ChemicalBook > CAS DataBase List > ETHYL 5-AMINO-1-TERT-BUTYLPYRAZOLE-4-CARBOXYLATE

ETHYL 5-AMINO-1-TERT-BUTYLPYRAZOLE-4-CARBOXYLATE

Product Name
ETHYL 5-AMINO-1-TERT-BUTYLPYRAZOLE-4-CARBOXYLATE
CAS No.
112779-14-3
Chemical Name
ETHYL 5-AMINO-1-TERT-BUTYLPYRAZOLE-4-CARBOXYLATE
Synonyms
BUTTPARK 87\09-30;-1H-pyrazole-4-carboxylate;Ethyl 5-amino-1-(tert-butyl);ETHYL 5-AMINO-1-TERT-BUTYLPYRAZOLE-4-CARBOXYLATE;1-(tert-butyl)-5-amino-pyrazole-4-carboxylic acid ethyl ester;1H-Pyrazole-4-carboxylic acid, 5-amino-1-(1,1-dimethylethyl)-, ethyl ester
CBNumber
CB0166599
Molecular Formula
C10H17N3O2
Formula Weight
211.26
MOL File
112779-14-3.mol
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ETHYL 5-AMINO-1-TERT-BUTYLPYRAZOLE-4-CARBOXYLATE Property

Boiling point:
110 °C(Press: 0.1 Torr)
Density 
1.15±0.1 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
pka
2.09±0.10(Predicted)
Appearance
Light yellow to brown Liquid
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
E899193
Product name
Ethyl5-Amino-1-tert-butylpyrazole-4-carboxylate
Packaging
250mg
Price
$75
Updated
2021/12/16
ChemScene
Product number
CS-0035629
Product name
Ethyl5-amino-1-tert-butylpyrazole-4-carboxylate
Packaging
1g
Price
$195
Updated
2021/12/16
AK Scientific
Product number
C004
Product name
Ethyl5-amino-1-tert-butylpyrazole-4-carboxylate
Packaging
5g
Price
$380
Updated
2021/12/16
ChemScene
Product number
CS-0035629
Product name
Ethyl5-amino-1-tert-butylpyrazole-4-carboxylate
Packaging
5g
Price
$585
Updated
2021/12/16
AK Scientific
Product number
C004
Product name
Ethyl5-amino-1-tert-butylpyrazole-4-carboxylate
Packaging
10g
Price
$600
Updated
2021/12/16
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ETHYL 5-AMINO-1-TERT-BUTYLPYRAZOLE-4-CARBOXYLATE Chemical Properties,Usage,Production

Synthesis

7400-27-3

94-05-3

112779-14-3

Step 1. A mixture of tert-butylhydrazine hydrochloride (10 g, 80.3 mmol), ethyl ethoxymethoxycarbonylcyanoacetate (13.6 g, 80.4 mmol), and anhydrous sodium acetate (8.2 g, 100 mmol) was stirred and reacted at reflux for 16 hours in 100 mL of ethanol. After completion of the reaction, the reaction solution was poured into ice water. The aqueous phase was extracted three times with dichloromethane and the organic phases were combined. The organic phase was washed sequentially with water and saturated brine solution and then dried with anhydrous sodium sulfate. The solvent was removed by distillation under reduced pressure to give ethyl 5-amino-1-tert-butyl-1H-pyrazole-4-carboxylate (13 g, 77% yield).

References

[1] Patent: US2007/225280, 2007, A1. Location in patent: Page/Page column 19

ETHYL 5-AMINO-1-TERT-BUTYLPYRAZOLE-4-CARBOXYLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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ETHYL 5-AMINO-1-TERT-BUTYLPYRAZOLE-4-CARBOXYLATE Suppliers

TAIYUAN RHF CO.,LTD.
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+86 351 7031519
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sales@RHFChem.com
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Shanghai YuLue Chemical Co., Ltd.
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View Lastest Price from ETHYL 5-AMINO-1-TERT-BUTYLPYRAZOLE-4-CARBOXYLATE manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
ETHYL5-AMINO-1-TERT-BUTYL-1H-PYRAZOLE-4-CARBOXYLATE 112779-14-3
Price
US $3.00-9.00/KG
Min. Order
0.1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2025-06-26

112779-14-3, ETHYL 5-AMINO-1-TERT-BUTYLPYRAZOLE-4-CARBOXYLATERelated Search:


  • ETHYL 5-AMINO-1-TERT-BUTYLPYRAZOLE-4-CARBOXYLATE
  • BUTTPARK 87\09-30
  • -1H-pyrazole-4-carboxylate
  • Ethyl 5-amino-1-(tert-butyl)
  • 1H-Pyrazole-4-carboxylic acid, 5-amino-1-(1,1-dimethylethyl)-, ethyl ester
  • 1-(tert-butyl)-5-amino-pyrazole-4-carboxylic acid ethyl ester
  • 112779-14-3