540
- Product name
- (2-Methoxy-3-pyridinyl)methanol
- Purity
- >95%
- Packaging
- 1g
- Price
- $44
- Updated
- 2021/12/16
3-Pyridinemethanol,2-methoxy-(9CI) Chemical Properties,Usage,Production
Synthesis
67367-26-4
112197-16-7
General procedure for the synthesis of (2-methoxy-3-pyridine)methanol from methyl 2-methoxynicotinate: Example 138: Preparation of (2-methoxy-3-pyridine)methanol Methyl 2-methoxy-3-pyridinecarboxylate (1.021 g, 6.11 mmol) was dissolved in anhydrous tetrahydrofuran (5 mL) and lithium borohydride (0.266 g, 1.22 mmol) was added batchwise. The reaction mixture was heated to 70 °C and kept for 2 hours. Upon completion of the reaction, the reaction was quenched by the addition of saturated aqueous ammonium chloride, followed by three extractions with ethyl acetate (3×). The organic phases were combined, dried with magnesium sulfate and concentrated under reduced pressure to give (2-methoxy-3-pyridine)methanol as a colorless oil (0.849 g, 100% yield). 1H-NMR (400 MHz, CDCl3): δ 2.29 (1H, m, OH), 4.0 (3H, s, OCH3), 4.67 (2H, m, CH2), 6.89 (1H, m, Ar-H), 7.59 (1H, m, Ar-H), 8.1 (1H, m, Ar-H) ppm.
References
[1] Patent: WO2007/71900, 2007, A1. Location in patent: Page/Page column 95
[2] Synthetic Communications, 1996, vol. 26, # 12, p. 2257 - 2272
[3] Patent: US2007/49632, 2007, A1. Location in patent: Page/Page column 38
[4] Journal of Medicinal Chemistry, 2000, vol. 43, # 18, p. 3386 - 3399
[5] Patent: EP1422228, 2004, A1. Location in patent: Page 205-206
3-Pyridinemethanol,2-methoxy-(9CI) Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 3-Pyridinemethanol,2-methoxy-(9CI) manufacturers
- Product
- 3-Pyridinemethanol,2-methoxy-(9CI) 112197-16-7
- Price
- US $1.00/g
- Min. Order
- 1g
- Purity
- 99.0%
- Supply Ability
- 100kg
- Release date
- 2020-01-09