ChemicalBook > CAS DataBase List > Damascenone

Damascenone

Product Name
Damascenone
CAS No.
23696-85-7
Chemical Name
Damascenone
Synonyms
β-Damascenone;2-Buten-1-one, 1-(2,6,6-trimethyl-1,3-cyclohexadien-1-yl)-;DAMASCENONE TOTAL;4-(2,6,6-Trimethyl cyclohexa-1,3-dienyl)but-2-en-4-one;1-(2,6,6-trimethyl-1,3-cyclohexadien-1-yl)-2-Buten-1-one;(E)-1-(2,6,6-triMethylcyclohexa-1,3-dien-1-yl)but-2-en-1-one;FEMA 3420;Damasione;DAMASCENON;Trimethyl cyclohexadienyl butenone
CBNumber
CB0203140
Molecular Formula
C13H18O
Formula Weight
190.28
MOL File
23696-85-7.mol
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Damascenone Property

Boiling point:
275.6±10.0 °C(Predicted)
Density 
0.800-0.830 g/mL at 25 °C (lit.)
refractive index 
1.350-1.380
FEMA 
3420 | 1-(2,6,6-TRIMETHYLCYCLOHEXA-1,3-DIENYL)-2-BUTEN-1-ONE
Flash point:
62°F
storage temp. 
2-8°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
liquid
color 
yellow
Odor
at 10.00 % in dipropylene glycol. natural sweet fruity rose plum grape raspberry sugar
Odor Type
floral
JECFA Number
387
Stability:
Light Sensitive
LogP
4.04
CAS DataBase Reference
23696-85-7(CAS DataBase Reference)
NIST Chemistry Reference
2-Buten-1-one, 1-(2,6,6-trimethyl-1,3-cyclohexadien-1-yl)-(23696-85-7)
EPA Substance Registry System
2-Buten-1-one, 1-(2,6,6-trimethyl-1,3-cyclohexadien-1-yl)- (23696-85-7)
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Safety

Hazard Codes 
F,Xi
Risk Statements 
11-43
Safety Statements 
7-16-36/37
RIDADR 
UN 1170
WGK Germany 
3
HS Code 
33021090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H317May cause an allergic skin reaction

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W342017
Product name
Damascenone
Purity
natural, 1.1-1.4 wt. % (190 proof ethanol), FG
Packaging
sample-k
Price
$58.5
Updated
2024/03/01
Sigma-Aldrich
Product number
W342017
Product name
Damascenone
Purity
natural, 1.1-1.4?wt. % (190 proof ethanol), FG
Packaging
25g
Price
$184
Updated
2024/03/01
Sigma-Aldrich
Product number
W342017
Product name
Damascenone
Purity
natural, 1.1-1.4?wt. % (190 proof ethanol), FG
Packaging
100g
Price
$459
Updated
2024/03/01
Sigma-Aldrich
Product number
W342017
Product name
Damascenone
Purity
natural, 1.1-1.4?wt. % (190 proof ethanol), FG
Packaging
1kg
Price
$2420
Updated
2024/03/01
Sigma-Aldrich
Product number
41163
Product name
Damascenone
Purity
analytical standard
Packaging
250mg
Price
$82.2
Updated
2024/03/01
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Damascenone Chemical Properties,Usage,Production

Occurrence

Reported found in raspberry oil, Burley tobacco, apple, lemon balm, summer savory, anise, hyssop, apple juice, cooked apple, apricot, sweet and sour cherry, black currant berries, fresh blackberry, strawberry jam, hop oil rum, white wine, red wine, black tea, tomato, rye bread, blue cheese, cow, goat and sheep milk, hop oil, beer, cognac, rum, whiskies, scotch, cider, grape wines, coffee, tea, popcorn, oatmeal, soybean, plum, prune, beans, starfruit, mango, tamarind, dill seed, corn oil, okra, cape gooseberry, anise hyssop and Roman chamomile oil.

Uses

Damascenone is a fragrance ingredient that can be used in shampoos, fine fragrances, decorative cosmetics, toilet soaps as well as non-cosmetic products like household cleaners and detergents.

Preparation

By treating the corresponding ethyl safranate with allyl lithium, followed by catalytic isomerization of the reaction product; also from the oxirane derivative of β-damascone by an acid-catalyzed reaction.

