4-Chlorostyrene

Product Name: 4-Chlorostyrene
CAS No.: 1073-67-2
Chemical Name: 4-Chlorostyrene
Synonyms: 1-Chloro-4-vinylbenzene;P-CHLOROSTYRENE;para-chlorostyrene;4-Chlorostyrene, stabilized, 99%;ARBA-020;orostyrene;p-Chlorstyrol;CHLOROSTYRENE-4;p-chloro-styren;4-CHLOROSTYRENE
CBNumber: CB0240404
Molecular Formula: C8H7Cl
Formula Weight: 138.59
MOL File: 1073-67-2.mol

More

Less

4-Chlorostyrene Property

Melting point:: -16 °C
Boiling point:: 192 °C(lit.)
Density: 1.155 g/mL at 25 °C(lit.)
vapor pressure: 0.68 mm Hg ( 20 °C)
refractive index: n20/D 1.565(lit.)
Flash point:: 140 °F
storage temp.: 2-8°C
form: Liquid
Specific Gravity: 1.155
color: Clear colorless to slightly yellow
Water Solubility: Immiscible with water.
BRN: 1098859
CAS DataBase Reference: 1073-67-2(CAS DataBase Reference)
NIST Chemistry Reference: Benzene, 1-chloro-4-ethenyl-(1073-67-2)
EPA Substance Registry System: Benzene, 1-chloro-4-ethenyl- (1073-67-2)

More

Less

Safety

Hazard Codes: Xi,F
Risk Statements: 36/37/38
Safety Statements: 23-24/25-37/39-26-36
RIDADR: 1993
WGK Germany: 3
RTECS: CZ0533000
TSCA: T
HazardClass: 3
PackingGroup: III
HS Code: 29036990
Hazardous Substances Data: 1073-67-2(Hazardous Substances Data)
Toxicity: LD50 orally in Rabbit: 5200 mg/kg

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: C71203
Product name: 4-Chlorostyrene
Purity: 97%, contains 500ppm 4-
Packaging: 10g
Price: $110
Updated: 2024/03/01

Sigma-Aldrich

Product number: C71203
Product name: 4-Chlorostyrene
Purity: 97%, contains 500ppm 4-
Packaging: 50g
Price: $411
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.02458
Product name: 4-Chlorostyrene
Purity: (stabilised with 4-tert-butylpyrocatechol) for synthesis
Packaging: 10ml
Price: $106
Updated: 2024/03/01

TCI Chemical

Product number: C0290
Product name: 4-Chlorostyrene (stabilized with TBC)
Purity: >98.0%(GC)
Packaging: 10mL
Price: $26
Updated: 2024/03/01

TCI Chemical

Product number: C0290
Product name: 4-Chlorostyrene (stabilized with TBC)
Purity: >98.0%(GC)
Packaging: 25mL
Price: $50
Updated: 2024/03/01

More

Less

4-Chlorostyrene Chemical Properties,Usage,Production

Chemical Properties

clear colourless to slightly yellow liquid. The side chain of p-chlorostyrene is a C=C double bond, so its chemical properties are more active. The compound can polymerize slowly at room temperature, and a polymerization inhibitor (stabilizer) can be added for storage.

Uses

4-Chlorostyrene is used in the preparation of new bis(pyrazolyl)borato olefin complexes of copper(I). It is also employed in the investigation of regioselectivity in the cationic Heck reaction of 4-substituted styrenes. Further, it plays an important role in the preparation of 4-[(4-chloro-phenyl)-thioacetyl]-morpholine.

Uses

4-Chlorostyrene was used in the following studies:
Study of chemical and biochemical properties of the vinyl group of styrene by the development of structure activity relationships (SAR).
Preparation of new bis(pyrazolyl)borato olefin complexes of copper(I).
To investigate the regioselectivity in the cationic Heck reaction of 4-substituted styrenes.

Preparation

Synthesis of 4-chlorostyrene: carry out catalytic dehydration reaction by 4-chlorophenethylalcohol at 280°C, the used catalyst is a modified aluminum silicate catalyst, and the yield is 80%.

Synthesis Reference(s)

p-Chlorostyrene is commercially produced as a monomer from p-chloroethylbenzene by an oxidation technique. It is also produced as a mixture with o-chlorostyrene.
Journal of the American Chemical Society, 69, p. 852, 1947 DOI: 10.1021/ja01196a033
Tetrahedron Letters, 31, p. 5061, 1990 DOI: 10.1016/S0040-4039(00)97806-7

General Description

4-Chlorostyrene is a para-halogenated styrene derivative. It undergoes graft copolymerization with acrylonitrile (AN) onto ethylene-propylene-diene terpolymer (EPDM) in the presence of benzoyl peroxide (initiator).

4-Chlorostyrene Preparation Products And Raw materials

Raw materials

Preparation Products

3-[2-chloro-2-(4-chlorophenyl)ethenyl]-2，2-dimethyl cyclopropane carboxylic acid

More

Less

4-Chlorostyrene Suppliers

Americas 1 Belgium 3 China 242 Europe 2 Finland 1 Germany 10 India 11 Japan 7 Lithuania 1 Slovakia 1 Switzerland 4 Ukraine 1 United Kingdom 20 United States 48 Global 352

Shanghai Kaisai Chemical Co., Ltd

Tel: 021-33516722 13701817765
Fax: 021-33516776
Email: kaisaichem@163.com
Country: China
ProdList: 4743
Advantage: 58

Hepharma Biology And Technology CO.,LTD.

