(2-fluoro-4-nitrophenyl)methanol
- Product Name
- (2-fluoro-4-nitrophenyl)methanol
- CAS No.
- 660432-43-9
- Chemical Name
- (2-fluoro-4-nitrophenyl)methanol
- Synonyms
- 2-Fluoro-4-nitrobenzylalcohol97%;(2-fluoro-4-nitrophenyl)methanol;Benzenemethanol, 2-fluoro-4-nitro-;2-Fluoro-4-nitrobenzyl alcohol 97%;2-Fluoro-4-nitrobenzyl alcohol, 97%;3-Fluoro-4-(hydroxymethyl)nitrobenzene, (2-Fluoro-4-nitrophenyl)methanol
- CBNumber
- CB01553783
- Molecular Formula
- C7H6FNO3
- Formula Weight
- 171.13
- MOL File
- 660432-43-9.mol
(2-fluoro-4-nitrophenyl)methanol Property
- Melting point:
- 103-105℃
- Boiling point:
- 319.9±27.0 °C(Predicted)
- Density
- 1.434±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- pka
- 13.14±0.10(Predicted)
- form
- Solid
- color
- White to yellow
- CAS DataBase Reference
- 660432-43-9
Safety
- HazardClass
- IRRITANT
- HS Code
- 2906290090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- B440635
- Product name
- (2-fluoro-4-nitrophenyl)methanol
- Packaging
- 50mg
- Price
- $65
- Updated
- 2021/12/16
- Product number
- PC57032
- Product name
- 2-Fluoro-4-nitrobenzylalcohol
- Purity
- 97%
- Packaging
- 250mg
- Price
- $35
- Updated
- 2021/12/16
- Product number
- 4654-3-W1
- Product name
- 2-Fluoro-4-nitrobenzyl alcohol
- Packaging
- 250mg
- Price
- $44
- Updated
- 2021/12/16
- Product number
- 066800
- Product name
- (2-Fluoro-4-nitrophenyl)methanol
- Purity
- >95%
- Packaging
- 500mg
- Price
- $102
- Updated
- 2021/12/16
- Product number
- PC57032
- Product name
- 2-Fluoro-4-nitrobenzylalcohol
- Purity
- 97%
- Packaging
- 1g
- Price
- $109
- Updated
- 2021/12/16
(2-fluoro-4-nitrophenyl)methanol Chemical Properties,Usage,Production
Synthesis
157701-72-9
660432-43-9
General procedure for the synthesis of 2-fluoro-4-nitrobenzyl alcohol from 2-fluoro-4-nitrobenzaldehyde: To a solution of 2-fluoro-4-nitrobenzaldehyde (1.0 g, 5.92 mmol) in methanol (10 mL) was slowly added sodium borohydride (814 mg, 22 mmol). The reaction mixture was stirred at room temperature for 15 min and then concentrated by rotary evaporator. The concentrated residue was subjected to liquid-liquid partitioning with ethyl acetate (100 mL) and saturated aqueous sodium chloride solution (100 mL). The combined organic phases were washed with saturated aqueous sodium chloride solution (100 mL x 2) and dried with anhydrous sodium sulfate. After filtration, the filtrate was concentrated to give the red solid product 2-fluoro-4-nitrobenzyl alcohol (1.0 g, 99% yield).
References
[1] Patent: TWI602818, 2017, B. Location in patent: Paragraph 0481; 0482
[2] Patent: WO2014/173289, 2014, A1. Location in patent: Paragraph 0479; 0481; 0482
(2-fluoro-4-nitrophenyl)methanol Preparation Products And Raw materials
Raw materials
Preparation Products
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