CIS-1-BROMO-1-PROPENE
- Product Name
- CIS-1-BROMO-1-PROPENE
- CAS No.
- 590-13-6
- Chemical Name
- CIS-1-BROMO-1-PROPENE
- Synonyms
- (Z)-1-broMoprop-1-ene;(Z)-1-Bromopropene;(Z)-1-bromo-1-propene;(Z)-1-Propenyl bromide;cis-1-Bromopropene;(Z)-Propenyl bromide;Propene,1-bromo-,(Z)-;CIS-1-BROMO-1-PROPENE;cis-1-bromo-prop-1-ene;(1Z)-1-bromoprop-1-ene
- CBNumber
- CB0247988
- Molecular Formula
- C3H5Br
- Formula Weight
- 120.98
- MOL File
- 590-13-6.mol
CIS-1-BROMO-1-PROPENE Property
- Melting point:
- -113°C
- Boiling point:
- 58 °C(lit.)
- Density
- 1.423 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.4545(lit.)
- Flash point:
- <−30 °F
- solubility
- soluble in Chloroform
- form
- Oil
- color
- Colourless
- Sensitive
- Light Sensitive
- Stability:
- Light Sensitive, Volatile
- CAS DataBase Reference
- 590-13-6
Safety
- Hazard Codes
- F,Xi
- Risk Statements
- 11-36/37/38
- Safety Statements
- 16-26-36/37/39
- RIDADR
- UN 1993 3/PG 2
- WGK Germany
- 3
- HazardClass
- 3
- PackingGroup
- II
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof electrical/ventilating/lighting/…/equipment.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 368679
- Product name
- cis-1-Bromo-1-propene
- Purity
- 97%
- Packaging
- 10g
- Price
- $104
- Updated
- 2024/03/01
- Product number
- 368679
- Product name
- cis-1-Bromo-1-propene
- Purity
- 97%
- Packaging
- 50g
- Price
- $360
- Updated
- 2024/03/01
- Product number
- 20471
- Product name
- CIS-1-BROMOPROPENE,98%
- Packaging
- 10g
- Price
- $67.34
- Updated
- 2021/12/16
- Product number
- HCH0014059
- Product name
- CIS-1-BROMO-1-PROPENE
- Purity
- 95.00%
- Packaging
- 10G
- Price
- $1165.7
- Updated
- 2021/12/16
- Product number
- HCH0014059
- Product name
- CIS-1-BROMO-1-PROPENE
- Purity
- 95.00%
- Packaging
- 50G
- Price
- $2711.1
- Updated
- 2021/12/16
CIS-1-BROMO-1-PROPENE Chemical Properties,Usage,Production
Uses
cis-1-Bromo-1-propene is generally used as a reactant in organic synthesis.
Application
Used as a precursor for (E)- or (Z)-1-propenyllithium and 1-propenylmagnesium bromide, and a reagent for electrophilic propenylation.
General Description
cis-1-Bromo-1-propene is an aliphatic olefin. Oxidation of cis-1-bromo-1-propene by toluene dioxygenase has been reported.
Synthesis
(Z)- and (E)-1-propenyl bromides can be obtained through spinning band distillation of the commercially available mixture of isomers (Z/E = 70/30). However, the (E)-isomer can only be obtained with difficulty due to thermal isomerization to the (Z)-isomer. Pure (Z)-1-propenyl bromide can be prepared by bromination of (E)-crotonic acid followed by bromodecarboxylation of the resulting erythro-2,3-dibromobutanoic acid in the presence of Triethylamine or Diisopropylethylamine at 40 °C (eq 1). (E)-1-Propenyl bromide can be obtained in 98% purity by treatment of the commercially available mixture of isomers (Z/E = 70/30) with Sodium Hydroxide in n-BuOH at reflux until no (Z)-1-propenyl bromide is detected by GLC.
storage
Stored in a refrigerator to inhibit thermal and acid-catalyzed isomerization. Avoid breathing vapor and contact with skin and eyes. Use in a fume hood.
CIS-1-BROMO-1-PROPENE Preparation Products And Raw materials
Raw materials
Preparation Products
CIS-1-BROMO-1-PROPENE Suppliers
- Tel
- 025-86918202 4000255188
- Fax
- 86-025-86918232
- sales@pharmablock.com
- Country
- China
- ProdList
- 4986
- Advantage
- 55
- Tel
- 025-83697070
- Fax
- +86-25-83453306
- info@chemlin.com.cn
- Country
- China
- ProdList
- 19186
- Advantage
- 64
- Tel
- 400-1166-196 18981987031
- Fax
- 028-84555506 800101999
- cdhxsj@163.com
- Country
- China
- ProdList
- 11707
- Advantage
- 57
- Tel
- 400-400-6206333 18521732826
- Fax
- 021-50323701
- market@aladdin-e.com
- Country
- China
- ProdList
- 25003
- Advantage
- 65
- Tel
- 17501653713
- xingui2022@126.com
- Country
- China
- ProdList
- 10022
- Advantage
- 58
- Tel
- 021-61415566 800-8193336
- orderCN@merckgroup.com
- Country
- China
- ProdList
- 51456
- Advantage
- 80
- Tel
- 18620099427
- Fax
- +86-20-62619665
- amy@howeipharm.com
- Country
- China
- ProdList
- 17687
- Advantage
- 55
- Tel
- 021-52907766-8042
- Fax
- 021-52906523
- Country
- China
- ProdList
- 9941
- Advantage
- 58
- Tel
- 025-66113011 18112977050
- Fax
- 02557626880
- sales01@aikonchem.com
- Country
- China
- ProdList
- 16027
- Advantage
- 58
- Tel
- 0531-61320525 15866703830
- 495745175@qq.com
- Country
- China
- ProdList
- 7397
- Advantage
- 58
View Lastest Price from CIS-1-BROMO-1-PROPENE manufacturers
- Product
- CIS-1-BROMO-1-PROPENE 590-13-6
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 mt
- Release date
- 2024-12-11