ChemicalBook > CAS DataBase List > 9-Azabicyclo[3.3.1]nonan-3-one, 9-(phenylmethyl)-
9-Azabicyclo[3.3.1]nonan-3-one, 9-(phenylmethyl)-
- Product Name
- 9-Azabicyclo[3.3.1]nonan-3-one, 9-(phenylmethyl)-
- CAS No.
- 2291-58-9
- Chemical Name
- 9-Azabicyclo[3.3.1]nonan-3-one, 9-(phenylmethyl)-
- Synonyms
- 9-Benzyl-3-oxo-9-azabicyc...;N-Benzylnorpseudopelletierine;9-Benzyl-9-aza-bicyclo3.3.1non-3-one;9-Benzyl-3-oxo-9-azabicyclo[3.3.1]nonane;9-(phenylmethyl)-9-azabicyclo[3.3.1]nonan-3-one;9-Azabicyclo[3.3.1]nonan-3-one, 9-(phenylmethyl)-;9-Benzyl-9-az9-Benzyl-9-azabicyclo[3.3.1]nonan-3-oneabicyclo[3.3.1]nonan-3-one
- CBNumber
- CB02552862
- Molecular Formula
- C15H19NO
- Formula Weight
- 229.32
- MOL File
- 2291-58-9.mol
More
Less
9-Azabicyclo[3.3.1]nonan-3-one, 9-(phenylmethyl)- Property
- Melting point:
- 72-75℃
- Boiling point:
- 165-169 °C(Press: 0.2 Torr)
- Density
- 1?+-.0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- pka
- 8.04±0.20(Predicted)
- Appearance
- White to off-white Solid
More
Less
Safety
- HS Code
- 2921309990
More
Less
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
More
Less
N-Bromosuccinimide Price
TRC
- Product number
- B230750
- Product name
- 9-Benzyl-9-azabicyclo[3.3.1]nonan-3-one
- Packaging
- 500mg
- Price
- $125
- Updated
- 2021/12/16
SynQuest Laboratories
- Product number
- 4H56-1-LF
- Product name
- 9-Benzyl-3-oxo-9-azabicyclo[3.3.1]nonane
- Packaging
- 5G
- Price
- $150
- Updated
- 2021/12/16
Biosynth Carbosynth
- Product number
- FB163632
- Product name
- 9-Benzyl-9-azabicyclo[3.3.1]nonan-3-one
- Packaging
- 2g
- Price
- $160
- Updated
- 2021/12/16
Matrix Scientific
- Product number
- 113432
- Product name
- 9-Benzyl-3-oxo-9-azabicyclo[3.3.1]nonane
- Packaging
- 5g
- Price
- $240
- Updated
- 2021/12/16
Biosynth Carbosynth
- Product number
- FB163632
- Product name
- 9-Benzyl-9-azabicyclo[3.3.1]nonan-3-one
- Packaging
- 5G
- Price
- $300
- Updated
- 2021/12/16
More
Less
9-Azabicyclo[3.3.1]nonan-3-one, 9-(phenylmethyl)- Chemical Properties,Usage,Production
Synthesis
542-05-2
111-30-8
100-46-9
2291-58-9
1. Benzylamine (5.0 g, 47 mmol) and Na?HPO?-12H?O (5.0 g) were dissolved in 50 mL of water and cooled in an ice water bath. 2. a 25% aqueous solution of 1,3-acetone dicarboxylic acid (8 g, 20 mmol, 1.0 eq.) was slowly added with stirring. 3. After the dropwise addition was completed within 60 minutes, the reaction mixture was allowed to warm slowly to room temperature and stirring was continued for 24 hours. 4. Upon completion of the reaction, the pH was adjusted to 3 with concentrated hydrochloric acid. 5. The reaction mixture was transferred to an oil bath at 50 °C, stirred for 2 hours and then cooled to room temperature. 6. The pH was adjusted to 10 with 20% NaOH solution, then extracted twice with dichloromethane and the organic phases were combined. 7. The organic phase was washed once with saturated brine and concentrated under reduced pressure to give a yellow solid crude product of 9-benzyl-9-azabicyclo[3.3.1]nonan-3-one. 8. The crude product was purified by crystallization with a solvent mixture of ethyl acetate and petroleum ether in the ratio of 1:5 by volume, and 9 g of light yellow solid product was obtained after filtration in 91% yield.
