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(3R,20S)-19α-Methyl-2-oxoformosanan-16-carboxylic acid methyl ester

Product Name
(3R,20S)-19α-Methyl-2-oxoformosanan-16-carboxylic acid methyl ester
CAS No.
14019-66-0
Chemical Name
(3R,20S)-19α-Methyl-2-oxoformosanan-16-carboxylic acid methyl ester
Synonyms
Uncarine F;(3R,20S)-19α-Methyl-2-oxoformosanan-16-carboxylic acid methyl ester;(1'S,3R,4'aS,5'aR,10'aS)-1,2,5',5'a,7',8',10',10'a-Octahydro-1'-methyl-2-oxospiro[3H-indole-3,6'(4'aH)-[1H]pyrano[3,4-f]indolizine]-4'-carboxylic acid methyl ester;Spiro[3H-indole-3,6'(4'aH)-[1H]pyrano[3,4-f]indolizine]-4'-carboxylic acid, 1,2,5',5'a,7',8',10',10'a-octahydro-1'-methyl-2-oxo-, methyl ester, (1'S,3R,4'aS,5'aR,10'aS)-
CBNumber
CB02362913
Molecular Formula
C21H24N2O4
Formula Weight
368.43
MOL File
14019-66-0.mol
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(3R,20S)-19α-Methyl-2-oxoformosanan-16-carboxylic acid methyl ester Property

Boiling point:
555.2±50.0 °C(Predicted)
Density 
1.33
pka
13.56±0.60(Predicted)
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Hazard and Precautionary Statements (GHS)

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(3R,20S)-19α-Methyl-2-oxoformosanan-16-carboxylic acid methyl ester Chemical Properties,Usage,Production

Description

An Uncaria alkaloid, this base forms a colourless, non-crystallizable glass. The specific rotation is [α]D + 84° (CHCI3 ). It is stereoisomeric with the other alkaloids of this species just described.

Definition

ChEBI: Uncarine F is a member of indolizines.

References

Hart, Johns, Lamberton., Chem. Commun., 87 (1967)
Hemingway, Phillipson., J. Pharm. Pharmacol., 24, 169P (1972)
Circular dichroism: Beecham et al., Tetrahedron Lett., 991 (1967)

(3R,20S)-19α-Methyl-2-oxoformosanan-16-carboxylic acid methyl ester Preparation Products And Raw materials

Raw materials

Preparation Products

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(3R,20S)-19α-Methyl-2-oxoformosanan-16-carboxylic acid methyl ester Suppliers

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14019-66-0, (3R,20S)-19α-Methyl-2-oxoformosanan-16-carboxylic acid methyl esterRelated Search:


  • (3R,20S)-19α-Methyl-2-oxoformosanan-16-carboxylic acid methyl ester
  • (1'S,3R,4'aS,5'aR,10'aS)-1,2,5',5'a,7',8',10',10'a-Octahydro-1'-methyl-2-oxospiro[3H-indole-3,6'(4'aH)-[1H]pyrano[3,4-f]indolizine]-4'-carboxylic acid methyl ester
  • Uncarine F
  • Spiro[3H-indole-3,6'(4'aH)-[1H]pyrano[3,4-f]indolizine]-4'-carboxylic acid, 1,2,5',5'a,7',8',10',10'a-octahydro-1'-methyl-2-oxo-, methyl ester, (1'S,3R,4'aS,5'aR,10'aS)-
  • 14019-66-0