4,4'-Methylenebis(2,6-di-tert-butylphenol)
- Product Name
- 4,4'-Methylenebis(2,6-di-tert-butylphenol)
- CAS No.
- 118-82-1
- Chemical Name
- 4,4'-Methylenebis(2,6-di-tert-butylphenol)
- Synonyms
- e702;l3mb1;E 702;L 3MB1;lz-mb1;bimoxm;binoxm;etil702;LZ-MB 1;Bis-BHT
- CBNumber
- CB0206363
- Molecular Formula
- C29H44O2
- Formula Weight
- 424.66
- MOL File
- 118-82-1.mol
4,4'-Methylenebis(2,6-di-tert-butylphenol) Property
- Melting point:
- 155-159 °C(lit.)
- Boiling point:
- 289 °C40 mm Hg(lit.)
- Density
- 0.99 g/cm3 (20℃)
- vapor pressure
- 0Pa at 25℃
- refractive index
- 1.4875 (estimate)
- Flash point:
- 289°C/40mm
- storage temp.
- Store below +30°C.
- solubility
- <0.0001g/l
- pka
- 12.03±0.40(Predicted)
- form
- solid
- color
- White
- Water Solubility
- 31.9ng/L at 20℃
- BRN
- 1916919
- Stability:
- Stable for 2 years from date of purchase as supplied. Solutions are not stable. Solutions must be made fresh and used within 1 working day.
- InChIKey
- MDWVSAYEQPLWMX-UHFFFAOYSA-N
- LogP
- 8.9 at 25℃
- CAS DataBase Reference
- 118-82-1(CAS DataBase Reference)
- NIST Chemistry Reference
- Phenol, 4,4'-methylenebis[2,6-bis(1,1-dimethylethyl)-(118-82-1)
- EPA Substance Registry System
- Phenol, 4,4'-methylenebis[2,6-bis(1,1-dimethylethyl)- (118-82-1)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38-38-37-36
- Safety Statements
- 26-36
- WGK Germany
- 1
- RTECS
- SL9650000
- TSCA
- Yes
- HS Code
- 29072990
- Toxicity
- LD50 oral in rat: > 24gm/kg
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 8.42857
- Product name
- 4,4′-Methylenebis(2,6-di-tert-butylphenol)
- Purity
- for synthesis
- Packaging
- 10g
- Price
- $39.7
- Updated
- 2024/03/01
- Product number
- 8.42857
- Product name
- 4,4′-Methylenebis(2,6-di-tert-butylphenol)
- Purity
- for synthesis
- Packaging
- 100g
- Price
- $62
- Updated
- 2024/03/01
- Product number
- M0214
- Product name
- 4,4'-Methylenebis(2,6-di-tert-butylphenol)
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $29
- Updated
- 2024/03/01
- Product number
- M0214
- Product name
- 4,4'-Methylenebis(2,6-di-tert-butylphenol)
- Purity
- >98.0%(GC)
- Packaging
- 500g
- Price
- $131
- Updated
- 2024/03/01
- Product number
- A18910
- Product name
- 4,4'-Methylenebis(2,6-di-tert-butylphenol), 98%
- Packaging
- 50g
- Price
- $22.65
- Updated
- 2024/03/01
4,4'-Methylenebis(2,6-di-tert-butylphenol) Chemical Properties,Usage,Production
Description
bis-BHT (118-82-1) is a potent antioxidant. Cell permeable.
Chemical Properties
light yellow crystalline
Uses
Antioxidant.
Application
4,4'-Methylenebis(2,6-di-tert-butylphenol), also known as H2-4DBP, could be used as a ligand to react with sets of M(OR)x and MRx. The ligand possesses more flexibility than OBzP or catecholate derivatives, and the para-OH makes it of interest for controlled alcoholysis. This compound has several characteristics, including (i) the ortho position possesses the sterically hindering t-butyl group which will assist in minimizing oligomerization, (ii) the para linkage prevents chelation of the 4DBP ligand to the metal upon coordination, and (iii) may act as a valuable model for complexation behavior of the plastic precursor bisphenol-A [BPA; 4,4' -(propane-2,2-diyl)diphenol] that has become of recent concern[2].
Definition
ChEBI: 4,4'-Methylenebis(2,6-di-tert-butylphenol) is a diarylmethane.
Flammability and Explosibility
Non flammable
References
1) Amorati et al. (2003), Antioxidant activity of 0-bisphenols: the role of intramolecular hydrogen bonding; J. Org. Chem. 68 5198.
[2] T. Boyle, Daniel T Yonemoto, L. Steele. “Synthesis and characterization of 4,4′-methylenebis (2,6-di-tert-butylphenol) derivatives of a series of metal alkoxides and alkyls.” Journal of Coordination Chemistry 65.1(2012): 487–505.
4,4'-Methylenebis(2,6-di-tert-butylphenol) Preparation Products And Raw materials
Raw materials
Preparation Products
4,4'-Methylenebis(2,6-di-tert-butylphenol) Suppliers
- Tel
- 800-4238616
- Fax
- +1-888-520-1075 / +1-503-283-1987
- sales@tciamerica.com
- Country
- Americas
- ProdList
- 23653
- Advantage
- 75
View Lastest Price from 4,4'-Methylenebis(2,6-di-tert-butylphenol) manufacturers
- Product
- 4,4'-Methylenebis(2,6-di-tert-butylphenol) 118-82-1
- Price
- US $30.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 5000KG/Week
- Release date
- 2024-04-24
- Product
- 4,4'-Methylenebis(2,6-di-tert-butylphenol) 118-82-1
- Price
- US $60.00/kg
- Min. Order
- 1kg
- Purity
- 99
- Supply Ability
- 5000
- Release date
- 2024-05-11
- Product
- Antioxidant 702 118-82-1
- Price
- US $200.00-95.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20ton
- Release date
- 2024-04-24