ChemicalBook > CAS DataBase List > methyl 3-(2-bromophenyl)propanoate

methyl 3-(2-bromophenyl)propanoate

Product Name
methyl 3-(2-bromophenyl)propanoate
CAS No.
66191-86-4
Chemical Name
methyl 3-(2-bromophenyl)propanoate
Synonyms
O-broMophenolMethyl propionate;Methyl 3-(2-bromophenyl)propionate;methyl 3-(2-bromophenyl)propanoate;Methyl3-(2-bromophenyl)propionate,98%;Methyl 3-(2-Bromophenyl)propionate >3-(2-bromophenyl)propanoic acid methyl ester;3-(2-Bromophenyl)propionic Acid Methyl Ester;Benzenepropanoic acid, 2-bromo-, methyl ester
CBNumber
CB01563913
Molecular Formula
C10H11BrO2
Formula Weight
243.1
MOL File
66191-86-4.mol
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methyl 3-(2-bromophenyl)propanoate Property

Boiling point:
87℃/0.02Torr
Density 
1.389±0.06 g/cm3(Predicted)
refractive index 
1.5380 to 1.5420
storage temp. 
Sealed in dry,Room Temperature
form 
Liquid
color 
Colorless to pale yellow
CAS DataBase Reference
66191-86-4
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Safety

HS Code 
2916399090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
M2587
Product name
Methyl 3-(2-Bromophenyl)propionate
Purity
>98.0%(GC)
Packaging
1g
Price
$30
Updated
2025/07/31
TCI Chemical
Product number
M2587
Product name
Methyl 3-(2-Bromophenyl)propionate
Purity
>98.0%(GC)
Packaging
5g
Price
$118
Updated
2025/07/31
TRC
Product number
M296543
Product name
Methyl3-(2-Bromophenyl)propanoate
Packaging
50mg
Price
$45
Updated
2021/12/16
TRC
Product number
M296543
Product name
Methyl3-(2-Bromophenyl)propanoate
Packaging
100mg
Price
$60
Updated
2021/12/16
TRC
Product number
M296543
Product name
Methyl3-(2-Bromophenyl)propanoate
Packaging
500mg
Price
$75
Updated
2021/12/16
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methyl 3-(2-bromophenyl)propanoate Chemical Properties,Usage,Production

Synthesis

67-56-1

15115-58-9

66191-86-4

To a stirred solution of 3-(2-bromophenyl)propionic acid (7.7 g, 33.6 mmol) in methanol (60 mL) at room temperature was added thionyl chloride (0.9 mL, 12 mmol) dropwise. The reaction mixture was heated to reflux for 1 hour. Subsequently, additional thionyl chloride (0.9 mL each, total 24 mmol) was added in two additions under reflux conditions, the second addition following the complete reaction of the first. After continuing the reflux reaction for 2 h, the volatile components were removed by distillation under reduced pressure (70 °C, 0.8 kPa). The light yellow oily residue obtained was dissolved in dichloromethane (60 mL) and washed with saturated aqueous sodium bicarbonate (60 mL). The organic layer was dried over anhydrous sodium sulfate, filtered, and concentrated under reduced pressure to afford methyl o-bromophenylpropionate (7.8 g, 96% yield) as a yellow oily liquid. The proton NMR spectral data of the product were in agreement with those reported in the literature [10].

References

[1] Angewandte Chemie - International Edition, 2016, vol. 55, # 51, p. 15797 - 15801
[2] Angew. Chem., 2016, vol. 128, p. 16029 - 16033,5
[3] Beilstein Journal of Organic Chemistry, 2015, vol. 11, p. 884 - 892
[4] Journal of Heterocyclic Chemistry, 2018, vol. 55, # 3, p. 670 - 684
[5] Tetrahedron, 2013, vol. 69, # 36, p. 7618 - 7626

methyl 3-(2-bromophenyl)propanoate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from methyl 3-(2-bromophenyl)propanoate manufacturers

Career Henan Chemical Co
Product
methyl 3-(2-bromophenyl)propanoate 66191-86-4
Price
US $1.00/ASSAYS
Min. Order
1ASSAYS
Purity
85.0-99.8%
Supply Ability
20tons
Release date
2020-01-08

66191-86-4, methyl 3-(2-bromophenyl)propanoateRelated Search:

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  • methyl 3-(2-bromophenyl)propanoate
  • Methyl 3-(2-bromophenyl)propionate
  • O-broMophenolMethyl propionate
  • 3-(2-bromophenyl)propanoic acid methyl ester
  • Methyl 3-(2-Bromophenyl)propionate &gt
  • Benzenepropanoic acid, 2-bromo-, methyl ester
  • Methyl3-(2-bromophenyl)propionate,98%
  • 3-(2-Bromophenyl)propionic Acid Methyl Ester
  • 66191-86-4