ChemicalBook > CAS DataBase List > 4-Chlorostyrene

4-Chlorostyrene

Product Name
4-Chlorostyrene
CAS No.
1073-67-2
Chemical Name
4-Chlorostyrene
Synonyms
1-Chloro-4-vinylbenzene;P-CHLOROSTYRENE;para-chlorostyrene;4-Chlorostyrene, stabilized, 99%;ARBA-020;orostyrene;p-Chlorstyrol;CHLOROSTYRENE-4;p-chloro-styren;4-CHLOROSTYRENE
CBNumber
CB0240404
Molecular Formula
C8H7Cl
Formula Weight
138.59
MOL File
1073-67-2.mol
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4-Chlorostyrene Property

Melting point:
-16 °C
Boiling point:
192 °C(lit.)
Density 
1.155 g/mL at 25 °C(lit.)
vapor pressure 
0.68 mm Hg ( 20 °C)
refractive index 
n20/D 1.565(lit.)
Flash point:
140 °F
storage temp. 
2-8°C
form 
Liquid
Specific Gravity
1.155
color 
Clear colorless to slightly yellow
Water Solubility 
Immiscible with water.
BRN 
1098859
CAS DataBase Reference
1073-67-2(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-chloro-4-ethenyl-(1073-67-2)
EPA Substance Registry System
Benzene, 1-chloro-4-ethenyl- (1073-67-2)
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Safety

Hazard Codes 
Xi,F
Risk Statements 
36/37/38
Safety Statements 
23-24/25-37/39-26-36
RIDADR 
1993
WGK Germany 
3
RTECS 
CZ0533000
TSCA 
T
HazardClass 
3
PackingGroup 
III
HS Code 
29036990
Hazardous Substances Data
1073-67-2(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: 5200 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
C71203
Product name
4-Chlorostyrene
Purity
97%, contains 500ppm 4-
Packaging
10g
Price
$110
Updated
2024/03/01
Sigma-Aldrich
Product number
C71203
Product name
4-Chlorostyrene
Purity
97%, contains 500ppm 4-
Packaging
50g
Price
$411
Updated
2024/03/01
Sigma-Aldrich
Product number
8.02458
Product name
4-Chlorostyrene
Purity
(stabilised with 4-tert-butylpyrocatechol) for synthesis
Packaging
10ml
Price
$106
Updated
2024/03/01
TCI Chemical
Product number
C0290
Product name
4-Chlorostyrene (stabilized with TBC)
Purity
>98.0%(GC)
Packaging
10mL
Price
$26
Updated
2024/03/01
TCI Chemical
Product number
C0290
Product name
4-Chlorostyrene (stabilized with TBC)
Purity
>98.0%(GC)
Packaging
25mL
Price
$50
Updated
2024/03/01
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4-Chlorostyrene Chemical Properties,Usage,Production

Chemical Properties

clear colourless to slightly yellow liquid. The side chain of p-chlorostyrene is a C=C double bond, so its chemical properties are more active. The compound can polymerize slowly at room temperature, and a polymerization inhibitor (stabilizer) can be added for storage.

Uses

4-Chlorostyrene is used in the preparation of new bis(pyrazolyl)borato olefin complexes of copper(I). It is also employed in the investigation of regioselectivity in the cationic Heck reaction of 4-substituted styrenes. Further, it plays an important role in the preparation of 4-[(4-chloro-phenyl)-thioacetyl]-morpholine.

Uses

4-Chlorostyrene was used in the following studies:
Study of chemical and biochemical properties of the vinyl group of styrene by the development of structure activity relationships (SAR).
Preparation of new bis(pyrazolyl)borato olefin complexes of copper(I).
To investigate the regioselectivity in the cationic Heck reaction of 4-substituted styrenes.

Preparation

Synthesis of 4-chlorostyrene: carry out catalytic dehydration reaction by 4-chlorophenethylalcohol at 280°C, the used catalyst is a modified aluminum silicate catalyst, and the yield is 80%.

Synthesis Reference(s)

p-Chlorostyrene is commercially produced as a monomer from p-chloroethylbenzene by an oxidation technique. It is also produced as a mixture with o-chlorostyrene.
Journal of the American Chemical Society, 69, p. 852, 1947 DOI: 10.1021/ja01196a033
Tetrahedron Letters, 31, p. 5061, 1990 DOI: 10.1016/S0040-4039(00)97806-7

General Description

4-Chlorostyrene is a para-halogenated styrene derivative. It undergoes graft copolymerization with acrylonitrile (AN) onto ethylene-propylene-diene terpolymer (EPDM) in the presence of benzoyl peroxide (initiator).

