(6aS)-5,6,6a,7-Tetrahydro-2-methoxy-4H-dibenzo[de,g]quinoline-1,10-diol
- Product Name
- (6aS)-5,6,6a,7-Tetrahydro-2-methoxy-4H-dibenzo[de,g]quinoline-1,10-diol
- CAS No.
- 2128-61-2
- Chemical Name
- (6aS)-5,6,6a,7-Tetrahydro-2-methoxy-4H-dibenzo[de,g]quinoline-1,10-diol
- Synonyms
- Sparsiflorine;(6aS)-5,6,6a,7-Tetrahydro-2-methoxy-4H-dibenzo[de,g]quinoline-1,10-diol;4H-Dibenzo[de,g]quinoline-1,10-diol, 5,6,6a,7-tetrahydro-2-methoxy-, (6aS)-
- CBNumber
- CB02142065
- Molecular Formula
- C17H17NO3
- Formula Weight
- 283.32
- MOL File
- 2128-61-2.mol
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(6aS)-5,6,6a,7-Tetrahydro-2-methoxy-4H-dibenzo[de,g]quinoline-1,10-diol Property
- Melting point:
- 230-232 °C (decomp)
- Boiling point:
- 528.0±50.0 °C(Predicted)
- Density
- 1.320±0.06 g/cm3(Predicted)
- pka
- 9?+-.0.20(Predicted)
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(6aS)-5,6,6a,7-Tetrahydro-2-methoxy-4H-dibenzo[de,g]quinoline-1,10-diol Chemical Properties,Usage,Production
Description
The leaves of Croton sparsijlorus Morung yield this noraporphine alkaloid which crystallizes as colourless, slender needles from EtOH. Two hydroxyl groups and an imino group are present and the base yields crystalline salts and derivatives, e.g. the hydrochloride, [α]30D + 43° (H20); methiodide, m.p. 218°C (dec.); the O,N-diacetyl derivative, m.p. 245°C and the triacetyl derivative, m.p. 196-7°C. The N-methyl compound gives a crystalline methiodide, m.p. 236-8°C (dec.). The structure has been established as 2-methoxy-l : 10-dihydroxynor aporphine.
References
Chatterjee et al., Tetrahedron Lett., 1539 (1965)
(6aS)-5,6,6a,7-Tetrahydro-2-methoxy-4H-dibenzo[de,g]quinoline-1,10-diol Preparation Products And Raw materials
Raw materials
Preparation Products
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