Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II), min. 98% Property

storage temp. 

under inert gas (nitrogen or Argon) at 2-8°C

form 

solid

color 

red-black

Sensitive 

air sensitive, store cold

CAS DataBase Reference

863971-63-5

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

Carbonylhydrido[6-(di-t-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine]ruthenium(II), min. 98% Chemical Properties,Usage,Production

Reaction

1. Ruthenium catalyst for the direct synthesis of amides from alcohols and primary amines.
2. Ruthenium catalyst for the hydrogenation of esters in high yields under mild pressure and neutral conditions.
3. Ruthenium catalyst for the dehydrogenative coupling of alcohols to form esters in high yields under neutral conditions.
4. Ruthenium catalyst for the synthesis of amides from esters and amines with liberation of hydrogen gas.
5. Ruthenium catalyst for the hydrogenation of 3-methyl-2-oxalidinone