ChemicalBook > CAS DataBase List > 4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE
4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE
Reactions- Product Name
- 4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE
- CAS No.
- 261733-18-0
- Chemical Name
- 4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE
- Synonyms
- NIXANTPHOS;N-XantPhos;4,6-BIS(DIPHENYLPHOSPHINO)-10H-PHENOXAZINE;N-XantPhos 97%;98% NixantPhos;CAS:261733-18-0;4,6-Bis(diphenyL;N-XantPhos;phosphino)phenoxazine;phosphino)phenoxazine NIXANTPHOS
- CBNumber
- CB0188382
- Molecular Formula
- C36H27NOP2
- Formula Weight
- 551.55
- MOL File
- 261733-18-0.mol
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4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE Property
- Melting point:
- 256-262 °C
- Boiling point:
- 662.1±55.0 °C(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- pka
- 1.34±0.20(Predicted)
- form
- Powder
- color
- white to off-white
- Water Solubility
- Miscible with water.
- InChIKey
- HSWZLYXRAOXOLL-UHFFFAOYSA-N
- SMILES
- C1=C2C(OC3=C(N2)C=CC=C3P(C2=CC=CC=C2)C2=CC=CC=C2)=C(P(C2=CC=CC=C2)C2=CC=CC=C2)C=C1
- CAS DataBase Reference
- 261733-18-0
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 666564
- Product name
- 4,6-Bis(diphenylphosphino)phenoxazine
- Purity
- 97%
- Packaging
- 500mg
- Price
- $127
- Updated
- 2025/07/31
Sigma-Aldrich
- Product number
- 666564
- Product name
- 4,6-Bis(diphenylphosphino)phenoxazine
- Purity
- 97%
- Packaging
- 1g
- Price
- $213
- Updated
- 2025/07/31
TCI Chemical
- Product number
- B2717
- Product name
- 4,6-Bis(diphenylphosphino)phenoxazine
- Purity
- >98.0%(HPLC)(N)
- Packaging
- 1g
- Price
- $247
- Updated
- 2025/07/31
TCI Chemical
- Product number
- B2717
- Product name
- 4,6-Bis(diphenylphosphino)phenoxazine
- Purity
- >98.0%(HPLC)(N)
- Packaging
- 100mg
- Price
- $44
- Updated
- 2025/07/31
Strem Chemicals
- Product number
- 15-0437
- Product name
- 4,6-Bis(diphenylphosphino)phenoxazine, min. 98% NIXANTPHOS
- Packaging
- 500mg
- Price
- $103
- Updated
- 2024/03/01
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4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE Chemical Properties,Usage,Production
Reactions
- A large bite-angle chelating bisphosphine that provides high levels of linear-to-branched selectivity in the hydroformylation of alkenes.
- A Deprotonatable Ligand for Room-Temperature Palladium-Catalyzed Cross-Couplings of Aryl Chlorides.
Uses
4,6-Bis(diphenylphosphino)phenoxazine used as an intermediate in the manufacture of pharmaceuticals, agrochemicals, dyestuffs, fine chemicals, medical and material synthesis.
Uses
N-XantPhos is a deprotonatable chelating aryldiphosphine ligand that can be used in:
- The preparation of Pd-NiXantphos catalyst system for the room temperature cross-coupling reactions of unactivated aryl chlorides.
- The synthesis of cinchonine iridium(III) cyclometalated complex that exhibits luminescence and good quantum efficiency.
- N-XantPhos and N-modified counterparts are also used in the preparation of rhodium based catalysts for hydroformylation reaction.
Uses
4,6-Bis(Diphenylphosphino)phenoxazine is used as a palladium catalyst in reactions involving the synthesis of triarylmethanes.
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings
4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE Preparation Products And Raw materials
Raw materials
Preparation Products
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4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE Suppliers
- Tel
- --
- Fax
- --
- Country
- Switzerland
- ProdList
- 6896
- Advantage
- 91
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View Lastest Price from 4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE manufacturers
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
- Product
- 4,6-Bis(diphenylphosphino)-10H-phenoxazine 261733-18-0
- Price
- US $2.00-5.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2025-06-26
Hebei Zhuanglai Chemical Trading Co Ltd
- Product
- 4, 6-Bis (DIPHENYLPHOSPHINO) Phenoxazine 261733-18-0
- Price
- US $79.00-38.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20ton
- Release date
- 2024-12-25
Henan Aochuang Chemical Co.,Ltd.
- Product
- 4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE 261733-18-0
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-09-27
261733-18-0, 4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINERelated Search:
1.1'-Binaphthyl-2.2'-diphemyl phosphine
(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE)
Phenoxazine
(S)-(2-METHOXYPHENYL)METHYLPHENYLPHOSPHINE
P-ANISYLDIPHENYLPHOSPHINE
(R)-(2-METHOXYPHENYL)METHYLPHENYLPHOSPHINE
4,6-BIS(DIPHENYLPHOSPHINO)PHENOXAZINE