ChemicalBook > CAS DataBase List > 2,3,6,7,10,11-Triphenylenehexol

2,3,6,7,10,11-Triphenylenehexol

Application

Product Name: 2,3,6,7,10,11-Triphenylenehexol
CAS No.: 4877-80-9
Chemical Name: 2,3,6,7,10,11-Triphenylenehexol
Synonyms: Hexahydroxytriphenylene;Triphenylene-2,3,6,7,10,11-hexaol;2,3,6,7,10,11-HEXAHYDROXYTRIPHENYLENE HYDRATE;DK7656;RMA-421;JACS-4877-80-9;Benzoicacid,5-iodyl-;2,3,6,7,10,11-Triphenylenehexol;triphenylene-2,3,6,7,10,11-hexol;2,3,6,7,10,11-Hexahydroxytriphenyl
CBNumber: CB0245984
Molecular Formula: C18H12O6
Formula Weight: 324.28
MOL File: 4877-80-9.mol

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2,3,6,7,10,11-Triphenylenehexol Property

Melting point:: >300℃
Boiling point:: 776.3±55.0 °C(Predicted)
Density: 1.778
storage temp.: Inert atmosphere,Room Temperature
solubility: very slightly in Tetrahydrofuran
form: powder to crystal
pka: 8.46±0.30(Predicted)
color: Light gray to Brown to Black
InChI: InChI=1S/C18H12O6/c19-13-1-7-8(2-14(13)20)10-4-17(23)18(24)6-12(10)11-5-16(22)15(21)3-9(7)11/h1-6,19-24H
InChIKey: QMLILIIMKSKLES-UHFFFAOYSA-N
SMILES: C1=C2C(C3C(C4C2=CC(O)=C(O)C=4)=CC(O)=C(O)C=3)=CC(O)=C1O
CAS DataBase Reference: 4877-80-9

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Safety

Risk Statements: 36/37/38
Safety Statements: 26-36/37/39
HS Code: 29072990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

TCI Chemical

Product number: H0907
Product name: 2,3,6,7,10,11-Hexahydroxytriphenylene Hydrate
Purity: >95.0%(HPLC)
Packaging: 1g
Price: $135
Updated: 2025/07/31

TCI Chemical

Product number: H0907
Product name: 2,3,6,7,10,11-Hexahydroxytriphenylene Hydrate
Purity: >95.0%(HPLC)
Packaging: 5g
Price: $456
Updated: 2025/07/31

TRC

Product number: T889153
Product name: Triphenylene-2,3,6,7,10,11-hexaol
Packaging: 50mg
Price: $60
Updated: 2021/12/16

AK Scientific

Product number: J55113
Product name: 2,3,6,7,10,11-Hexahydroxytriphenylene Hydrate
Packaging: 250mg
Price: $49
Updated: 2021/12/16

AK Scientific

Product number: V3252
Product name: 2,3,6,7,10,11-Hexahydroxytriphenylene Hydrate
Packaging: 250mg
Price: $67
Updated: 2021/12/16

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2,3,6,7,10,11-Triphenylenehexol Chemical Properties,Usage,Production

Application

2,3,6,7,10,11-Hexahydroxytriphenyl can be used to prepare metal-organic frameworks (MOFs). MOFs are a class of materials formed by the coordination of metal ions and organic ligands. Compared with traditional inorganic porous materials, MOFs have higher porosity, larger specific surface area, tunable pore structure, and excellent structural stability, and are widely used in chemical energy storage.