4-Chlorostyrene Preparation Products And Raw materials

Raw materials

Preparation Products

3-[2-chloro-2-(4-chlorophenyl)ethenyl]-2，2-dimethyl cyclopropane carboxylic acid
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View Lastest Price from 4-Chlorostyrene manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
4-Chlorostyrene 1073-67-2
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-31
Hebei Yanxi Chemical Co., Ltd.
Product
4-Chlorostyrene 1073-67-2
Price
US $50.00-10.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-09-28
Hebei Chuanghai Biotechnology Co,.LTD
Product
4-chloropacking 1073-67-2
Price
US $9.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 ton
Release date
2024-08-20

1073-67-2, 4-ChlorostyreneRelated Search:

OCTACHLOROSTYRENE Styrene Vinylbenzyl chloride 4-Chlorobenzyl cyanide 4-CHLOROPHENETOLE 4-Chlorophenoxyacetic acid 4-Chlorophenylacetic acid 4'-Chloroacetophenone 4-CHLOROBENZOYLACETONITRILE 3,4-DICHLOROSTYRENE meta-chlorostyren 3,4-Dichlorocinnamic acid 4,4'-Dichlorochalcone TRANS-2,4-DICHLOROCINNAMIC ACID POLY(3-CHLOROSTYRENE),3-CHLOROSTYRENE POLYMER (R)-4-CHLOROSTYRENE OXIDE 4-CHLOROSTYRENE RESIN,POLY(4-CHLOROSTYRENE), AVERAGE MW CA. 75 ,000 (GPC),POLY(4-CHLOROSTYRENE) o-Chlorobenzylidene malononitrile

  • CHLOROSTYRENE-4
  • 4-Chlorostyrene, stabilized, 99%
  • 4-CHLOROSTYRENE , STABILIZED WITH 0.1% 4-TERT-BUTYLCATECHOL
  • 4-CHLOROSTYRENE Stabilised with 0.1% 4-tert-butylcatechol
  • P-CHLOROSTYRENE
  • p-chloro-styren
  • Styrene, p-chloro-
  • styrene,p-chloro-
  • 4-CHLOROSTYRENE
  • 4-VINYLCHLOROBENZENE
  • (4-Chlorophenyl)ethene
  • 4-Chloro-1-ethenylbenzen
  • p-Chlorovinylbenzene
  • p-Vinylphenyl chloride
  • 4-Chlorostyrene, 99%, stabilized
  • 1-Ethenyl-4-chlorobenzene
  • 4-Chloro-1-vinylbenzene
  • 4-Vinylphenyl chloride
  • 4-CHLOROSTYRENE, 99%, STAB.
  • 4-Chlorostyrene (stabilized with TBC)
  • 1-Ethenyl-4-chlorobenzol
  • 4-Chlorostyrene, 99%, stab. with 0.1% 4-tert-butylcatechol
  • P-chlorobenzene ethylene
  • 1-chloro-4-ethenyl-benzen
  • 1-chloro-4-ethenylbenzene
  • 1-Chloro-4-vinylbenzene
  • 4-chloro-styren
  • Benzene, 4-chloro-1-ethenyl-
  • benzene,1-chloro-4-ethenyl-
  • Parachlorostyrene
  • para-chlorostyrene
  • 4-Chlorostyrene, Stab.
  • 1-Chloro-4-vinylbenzene, 1-Chloro-4-ethenylbenzene
  • 4-Chlorostyrene, stabilized, 99% 10GR
  • 4-CHLOROSTYRENE (STABILISED WITH 4-TERT-
  • 4-Chlorostyrene, 98%, stabilized with 0.1% TBC
  • 4-Chlorostyrene, stabilized with 0.1% TBC
  • 4-chloro-1-ethenylbenzene
  • 4-Chlorostyrene, 98%, stabilized with TBC
  • p-Chlorostyrene, 99% (Inhibited)
  • ARBA-020
  • Chlorobenzene ethylene
  • p-Chlorstyrol
  • 4-Chlorostyrene - stabilised with 4-tert-butylcatechol
  • orostyrene
  • 4-Chlorostyrene (stabilized with TBC)&gt
  • 4-Chlorostyrene ISO 9001：2015 REACH
  • 4-chloropacking
  • 4-Chlorostyrene (stabilizer 0.1% tert.-butylcatechol)
  • 1-Chloro-4-vinylbenzene[N/A
  • 1073-67-2
  • 1063-67-2
  • H2CCHC6H4Cl
  • ClC6H4CHCH2
  • HALOGEN
  • Alkenyl
  • Building Blocks
  • Halogenated Hydrocarbons