2,2'-Biquinoline
- Product Name
- 2,2'-Biquinoline
- CAS No.
- 119-91-5
- Chemical Name
- 2,2'-Biquinoline
- Synonyms
- CUPROIN;CUPROINE;CUPROIN R. G.;2,2'-Quinolyl;2,2'-BiquinoL;A,A -DIQUINOLYL;2,2'-DIQUINOLYL;2,2-BIQUINOLINE;2,2'-BIQUINOLYL;α,α'-Biquinolyl
- CBNumber
- CB0213789
- Molecular Formula
- C18H12N2
- Formula Weight
- 256.3
- MOL File
- 119-91-5.mol
2,2'-Biquinoline Property
- Melting point:
- 192-195 °C(lit.)
- Boiling point:
- 389.54°C (rough estimate)
- Density
- 0.9734 (rough estimate)
- refractive index
- 1.6300 (estimate)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- 1.02mg/l
- pka
- 2.19±0.61(Predicted)
- form
- Shiny Flakes
- color
- Slightly yellow to light beige
- Water Solubility
- Sparingly soluble in water (0.001g/L).
- BRN
- 187259
- InChIKey
- WPTCSQBWLUUYDV-UHFFFAOYSA-N
- CAS DataBase Reference
- 119-91-5(CAS DataBase Reference)
- NIST Chemistry Reference
- 2,2'-Biquinoline(119-91-5)
- EPA Substance Registry System
- 2,2'-Biquinoline (119-91-5)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36-37/39
- WGK Germany
- 3
- F
- 8
- TSCA
- Yes
- HS Code
- 29334990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- 35020
- Product name
- 2,2′-Biquinoline
- Purity
- for spectrophotometric det. of Cu, ≥99.0%
- Packaging
- 1g
- Price
- $48.3
- Updated
- 2022/05/15
- Product number
- 1.02955
- Product name
- 2,2′-Biquinoline
- Purity
- GR for analysis
- Packaging
- 5G
- Price
- $1040
- Updated
- 2022/05/15
- Product number
- B0470
- Product name
- 2,2'-Biquinoline
- Purity
- >98.0%(HPLC)(T)
- Packaging
- 1g
- Price
- $45
- Updated
- 2024/03/01
- Product number
- B0470
- Product name
- 2,2'-Biquinoline
- Purity
- >98.0%(HPLC)(T)
- Packaging
- 5g
- Price
- $147
- Updated
- 2024/03/01
- Product number
- A10907
- Product name
- 2,2'-Biquinoline, 98+%
- Packaging
- 1g
- Price
- $38.65
- Updated
- 2024/03/01
2,2'-Biquinoline Chemical Properties,Usage,Production
Chemical Properties
SLIGHTLY YELLOW TO LIGHT BEIGE SHINY FLAKES
Uses
2,2'-Biquinoline is used as a reagent for spectrophotometric determination of Cu and as an indicator for titration of organolithium reagents, giving yellow-green charge-transfer complexes.
Application
2,2'-Biquinoline, also known as cuprous reagent, reacts with monovalent cupric ion to give a purple color. It is a highly selective reagent for the determination of cuprous. It can be utilized as a ligand in the synthesis of heteroleptic Cu(I) complexes for light-emitting diodes(LED) and cationic iridium(III) complexes as phosphorescent dyes for live-cell imaging.
Synthesis Reference(s)
Tetrahedron Letters, 15, p. 2373, 1974 DOI: 10.1016/S0040-4039(01)92259-2
General Description
2,2′-Biquinoline is a white crystalline solid and it melts at 176°C. It is insoluble in water, but is soluble in ethyl, amyl and isoamyl alcohol, isoamyl acetate, dimethylformamide, acetic acid, acetonitrile and carbon tetrachloride.
Purification Methods
Decolourise 2,2'-biquinolyl in CHCl3 solution (charcoal), then crystallise it to constant melting point from EtOH or pet ether [Cumper et al. J Chem Soc 1188 1962]. [Beilstein 23/10 V 8.]
2,2'-Biquinoline Preparation Products And Raw materials
Raw materials
Preparation Products
2,2'-Biquinoline Suppliers
- Tel
- +49 3493/605464
- Fax
- +49 3493/605470
- sales@intatrade.de
- Country
- Germany
- ProdList
- 3576
- Advantage
- 66
- Tel
- --
- Fax
- --
- ccc@merckgroup.com
- Country
- Germany
- ProdList
- 2010
- Advantage
- 58
View Lastest Price from 2,2'-Biquinoline manufacturers
- Product
- biquinoline 119-91-5
- Price
- US $5.00/kg
- Min. Order
- 1kg
- Purity
- 99.92%
- Supply Ability
- 50000tons
- Release date
- 2024-04-24
- Product
- 2,2'-Biquinoline 119-91-5
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 50000tons
- Release date
- 2022-10-15
- Product
- 2,2’-biquinoline 119-91-5
- Price
- US $23.00-317.00/g
- Min. Order
- 1g
- Purity
- 0.98
- Supply Ability
- 25kg
- Release date
- 2023-10-19