6-AMINO-1,3-BENZODIOXOLE-5-CARBOXYLIC ACID
- Product Name
- 6-AMINO-1,3-BENZODIOXOLE-5-CARBOXYLIC ACID
- CAS No.
- 20332-16-5
- Chemical Name
- 6-AMINO-1,3-BENZODIOXOLE-5-CARBOXYLIC ACID
- Synonyms
- 1,3-Benzodioxole-5-carboxylicacid, 6-aMino-;6-AMinobenzo[d][1,3]dioxole-5-carboxylic acid
- CBNumber
- CB01491146
- Molecular Formula
- C8H7NO4
- Formula Weight
- 181.15
- MOL File
- 20332-16-5.mol
6-AMINO-1,3-BENZODIOXOLE-5-CARBOXYLIC ACID Property
- Melting point:
- 176-178 °C
- Boiling point:
- 387.9±42.0 °C(Predicted)
- Density
- 1.569±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- pka
- 2.35±0.20(Predicted)
- Appearance
- Yellow to brown Solid
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- A637663
- Product name
- 6-Aminobenzo[d][1,3]dioxole-5-carboxylicacid
- Packaging
- 5mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- A637663
- Product name
- 6-Aminobenzo[d][1,3]dioxole-5-carboxylicacid
- Packaging
- 50mg
- Price
- $90
- Updated
- 2021/12/16
- Product number
- 0416AB
- Product name
- 6-Aminobenzo[d][1,3]dioxole-5-carboxylicacid
- Packaging
- 250mg
- Price
- $153
- Updated
- 2021/12/16
- Product number
- CHM0117892
- Product name
- 6-AMINO-BENZO[1,3]DIOXOLE-5-CARBOXYLIC ACID
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $925.31
- Updated
- 2021/12/16
- Product number
- CHM0117892
- Product name
- 6-AMINO-BENZO[1,3]DIOXOLE-5-CARBOXYLIC ACID
- Purity
- 95.00%
- Packaging
- 2.5G
- Price
- $1363.65
- Updated
- 2021/12/16
6-AMINO-1,3-BENZODIOXOLE-5-CARBOXYLIC ACID Chemical Properties,Usage,Production
Synthesis
40680-63-5
20332-16-5
General procedure for the synthesis of 6-aminobenzo[d][1,3]dioxole-5-carboxylic acid from methyl 6-aminobenzo[d][1,3]dioxole-5-carboxylate: Sodium hydroxide (2.95 g, 73.8 mmol) was added to water (75 mL), and stirred until completely dissolved. Methyl 6-aminobenzo[d][1,3]dioxole-5-carboxylate (12.0 g, 61.5 mmol) was then added and the reaction mixture was heated to 90°C and stirred for 2 hours. After completion of the reaction, the reaction mixture was cooled with ice water and the pH was adjusted to 2 with concentrated hydrochloric acid to precipitate a solid. The mixture was stirred thoroughly and filtered, the filter cake was washed with water and dried to give 6-aminobenzo[d][1,3]dioxole-5-carboxylic acid (7.2 g, 65% yield).
References
[1] Patent: CN104557955, 2017, B. Location in patent: Paragraph 0152; 0156
6-AMINO-1,3-BENZODIOXOLE-5-CARBOXYLIC ACID Preparation Products And Raw materials
Raw materials
Preparation Products
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