2,6-dibromo-4-methoxyaniline
- Product Name
- 2,6-dibromo-4-methoxyaniline
- CAS No.
- 95970-05-1
- Chemical Name
- 2,6-dibromo-4-methoxyaniline
- Synonyms
- 2,6-Dibromo-p-anisidine;Phloroglucinol Impurity 36;,6-DIBROMO-4-METHOXYANILINE;2,6-dibromo-4-methoxyaniline;6-dibroMo-4-MethoxybenzenaMine;2,6-dibroMo-4-MethoxybenzenaMine;2,6-DibroMo-4-Methoxy-phenylaMine;Benzenamine, 2,6-dibromo-4-methoxy-
- CBNumber
- CB02535847
- Molecular Formula
- C7H7Br2NO
- Formula Weight
- 280.94
- MOL File
- 95970-05-1.mol
2,6-dibromo-4-methoxyaniline Property
- Melting point:
- 81-83℃
- Boiling point:
- 293.6±35.0 °C(Predicted)
- Density
- 1.897
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- pka
- 1.08±0.10(Predicted)
- Appearance
- White to light brown Solid
- InChI
- InChI=1S/C7H7Br2NO/c1-11-4-2-5(8)7(10)6(9)3-4/h2-3H,10H2,1H3
- InChIKey
- JIZVMILRYBKPFN-UHFFFAOYSA-N
- SMILES
- C1(N)=C(Br)C=C(OC)C=C1Br
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- B426293
- Product name
- 2,6-Dibromo-4-methoxyaniline
- Packaging
- 50mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- 144886
- Product name
- 2,6-Dibromo-4-methoxybenzenamine
- Purity
- 95%
- Packaging
- 500mg
- Price
- $1462
- Updated
- 2021/12/16
- Product number
- 144886
- Product name
- 2,6-Dibromo-4-methoxybenzenamine
- Purity
- 95%
- Packaging
- 1g
- Price
- $2202
- Updated
- 2021/12/16
- Product number
- 8192BA
- Product name
- 2,6-Dibromo-4-methoxyaniline
- Packaging
- 10g
- Price
- $948
- Updated
- 2021/12/16
- Product number
- 8192BA
- Product name
- 2,6-Dibromo-4-methoxyaniline
- Packaging
- 250mg
- Price
- $138
- Updated
- 2021/12/16
2,6-dibromo-4-methoxyaniline Chemical Properties,Usage,Production
Synthesis
104-94-9
95970-05-1
2.3.2 Synthesis of 2,6-dibromo-4-methoxyaniline (B) Compound 2,6-dibromo-4-methoxyaniline was synthesized using the method reported in literature [15] with slight modifications. The procedure was carried out as follows: bromine (4.9 mL, 95.48 mmol) was slowly added dropwise to a methanol:dichloromethane (50:40 mL) mixture of p-anisidine (5 g, 40.63 mmol) to the reaction system under ice-bath conditions, and the dropwise addition process was controlled to be completed within 30 min. The reaction mixture was continued to be stirred in an ice bath and subsequently moved to room temperature and stirred overnight. Upon completion of the reaction, the mixture was transferred to a 500 mL beaker and subjected to solvent evaporation in a fume hood. When the solvent volume was reduced to about 40 mL, white needle-like crystals were observed to precipitate. The crystals were collected by filtration and washed with a small amount of cold methanol and subsequently dried in air. Finally, 22.5 g of the target product was obtained in about 75% yield.
References
[1] Bulletin of the Chemical Society of Japan, 1988, vol. 61, # 2, p. 597 - 599
[2] Inorganica Chimica Acta, 2018, vol. 482, p. 925 - 934
[3] Patent: WO2010/93419, 2010, A1. Location in patent: Page/Page column 215-216
[4] Journal of Organic Chemistry, 2013, vol. 78, # 10, p. 5103 - 5109
[5] Journal of the American Chemical Society, 2009, vol. 131, # 48, p. 17583 - 17590
2,6-dibromo-4-methoxyaniline Preparation Products And Raw materials
Raw materials
Preparation Products
2,6-dibromo-4-methoxyaniline Suppliers
- Tel
- --
- Fax
- --
- enquiries@fluorochem.co.uk
- Country
- United Kingdom
- ProdList
- 6401
- Advantage
- 74
View Lastest Price from 2,6-dibromo-4-methoxyaniline manufacturers
- Product
- 2,6-dibromo-4-methoxyaniline 95970-05-1
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2024-11-08