Tel: 187-26307739 18726307739
Email: waimaobu@hepharma.cn
Country: China
ProdList: 1078
Advantage: 58

Creasyn Finechem(Tianjin) Co., Ltd.

Tel: 022-83946278 13820503911
Fax: 022-83945176
Email: sales@creasyn.com
Country: China
ProdList: 988
Advantage: 68

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

INTATRADE GmbH

Tel: +49 3493/605464
Fax: +49 3493/605470
Email: sales@intatrade.de
Country: Germany
ProdList: 3572
Advantage: 66

3B Pharmachem (Wuhan) International Co.,Ltd.

Tel: 821-50328103-801 18930552037
Fax: 86-21-50328109
Email: 3bsc@sina.com
Country: China
ProdList: 15839
Advantage: 69

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44688
Advantage: 61

More

Less

View Lastest Price from 4-Chlorostyrene manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: 4-Chlorostyrene 1073-67-2
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-12-02

Hebei Weibang Biotechnology Co., Ltd

Product: 4-Chlorostyrene 1073-67-2
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-10-31

Hebei Yanxi Chemical Co., Ltd.

Product: 4-Chlorostyrene 1073-67-2
Price: US $50.00-10.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 20 tons
Release date: 2023-09-28

1073-67-2, 4-ChlorostyreneRelated Search:

OCTACHLOROSTYRENE Styrene Vinylbenzyl chloride 4-Chlorobenzyl cyanide 4-CHLOROPHENETOLE 4-Chlorophenoxyacetic acid 4-Chlorophenylacetic acid 4'-Chloroacetophenone 4-CHLOROBENZOYLACETONITRILE 3,4-DICHLOROSTYRENE meta-chlorostyren 3,4-Dichlorocinnamic acid 4,4'-Dichlorochalcone TRANS-2,4-DICHLOROCINNAMIC ACID POLY(3-CHLOROSTYRENE),3-CHLOROSTYRENE POLYMER (R)-4-CHLOROSTYRENE OXIDE 4-CHLOROSTYRENE RESIN,POLY(4-CHLOROSTYRENE), AVERAGE MW CA. 75 ,000 (GPC),POLY(4-CHLOROSTYRENE) o-Chlorobenzylidene malononitrile

CHLOROSTYRENE-4

4-Chlorostyrene, stabilized, 99%

4-CHLOROSTYRENE , STABILIZED WITH 0.1% 4-TERT-BUTYLCATECHOL

4-CHLOROSTYRENE Stabilised with 0.1% 4-tert-butylcatechol

P-CHLOROSTYRENE

p-chloro-styren

Styrene, p-chloro-

styrene,p-chloro-

4-CHLOROSTYRENE

4-VINYLCHLOROBENZENE

(4-Chlorophenyl)ethene

4-Chloro-1-ethenylbenzen

p-Chlorovinylbenzene

p-Vinylphenyl chloride

4-Chlorostyrene, 99%, stabilized

1-Ethenyl-4-chlorobenzene

4-Chloro-1-vinylbenzene

4-Vinylphenyl chloride

4-CHLOROSTYRENE, 99%, STAB.

4-Chlorostyrene (stabilized with TBC)

1-Ethenyl-4-chlorobenzol

4-Chlorostyrene, 99%, stab. with 0.1% 4-tert-butylcatechol

P-chlorobenzene ethylene

1-chloro-4-ethenyl-benzen

1-chloro-4-ethenylbenzene

1-Chloro-4-vinylbenzene

4-chloro-styren

Benzene, 4-chloro-1-ethenyl-

benzene,1-chloro-4-ethenyl-

Parachlorostyrene

para-chlorostyrene

4-Chlorostyrene, Stab.

1-Chloro-4-vinylbenzene, 1-Chloro-4-ethenylbenzene

4-Chlorostyrene, stabilized, 99% 10GR

4-CHLOROSTYRENE (STABILISED WITH 4-TERT-

4-Chlorostyrene, 98%, stabilized with 0.1% TBC

4-Chlorostyrene, stabilized with 0.1% TBC

4-chloro-1-ethenylbenzene

4-Chlorostyrene, 98%, stabilized with TBC

p-Chlorostyrene, 99% (Inhibited)

ARBA-020

Chlorobenzene ethylene

p-Chlorstyrol

4-Chlorostyrene - stabilised with 4-tert-butylcatechol

orostyrene

4-Chlorostyrene (stabilized with TBC)&gt

4-Chlorostyrene ISO 9001：2015 REACH

4-chloropacking

4-Chlorostyrene (stabilizer 0.1% tert.-butylcatechol)

1-Chloro-4-vinylbenzene[N/A

1073-67-2

1063-67-2

H2CCHC6H4Cl

ClC6H4CHCH2

HALOGEN

Alkenyl

Building Blocks

Halogenated Hydrocarbons