Di-n-butylmagnesium

Product Name: Di-n-butylmagnesium
CAS No.: 1191-47-5
Chemical Name: Di-n-butylmagnesium
Synonyms: nesium soL;dibutyl-magnesiu;DIBUTYLMAGNESIUM;MAGNESIUM DIBUTYL;DI-N-BUTYLMAGNESIUM;DI-N-BUTYLMAGNESIUM;Dibutylmagnesium solution;dibutyl magnesium solution;di-n-butylmagnesium solution;DIBUTYL MAGNESIUM SOLUTION APPROX. 0.75
CBNumber: CB0232591
Molecular Formula: C8H18Mg
Formula Weight: 138.54
MOL File: 1191-47-5.mol

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Di-n-butylmagnesium Property

Melting point:: -71 °C
Density: 0.749 g/mL at 20 °C
Flash point:: 21 °F
storage temp.: 2-8°C
BRN: 3535184
InChIKey: ODHFJIDDBSDWNU-UHFFFAOYSA-N
CAS DataBase Reference: 1191-47-5
EPA Substance Registry System: Magnesium, dibutyl- (1191-47-5)

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Safety

Hazard Codes: F+,C,T,F,N
Risk Statements: 12-14/15-22-34-66-67-48/20/22-40-39/23/24/25-23/24/25-11-10-65-50/53-17-19-62-52/53-48/20
Safety Statements: 16-26-36/37/39-43-45-7/8-62-61-60
RIDADR: UN 3399 4.3/PG 1
WGK Germany: 1
F: 1-3-10
HS Code: 29310099

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H224Extremely flammable liquid and vapour

H225Highly Flammable liquid and vapour

H250Catches fire spontaneously if exposed to air

H260In contact with water releases flammable gases which may ignite spontaneously

H302Harmful if swallowed

H304May be fatal if swallowed and enters airways

H314Causes severe skin burns and eye damage

H336May cause drowsiness or dizziness

H373May cause damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P231+P232Handle under inert gas. Protect from moisture.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P302+P334IF ON SKIN: Immerse in cool water/wrap in wet bandages.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P331Do NOT induce vomiting.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P422Store contents under …

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 345113
Product name: Di-n-butylmagnesium solution
Purity: 1.0 M in heptane
Packaging: 100ml
Price: $125
Updated: 2024/03/01

Sigma-Aldrich

Product number: 345113
Product name: Di-n-butylmagnesium solution
Purity: 1.0 M in heptane
Packaging: 800ml
Price: $976
Updated: 2024/03/01

Sigma-Aldrich

Product number: 731110
Product name: Di-n-butylmagnesium solution
Purity: 1 M in ether and hexanes
Packaging: 100ml
Price: $525
Updated: 2023/06/20

American Custom Chemicals Corporation

Product number: CHM0299895
Product name: DI-N-BUTYLMAGNESIUM
Purity: 95.00%
Packaging: 5MG
Price: $498.04
Updated: 2021/12/16

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Di-n-butylmagnesium Chemical Properties,Usage,Production

Chemical Properties

The pure substance is a waxy solid. Commercially, it is marketed as solution in?heptane. Di-n-butylmagnesium solution is a useful reagent for the synthesis of organomagnesium compounds.

Uses

Electrochemically inactive [Mg₂(μ-Cl)₃.6THF][C₂H₅AlCl₃] crystal may be obtained from an electrolyte composed of Di-n-butylmagnesium and ethylaluminum dichloride. Di-n-butylmagnesium may be used in the carbon metallation of α-olefins. A study reports the possible use of the organometallic compound in the intercalation of magnesium and zinc into the layers of TiS₂ or WO₂Cl₂. Interaction of lithium alkoxide with di-n-butylmagnesium was investigated.

Application

Di-n-butylmagnesium solution can be used as a reagent for the deprotection of aromatic and aliphatic benzyl thioethers to synthesize corresponding benzylthiols in the presence of titanocene dichloride. It can also be used as a catalyst to synthesize enantioenriched nitrogen-containing heterocyclic derivatives by the asymmetric ring-opening reaction of aziridines with substituted tetrazoles in the presence of chiral ligand.

General Description

Contains up to 1 wt. % Triethylaluminum as a viscosity reducer. stable under normal temperature and pressure, sensitive to light. contact with water releases flammable gas.

Di-n-butylmagnesium Preparation Products And Raw materials

Raw materials

Preparation Products

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Di-n-butylmagnesium Suppliers

Belgium 1 China 81 India 6 Switzerland 2 The Netherlands 2 United States 3 Global 95

Huangshi Bo’Er Chemical Co., Ltd.

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J & K SCIENTIFIC LTD.

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Syntechem Co.,Ltd

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Maya High Purity Chemicals

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View Lastest Price from Di-n-butylmagnesium manufacturers

Hebei Mojin Biotechnology Co., Ltd

Product: Di-n-butylmagnesium 1191-47-5
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-10-26

Hebei Guanlang Biotechnology Co., Ltd.

Product: Di-n-butylmagnesium 1191-47-5
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2023-03-29

Career Henan Chemical Co

Product: Di-n-butylmagnesium 1191-47-5
Price: US $9.80/KG
Min. Order: 1KG
Purity: ≥98%
Supply Ability: 20 tons
Release date: 2020-01-09

1191-47-5, Di-n-butylmagnesiumRelated Search:

ISOBUTYLMAGNESIUM BROMIDE ALLYLMAGNESIUM BROMIDE 3-FLUOROPHENYLMAGNESIUM BROMIDE Lithium hydroxide Potassium pyrophosphate SEC-BUTYLMAGNESIUM CHLORIDE TERT-BUTYLMAGNESIUM CHLORIDE Isopropylmagnesium chloride lithium chloride complex CYCLOPENTYLMAGNESIUM CHLORIDE ISOBUTYLMAGNESIUM CHLORIDE PENTYLMAGNESIUM CHLORIDE Butylmagnesium chloride Dimethyl magnesium Di-n-butylmagnesium N-BUTYLETHYLMAGNESIUM MAGNESIUM DIETHYL Magnesium DI-N-BUTYLMAGNESIUM

MAGNESIUM DIBUTYL

DI-N-BUTYLMAGNESIUM

DIBUTYLMAGNESIUM

dibutyl-magnesiu

dibutyl magnesium solution

Dibutylmagnesium solution

DIBUTYL MAGNESIUM SOLUTION, ~1 M IN HEPT ANE

DIBUTYLMAGNESIUM, 1.0M SOLUTION IN HEPTA NE

DIBUTYL MAGNESIUM SOLUTION APPROX. 0.75

Di-n-butylmagnesium, 0.5M solution in heptane

di-n-butylmagnesium solution

Di-n-butylmagnesium0.5M solution in heptaneAcroSeal§3

Di-n-butylmagnesium solution 1.0 in heptane

Di-n-butylmagnesium, 0.5M solution in heptane, AcroSeal

Di-n-butylMagnesiuM, 0.5M solution in heptane, AcroSeal 100ML

Di-n-butylMagnesiuM solution 1.0 M in heptane

Di-n-butylMagnesiuM solution, 1.0 M solution in heptane, SpcSeal

Di-n-butylmagnesium, 1.0M solution in hexane, J&KSeal

Di-n-butylMagnesiuM, 0.5M solution in heptane, SpcSeal

Di-n-butylmagnesium solution 1 M in ether and hexanes

nesium soL

DI-N-BUTYLMAGNESIUM

1191-47-5

C8H18Mg1

C8H18Mg

CH3CH232Mg

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