Umicore M71 SIPr

Reaction

Product Name: Umicore M71 SIPr
CAS No.: 1212008-99-5
Chemical Name: Umicore M71 SIPr
Synonyms: M71-S1Pr;Umicore M71 SIPr;Hoveyda-Grubbs Catalyst(R) M711;UMicore M71 SIPr, 12% Ru, Product of UMicore;[1,3-Bis(2,6-diisopropylphenyl)-2-imidazolidinylidene]dichloro[(2- isopropoxy)(5-trifluoroacetamido)benzylidene]ruthenium(II);1,3-Bis(2,6-diisopropylphenyl)-2-imidazolidinylidene](dichloro){ 2-isopropoxy-5-[(trifluoroacetyl)amino]benzylidene}ruthenium;[1,3-Bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylidene]-[2-i-propoxy-5-(trifluoroacetamido)phenyl]methyleneruthenium(II);1,3-Bis(2,6-diisopropylphenyl)imidazolidin-2-ylidene][2-isopropoxy-5-(2,2,2-trifluoroacetamido)benzylidene]ruthenium(VI) Chloride;[1,3-Bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylidene]-[2-i-propoxy-5-(trifluoroacetamido)phenyl]methyleneruthenium(II)dichloride;[1,3-Bis(2,6-di-i-propylphenyl)-4,5-dihydroiMidazol-2-ylidene]-[2-i-propoxy-5-(trifluoroacetaMido)phenyl]MethylenerutheniuM(II) dichloride M71-S1Pr
CBNumber: CB02551890
Molecular Formula: C39H49Cl2F3N3O2Ru
Formula Weight: 820.81
MOL File: 1212008-99-5.mol

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Umicore M71 SIPr Property

Melting point:: >300 °C
form: Powder
color: green
CAS DataBase Reference: 1212008-99-5

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Safety

HS Code: 28439000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P321Specific treatment (see … on this label).

P322Specific measures (see …on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P363Wash contaminated clothing before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 909165
Product name: Hoveyda-Grubbs Catalyst® M711
Purity: Umicore
Packaging: 100MG
Price: $98.4
Updated: 2024/03/01

Sigma-Aldrich

Product number: 909165
Product name: Hoveyda-Grubbs Catalyst® M711
Purity: Umicore
Packaging: 1G
Price: $354.6
Updated: 2024/03/01

Strem Chemicals

Product number: 44-0055
Product name: [1,3-Bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylidene]-[2-i-propoxy-5-(trifluoroacetamido)phenyl]methyleneruthenium(II) dichloride M71-S1Pr
Packaging: 100mg
Price: $116
Updated: 2024/03/01

Strem Chemicals

Product number: 44-0055
Product name: [1,3-Bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylidene]-[2-i-propoxy-5-(trifluoroacetamido)phenyl]methyleneruthenium(II) dichloride M71-S1Pr
Packaging: 500mg
Price: $458
Updated: 2024/03/01

Chemenu

Product number: CM102932
Product name: [1,3-Bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylidene]-[2-i-propoxy-5-(trifluoroacetamido)phenyl]methyleneruthenium(II)
Purity: 95%
Packaging: 100mg
Price: $240
Updated: 2021/12/16

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Umicore M71 SIPr Chemical Properties,Usage,Production

Reaction

Enhanced activity ruthenium "boomerang" pre-catalyst used in the olefin metathesis, enyne metathesis, and cross metathesis reactions, that can be recycled, and leaves reduced ruthenium in the product after silica gel chromatography.

Chemical Properties

solid

Uses

Umicore Hoveyda-Grubbs Catalyst M711 is a homogeneous catalyst useful for alkene metathesis, cross metathesis, ring closing metathesis, and self metathesis.

Umicore M71 SIPr Preparation Products And Raw materials

Raw materials

Preparation Products

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Umicore M71 SIPr Suppliers

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1212008-99-5, Umicore M71 SIPrRelated Search:

Cumene Umicore M31 Umicore M41 Tricyclohexylphosphine[3-phenyl-1H-inden-1-ylidene][1,3-bis(2,4,6-triMethylphenyl)-4,5-dihydroiMidazol-2-ylidene]rutheniuM(II) Umicore M71 SIMes Umicore M52 DICHLORO-(3-PHENYL-1H-INDEN-1-YLIDENE)BIS(ISOBUTYLPHOBANE)RUTHENIUM(II) Umicore M42 Umicore M73 SIMes (3-Phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)rutheniuM(IV) Dichloride Umicore M73 SIPr Umicore M51

[1,3-Bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylidene]-[2-i-propoxy-5-(<br />trifluoroacetamido)phenyl]methyleneruthenium(II) dichloride omega CS1

[1,3-Bis(2,6-diisopropylphenyl)-2-imidazolidinylidene]dichloro[(2- isopropoxy)(5-trifluoroacetamido)benzylidene]ruthenium(II)

M71-S1Pr

[1,3-Bis(2,6-di-i-propylphenyl)-4,5-dihydroiMidazol-2-ylidene]-[2-i-propoxy-5-(trifluoroacetaMido)phenyl]MethylenerutheniuM(II) dichloride M71-S1Pr

[1,3-Bis[2,6-bis(1-methylethyl)phenyl]-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy)-5-[(2,2,2-trifluoroacetyl)amino]phenyl]methylene]-ruthenium

Umicore M71 SIPr

UMicore M71 SIPr, 12% Ru, Product of UMicore

[1,3-Bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylidene]-[2-i-propoxy-5-(trifluoroacetamido)phenyl]methyleneruthenium(II)

[1,3-Bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylidene]-[2-i-propoxy-5-(trifluoroacetamido)phenyl]methyleneruthenium(II)dichloride

Hoveyda-Grubbs Catalyst(R) M711

1,3-Bis(2,6-diisopropylphenyl)-2-imidazolidinylidene](dichloro){ 2-isopropoxy-5-[(trifluoroacetyl)amino]benzylidene}ruthenium

1,3-Bis(2,6-diisopropylphenyl)imidazolidin-2-ylidene][2-isopropoxy-5-(2,2,2-trifluoroacetamido)benzylidene]ruthenium(VI) Chloride

1212008-99-5

C39H50Cl2F3N3O2Ru

Ru

organometallic complex