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(2-fluoro-4-nitrophenyl)methanol

Product Name
(2-fluoro-4-nitrophenyl)methanol
CAS No.
660432-43-9
Chemical Name
(2-fluoro-4-nitrophenyl)methanol
Synonyms
2-Fluoro-4-nitrobenzylalcohol97%;(2-fluoro-4-nitrophenyl)methanol;Benzenemethanol, 2-fluoro-4-nitro-;2-Fluoro-4-nitrobenzyl alcohol 97%;2-Fluoro-4-nitrobenzyl alcohol, 97%;3-Fluoro-4-(hydroxymethyl)nitrobenzene, (2-Fluoro-4-nitrophenyl)methanol
CBNumber
CB01553783
Molecular Formula
C7H6FNO3
Formula Weight
171.13
MOL File
660432-43-9.mol
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(2-fluoro-4-nitrophenyl)methanol Property

Melting point:
103-105℃
Boiling point:
319.9±27.0 °C(Predicted)
Density 
1.434±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
pka
13.14±0.10(Predicted)
form 
Solid
color 
White to yellow
CAS DataBase Reference
660432-43-9
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Safety

HazardClass 
IRRITANT
HS Code 
2906290090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC
Product number
B440635
Product name
(2-fluoro-4-nitrophenyl)methanol
Packaging
50mg
Price
$65
Updated
2021/12/16
Apolloscientific
Product number
PC57032
Product name
2-Fluoro-4-nitrobenzylalcohol
Purity
97%
Packaging
250mg
Price
$35
Updated
2021/12/16
SynQuest Laboratories
Product number
4654-3-W1
Product name
2-Fluoro-4-nitrobenzyl alcohol
Packaging
250mg
Price
$44
Updated
2021/12/16
Matrix Scientific
Product number
066800
Product name
(2-Fluoro-4-nitrophenyl)methanol
Purity
>95%
Packaging
500mg
Price
$102
Updated
2021/12/16
Apolloscientific
Product number
PC57032
Product name
2-Fluoro-4-nitrobenzylalcohol
Purity
97%
Packaging
1g
Price
$109
Updated
2021/12/16
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(2-fluoro-4-nitrophenyl)methanol Chemical Properties,Usage,Production

Synthesis

157701-72-9

660432-43-9

General procedure for the synthesis of 2-fluoro-4-nitrobenzyl alcohol from 2-fluoro-4-nitrobenzaldehyde: To a solution of 2-fluoro-4-nitrobenzaldehyde (1.0 g, 5.92 mmol) in methanol (10 mL) was slowly added sodium borohydride (814 mg, 22 mmol). The reaction mixture was stirred at room temperature for 15 min and then concentrated by rotary evaporator. The concentrated residue was subjected to liquid-liquid partitioning with ethyl acetate (100 mL) and saturated aqueous sodium chloride solution (100 mL). The combined organic phases were washed with saturated aqueous sodium chloride solution (100 mL x 2) and dried with anhydrous sodium sulfate. After filtration, the filtrate was concentrated to give the red solid product 2-fluoro-4-nitrobenzyl alcohol (1.0 g, 99% yield).

References

[1] Patent: TWI602818, 2017, B. Location in patent: Paragraph 0481; 0482
[2] Patent: WO2014/173289, 2014, A1. Location in patent: Paragraph 0479; 0481; 0482

(2-fluoro-4-nitrophenyl)methanol Preparation Products And Raw materials

Raw materials

Preparation Products

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(2-fluoro-4-nitrophenyl)methanol Suppliers

Alfa Aesar
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660432-43-9, (2-fluoro-4-nitrophenyl)methanolRelated Search:


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