ChemicalBook > CAS DataBase List > 6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(T-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN
6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(T-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN
Reaction- Product Name
- 6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(T-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN
- CAS No.
- 149646-83-3
- Chemical Name
- 6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(T-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN
- Synonyms
- (R,R)-CHIRAPHITE;(2R,4R)-Chiraphite;6,6’-[(2R,4R)-Pentane-2,4-diylbis(oxy)]bis(4,8-di-tert-butyl-2,10-dimethoxydibenzo[d,f][1,3,2]dioxaphosphepine);6,6’-[(2R,4R)-Pentane-2,4-diylbis(oxy)]bis(4,8-di-tert-butyl-2,10-dimethoxydibenzo[d,f][1,3,2]dioxaphosphepine);6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(T-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN;(+)-6,6-([(1R,3R)-1,3-Dimethyl-1,3-propanediyl]bis(oxy)}bis[4,8-bis(t-butyl)-2,10-dimethoxy-bibenzo[d,f][1,3,2]dioxaphosphepin];(+)-6,6'-([(1R,3R)-1,3-Dimethyl-1,3-propanediyl]bis(oxy)}bis[4,8-bis(t-butyl)-2,10-dimethoxy-bibenzo[d,f][1,3,2]dioxaphosphepin;(+)-6,6'-{[(1r,3r)-1,3-dimethyl-1,3-propanediyl]bis(oxy)}bis[4,8-bis(t-butyl)-2,10-dimethoxy-bibenzo[d,f][1,3,2]dioxaphosphepin;(+)-6,6''-{[(1R,3R)-1,3-Dimethyl-1,3-propanediyl]bis(oxy)}bis[4,8-bis(t-butyl)-2,10-dimethoxy-bibenzo[d,f][1,3,2]dioxaphosphepin];Dibenzo[d,f][1,3,2]dioxaphosphepin, 6,6'-[[(1R,3R)-1,3-dimethyl-1,3-propanediyl]bis(oxy)]bis[4,8-bis(1,1-dimethylethyl)-2,10-dimethoxy-
- CBNumber
- CB0188953
- Molecular Formula
- C49H66O10P2
- Formula Weight
- 876.99
- MOL File
- 149646-83-3.mol
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6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(T-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN Property
- alpha
- +35.4° (c 1.0, CH2Cl2)
- Boiling point:
- 816.6±65.0 °C(Predicted)
- form
- Powder
- color
- off-white
- Sensitive
- air sensitive, moisture sensitive
- CAS DataBase Reference
- 149646-83-3
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Safety
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
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N-Bromosuccinimide Price
Strem Chemicals
- Product number
- 15-1455
- Product name
- (+)-6,6'-{[(1R,3R)-1,3-Dimethyl-1,3-propanediyl]bis(oxy)}bis[4,8-bis(t-butyl)-2,10-dimethoxy-bibenzo[d,f][1,3,2]dioxaphosphepin], min. 95% (R,R)-Chiraphite
- Packaging
- 100mg
- Price
- $102
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1455
- Product name
- (+)-6,6'-{[(1R,3R)-1,3-Dimethyl-1,3-propanediyl]bis(oxy)}bis[4,8-bis(t-butyl)-2,10-dimethoxy-bibenzo[d,f][1,3,2]dioxaphosphepin], min. 95% (R,R)-Chiraphite
- Packaging
- 500mg
- Price
- $412
- Updated
- 2024/03/01
American Custom Chemicals Corporation
- Product number
- ING0001105
- Product name
- (+)-6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(TERT-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN
- Purity
- 95.00%
- Packaging
- 100MG
- Price
- $625.78
- Updated
- 2021/12/16
American Custom Chemicals Corporation
- Product number
- ING0001105
- Product name
- (+)-6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(TERT-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN
- Purity
- 95.00%
- Packaging
- 500MG
- Price
- $865.9
- Updated
- 2021/12/16
BLDpharm
- Product number
- BD635816
- Product name
- (+)-6,6'-{[(1R,3R)-1,3-Dimethyl-1,3-propanediyl]bis(oxy)}bis[4,8-bis(t-butyl)-2,10-dimethoxy-bibenzo[d,f][1,3,2]dioxaphosphepin]
- Purity
- 98%
- Packaging
- 50mg
- Price
- $107
- Updated
- 2021/12/16
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6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(T-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN Chemical Properties,Usage,Production
Reaction
Useful catalyst for the asymmetric hydroformylation of olefins under mild conditions. High enantioand regioselectivities have been demonstrated for several prochiral vinylarenes, and a wide variety of functional groups can be tolerated.
6,6'-[[(1R,3R)-1,3-DIMETHYL-1,3-PROPANEDIYL]BIS(OXY)]BIS[4,8-BIS(T-BUTYL)-2,10-DIMETHOXY-BIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN Preparation Products And Raw materials
Raw materials
Preparation Products
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