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ChemicalBook > CAS DataBase List > 4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE

4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE

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Product Name
4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE
CAS No.
261733-18-0
Chemical Name
4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE
Synonyms
NIXANTPHOS;N-XantPhos;4,6-BIS(DIPHENYLPHOSPHINO)-10H-PHENOXAZINE;N-XantPhos 97%;98% NixantPhos;4,6-Bis(diphenyL;phosphino)phenoxazine;phosphino)phenoxazine NIXANTPHOS;4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE;N-XantPhos / 4,6-Bis(diphenylphosphin
CBNumber
CB0188382
Molecular Formula
C36H27NOP2
Formula Weight
551.55
MOL File
261733-18-0.mol
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4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE Property

Melting point:
256-262 °C
Boiling point:
662.1±55.0 °C(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
pka
1.34±0.20(Predicted)
form 
Powder
color 
white to off-white
Water Solubility 
Miscible with water.
InChIKey
HSWZLYXRAOXOLL-UHFFFAOYSA-N
CAS DataBase Reference
261733-18-0
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Safety

Risk Statements 
36/37/38
Safety Statements 
22-24/25
WGK Germany 
3
TSCA 
No
HS Code 
2934.99.4400
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
666564
Product name
4,6-Bis(diphenylphosphino)phenoxazine
Purity
97%
Packaging
500mg
Price
$123
Updated
2024/03/01
Sigma-Aldrich
Product number
666564
Product name
4,6-Bis(diphenylphosphino)phenoxazine
Purity
97%
Packaging
1g
Price
$207
Updated
2024/03/01
TCI Chemical
Product number
B2717
Product name
4,6-Bis(diphenylphosphino)phenoxazine
Purity
>98.0%(HPLC)(N)
Packaging
1g
Price
$239
Updated
2024/03/01
TCI Chemical
Product number
B2717
Product name
4,6-Bis(diphenylphosphino)phenoxazine
Purity
>98.0%(HPLC)(N)
Packaging
100mg
Price
$43
Updated
2024/03/01
Alfa Aesar
Product number
H27330
Product name
4,6-Bis(diphenylphosphino)phenoxazine, 98+%
Packaging
1g
Price
$198
Updated
2024/03/01
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4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE Chemical Properties,Usage,Production

Reactions

  1. A large bite-angle chelating bisphosphine that provides high levels of linear-to-branched selectivity in the hydroformylation of alkenes.
  2. A Deprotonatable Ligand for Room-Temperature Palladium-Catalyzed Cross-Couplings of Aryl Chlorides.

Uses

4,6-Bis(diphenylphosphino)phenoxazine used as an intermediate in the manufacture of pharmaceuticals, agrochemicals, dyestuffs, fine chemicals, medical and material synthesis.

Uses

N-XantPhos is a deprotonatable chelating aryldiphosphine ligand that can be used in:

  • The preparation of Pd-NiXantphos catalyst system for the room temperature cross-coupling reactions of unactivated aryl chlorides.
  • The synthesis of cinchonine iridium(III) cyclometalated complex that exhibits luminescence and good quantum efficiency.
  • N-XantPhos and N-modified counterparts are also used in the preparation of rhodium based catalysts for hydroformylation reaction.

Uses

4,6-Bis(Diphenylphosphino)phenoxazine is used as a palladium catalyst in reactions involving the synthesis of triarylmethanes.

4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE Preparation Products And Raw materials

Raw materials

Preparation Products

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4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE Suppliers

SIGMA-RBI
Tel
--
Fax
--
Country
Switzerland
ProdList
6896
Advantage
91
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View Lastest Price from 4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE 261733-18-0
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2022-11-01
Shaanxi Dideu Medichem Co. Ltd
Product
4,6-Bis(diphenylphosphino)phenoxazine 261733-18-0
Price
US $1.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 tons
Release date
2020-01-16
Hebei Mojin Biotechnology Co., Ltd
Product
4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE 261733-18-0
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-08-18

261733-18-0, 4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINERelated Search:


  • 4,6-Bis(diphenylphosphino)phenoxazine 97%
  • N-XantPhos 97%
  • 4,6-Bis(diphenylphosphino)phenoxazine, min. 98%
  • NIXANTPHOS
  • 4,6-BIS(DIPHENYLPHOSPHINO)-10H-PHENOXAZINE
  • 4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE
  • 4,6-Bis(diphenylphosphino)phenoxazine, NIXANTPHOS
  • 4,6-Bis(diphenylphosphino)phenoxazine,min.98%NIXANTPHOS
  • 4,6-Bis(diphenylphosphino)phenoxazine, 98+%
  • (6-diphenylphosphanyl-10H-phenoxazin-4-yl)-diphenylphosphane
  • 4,6-bis(diphenylphosphanyl)-10H-phenoxazine
  • 4,6-Bis(diphenylphosphino)-10H- phenoxazine (NixantPhos)
  • N-XantPhos / 4,6-Bis(diphenylphosphino)-10H-phenoxazine
  • 4,6-Bis(diphenylphosphino)phenoxazine, 98+% NIXANTPHOS
  • 98% NixantPhos
  • N-XantPhos
  • 4,6-Bis(diphenylphosphino)phenoxazine &gt
  • phosphino)phenoxazine NIXANTPHOS
  • 4,6-Bis(diphenyL
  • 10H-Phenoxazine, 4,6-bis(diphenylphosphino)-
  • phosphino)phenoxazine
  • N-XantPhos / 4,6-Bis(diphenylphosphin
  • 4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE (N-Xantphos)
  • 4,6-bis (diphenylphosphine) phenazine
  • 261733-18-0
  • C36H27NOP2
  • C6H32NOPC6H522
  • Phosphorus Compounds
  • Polydentate Phosphine Ligands
  • Catalysis and Inorganic Chemistry
  • Achiral Phosphine
  • Aryl Phosphine
  • Phosphine Ligands
  • Synthetic Organic Chemistry
  • organophosphine ligand