ChemicalBook > CAS DataBase List > 6-AMINO-1,3-BENZODIOXOLE-5-CARBOXYLIC ACID

6-AMINO-1,3-BENZODIOXOLE-5-CARBOXYLIC ACID

Product Name
6-AMINO-1,3-BENZODIOXOLE-5-CARBOXYLIC ACID
CAS No.
20332-16-5
Chemical Name
6-AMINO-1,3-BENZODIOXOLE-5-CARBOXYLIC ACID
Synonyms
1,3-Benzodioxole-5-carboxylicacid, 6-aMino-;6-AMinobenzo[d][1,3]dioxole-5-carboxylic acid
CBNumber
CB01491146
Molecular Formula
C8H7NO4
Formula Weight
181.15
MOL File
20332-16-5.mol
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6-AMINO-1,3-BENZODIOXOLE-5-CARBOXYLIC ACID Property

Melting point:
176-178 °C
Boiling point:
387.9±42.0 °C(Predicted)
Density 
1.569±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
pka
2.35±0.20(Predicted)
Appearance
Yellow to brown Solid
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
A637663
Product name
6-Aminobenzo[d][1,3]dioxole-5-carboxylicacid
Packaging
50mg
Price
$90
Updated
2021/12/16
TRC
Product number
A637663
Product name
6-Aminobenzo[d][1,3]dioxole-5-carboxylicacid
Packaging
5mg
Price
$45
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0117892
Product name
6-AMINO-BENZO[1,3]DIOXOLE-5-CARBOXYLIC ACID
Purity
95.00%
Packaging
1G
Price
$925.31
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0117892
Product name
6-AMINO-BENZO[1,3]DIOXOLE-5-CARBOXYLIC ACID
Purity
95.00%
Packaging
2.5G
Price
$1363.65
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0117892
Product name
6-AMINO-BENZO[1,3]DIOXOLE-5-CARBOXYLIC ACID
Purity
95.00%
Packaging
5G
Price
$1759.28
Updated
2021/12/16
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6-AMINO-1,3-BENZODIOXOLE-5-CARBOXYLIC ACID Chemical Properties,Usage,Production

Synthesis

40680-63-5

20332-16-5

General procedure for the synthesis of 6-aminobenzo[d][1,3]dioxole-5-carboxylic acid from methyl 6-aminobenzo[d][1,3]dioxole-5-carboxylate: Sodium hydroxide (2.95 g, 73.8 mmol) was added to water (75 mL), and stirred until completely dissolved. Methyl 6-aminobenzo[d][1,3]dioxole-5-carboxylate (12.0 g, 61.5 mmol) was then added and the reaction mixture was heated to 90°C and stirred for 2 hours. After completion of the reaction, the reaction mixture was cooled with ice water and the pH was adjusted to 2 with concentrated hydrochloric acid to precipitate a solid. The mixture was stirred thoroughly and filtered, the filter cake was washed with water and dried to give 6-aminobenzo[d][1,3]dioxole-5-carboxylic acid (7.2 g, 65% yield).

References

[1] Patent: CN104557955, 2017, B. Location in patent: Paragraph 0152; 0156

6-AMINO-1,3-BENZODIOXOLE-5-CARBOXYLIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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6-AMINO-1,3-BENZODIOXOLE-5-CARBOXYLIC ACID Suppliers

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20332-16-5, 6-AMINO-1,3-BENZODIOXOLE-5-CARBOXYLIC ACIDRelated Search:


  • 6-AMinobenzo[d][1,3]dioxole-5-carboxylic acid
  • 1,3-Benzodioxole-5-carboxylicacid, 6-aMino-
  • 20332-16-5