Chemical Properties

Light brown to brown powder

Synthesis

808-57-1

4877-80-9

The general procedure for the synthesis of 2,3,6,7,10,11-hexamethoxytriphenylene from 2,3,6,7,10,11-hexahydroxytriphenylene was carried out as follows: the preparation of compound 4 was carried out with reference to the method described in literature [14]. Hexamethoxytriphenylene (7 g, 17.14 mmol) was dissolved in dichloromethane (50 ml) and the resulting solution was cooled in an ice bath. Subsequently, boron tribromide solution (11.47 ml) was slowly added dropwise to the reaction mixture over a period of 30 min. After completion of the dropwise addition, the reaction mixture was stirred at room temperature overnight. After completion of the reaction, the mixture was slowly poured into crushed ice (100 g) and stirred vigorously until the ice was completely melted. Next, multiple extractions were carried out with ethyl acetate (6 x 150 ml), the organic phases were combined and dried over anhydrous sodium sulfate, and finally concentrated to dryness under reduced pressure to give a dark purple solid product. The yield of this step was nearly quantitative and the resulting compound could be used in subsequent reactions without further purification.

References

[1] Journal of Materials Chemistry, 2002, vol. 12, # 8, p. 2208 - 2213
[2] Journal of Molecular Liquids, 2016, vol. 223, p. 734 - 740
[3] Journal of the American Chemical Society, 2017, vol. 139, # 46, p. 16759 - 16767
[4] Patent: US2002/157939, 2002, A1
[5] Journal of Materials Chemistry A, 2017, vol. 5, # 24, p. 12080 - 12085

2,3,6,7,10,11-Triphenylenehexol Preparation Products And Raw materials

Raw materials

Preparation Products

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2,3,6,7,10,11-Triphenylenehexol Suppliers

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View Lastest Price from 2,3,6,7,10,11-Triphenylenehexol manufacturers

Henan Aochuang Chemical Co.,Ltd.

Product: 2,3,6,7,10,11-HEXAHYDROXYTRIPHENYLENE 4877-80-9
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1ton
Release date: 2022-09-30

Shaanxi Dideu Medichem Co. Ltd

Product: 2,3,6,7,10,11-Triphenylenehexol 4877-80-9
Price: US $1.00-2.10/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20000KG
Release date: 2024-08-08

Hebei Xinsheng New Material Technology Co., LTD.

Product: 2,3,6,7,10,11-Triphenylenehexol 4877-80-9
Price: US $35.00-25.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20 Ton
Release date: 2023-11-01

4877-80-9, 2,3,6,7,10,11-TriphenylenehexolRelated Search:

Benzenamine,4,4',4''-[1,3,5-triazine-2,4,6-triyltris(oxy)]tris- Tetra-p-tolylethene 2,3,6,7,10,11-Triphenylenehexol 2,3,6,7,10,11-HEXAACETOXYTRIPHENYLENE 2,3,6,7,10,11-HEXAMETHOXYTRIPHENYLENE 2,3,6,7,10,11-HEXAKIS(PENTYLOXY)TRIPHENYLENE 2,7-Dihydroxy-3,6,10,11-tetrakis(pentyloxy)triphenylene

2,3,6,7,10,11-HEXAHYDROXYTRIPHENYLENE

2,3,6,7,10,11-HEXAHYDROXYTRIPHENYLENE HYDRATE

Hexahydroxytriphenylene

2,3,6,7,10,11-HEXAHYDROXYTRIPHENYLENE 95+%

Triphenylene-2,3,6,7,10,11-hexaol

2,3,6,7,10,11-Triphenylenehexol

triphenylene-2,3,6,7,10,11-hexol

JACS-4877-80-9

2,3,6,7,10,11-HexahydroxytriphenyleneHydrate&gt

2,3,6,7,10,11-Hexahydroxytriphenylene hydrate, 95%, for synthesis

Triphenylene-2，3，6，7，10，11-hexaol Monohydrate

2,3,6,7,1,11-Hexahydroxytriphenylene hydrate

tianfu-chem_2,3,6,7,10,11-HEXAHYDROXYTRIPHENYLENE// 4877-80-9

Benzoicacid,5-iodyl-

DK7656

RMA-421

2,3,6,7,10,11-Hexahydroxytriphenyl

4877-80-9

C18H12O6xH2O

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