Definition

ChEBI: Beta-damascenone is a cyclic monoterpene ketone that is 2,6,6-trimethylcyclohexa-1,3-diene substituted at position 1 by a crotonoyl group. It has a role as a fragrance, a volatile oil component and a plant metabolite. It is an enone, an apo carotenoid monoterpenoid and a cyclic monoterpene ketone.

Aroma threshold values

Detection: 0.0007 to 0.009 ppb. Aroma characteristics at 1.0%: sweet, brown woody, tobacco, davana-like fruity, with a spicy balsamic undernote.

Taste threshold values

Taste characteristics at 1 to 5 ppm: sweet brown, tea-like, davana dried fruity, with jamy berry, strawberry and raspberry nuances, woody, floral, herbal, green and fruity with spicy tobacco nuances.

General Description

Damascenone is a norisoprenoid ketone mainly found in red wines. It occurs naturally in tomato and grapes.

Biochem/physiol Actions

Taste at 1-5 ppm

Damascenone Preparation Products And Raw materials

Raw materials

Mesityl oxide TRANS-1,3-PENTADIENE

Preparation Products

beta-Damascenone
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View Lastest Price from Damascenone manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Damascenone 23696-85-7
Price
US $0.00/Kg/Drum
Min. Order
1KG
Purity
98%min
Supply Ability
500KGS
Release date
2021-06-19
Shandong Deshang Chemical Co., Ltd.
Product
Damascenone 23696-85-7
Price
US $15.00-10.00/kg
Min. Order
1kg
Purity
99.99%
Supply Ability
10 tons
Release date
2024-06-19
Shandong Deshang Chemical Co., Ltd.
Product
Damascenone 23696-85-7
Price
US $5.90-3.20/kg
Min. Order
1kg
Purity
99%
Supply Ability
10 tons
Release date
2024-06-25

23696-85-7, DamascenoneRelated Search:

Tiglic aldehyde Cyclohexene Mesityl oxide 6-Methyl-5-hepten-2-one 2-Cyclohexen-1-one Phenylbutazone Methyl cyclopentenolone Trimethyl borate METHYLCYCLOHEXANONE Methyl vinyl ketone SAFRANAL 1,3-CYCLOHEXADIENE 1,4-HEXADIENE DAMASCONE METHYL CYCLOHEXADIENE 1-METHYL-1,3-CYCLOHEXADIENE 3,3-DIMETHYL-2-METHYLENE-BUTYRALDEHYDE Damascenone

  • DAMASCENONE
  • FEMA 3420
  • 4-(2,6,6-Trimethyl cyclohexa-1,3-dienyl)but-2-en-4-one
  • Trimethyl cyclohexadienyl butenone
  • 1-(2,6,6-trimethyl-1,3-cyclohexadien-1-yl)-2-buten-1-on
  • 1-(2,6,6-trimethyl-1,3-cyclohexadien-1-yl)-2-Buten-1-one
  • Damasione
  • 2-Buten-1-one, 1-(2,6,6-trimethyl-1,3-cyclohexadien-1-yl)-
  • DAMASCENON
  • DAMASCENONE TOTAL
  • 1-(2,6,6-Trimethyl-1,3-cyclohexadienyl)-2-butene-1-one
  • 1-(2,6,6-Trimethylcyclohexa-1,3-diene-1-yl)-2-butene-1-one
  • 1-(2-Butenoyl)-2,6,6-trimethyl-1,3-cyclohexadiene
  • 3,5,8-Megastigmatrien-7-one
  • Damascenone (natural)
  • Einecs 245-833-2
  • Fema no. 3420
  • (E)-1-(2,6,6-triMethylcyclohexa-1,3-dien-1-yl)but-2-en-1-one
  • 1-(2,6,6-Trimethylcyclohexa-1,3-dien-1-yl)-2-buten-1-one
  • β-Damascenone
  • Damascenone USP/EP/BP
  • DAMASCENONE1#,2#
  • Factory supply FEMA 3420 Damascenone cas 23696-85-7
  • Damacenone
  • (2E)-1-(2,6,6-trimethylcyclohexa-1,3-dienyl)but-2-en-1-one
  • Turkenone
  • Turkic peoples
  • 23696-85-7
  • 43952-87-5
  • C-D
  • Alphabetical Listings
  • Flavors and Fragrances