References
[1] Patent: CN106366082, 2017, A. Location in patent: Paragraph 0047-0049
[2] Patent: WO2012/112851, 2012, A2. Location in patent: Page/Page column 54
[3] Chemical and Pharmaceutical Bulletin, 2011, vol. 59, # 12, p. 1570 - 1573
[4] Journal of Medicinal Chemistry, 2006, vol. 49, # 11, p. 3159 - 3171
[5] Patent: EP2594550, 2013, A1. Location in patent: Paragraph 0037; 0038
9-Azabicyclo[3.3.1]nonan-3-one, 9-(phenylmethyl)- Preparation Products And Raw materials
Raw materials
Preparation Products
More
Less
9-Azabicyclo[3.3.1]nonan-3-one, 9-(phenylmethyl)- Suppliers
- Tel
- 021-50795510 4000665055
- Fax
- 021-50795055
- sales@accelachem.com
- Country
- China
- ProdList
- 11035
- Advantage
- 64
- Tel
- 0519-81291281 18015082300
- Fax
- 0519-81291281
- siduchem@hotmail.com
- Country
- China
- ProdList
- 274
- Advantage
- 62
- Tel
- 028-85114309 18982182443
- yangli@happysyn.com
- Country
- China
- ProdList
- 2152
- Advantage
- 55
- Tel
- 0514-015380367604 15380367604
- Fax
- 0514-83828236
- sales@ruibobiotech.com
- Country
- China
- ProdList
- 511
- Advantage
- 55
- Tel
- 021-20960837
- Fax
- 021-20960837
- market@aloespharm.com
- Country
- China
- ProdList
- 1302
- Advantage
- 55
- Tel
- 0512-56316828 4008675858
- Fax
- +86-512-56316826
- sales@amateksci.com
- Country
- China
- ProdList
- 9874
- Advantage
- 55
- Tel
- 21-33526724 18930996265
- Fax
- 37023730
- info@carlowchem.com
- Country
- China
- ProdList
- 1922
- Advantage
- 58
- Tel
- 028-84502008 13568869383
- Fax
- 028-66476329
- sales@hygeiapharm.com
- Country
- China
- ProdList
- 296
- Advantage
- 55
- Tel
- 400-164-7117 13681763483
- Fax
- +86-21-61629029
- product02@bidepharm.com
- Country
- China
- ProdList
- 39966
- Advantage
- 60
- Tel
- 微信 17321281695 18019252918
- Fax
- 17321281695
- sale@amkchem.com
- Country
- China
- ProdList
- 15136
- Advantage
- 55
- Tel
- 021-64340559 13651849907;
- Fax
- 021- 64345308
- xinyu_shi@jwypharmlab.com.cn
- Country
- China
- ProdList
- 12000
- Advantage
- 58
- Tel
- 0756-8699456 13427714006
- Fax
- +86-756-8699456
- sales@zhberi.com
- Country
- China
- ProdList
- 199
- Advantage
- 58
- Tel
- 021-20960837,QQ1332204249
- Fax
- 021-20960837
- sales@skychemical.com
- Country
- China
- ProdList
- 3341
- Advantage
- 55
- Tel
- 021-61312847; 18021002903
- Fax
- QQ:3008007432
- 3008007409@qq.com
- Country
- China
- ProdList
- 71826
- Advantage
- 60
- Tel
- 0519-85528066 13775048983
- Fax
- 0519-85528066
- sales@hopschem.com
- Country
- China
- ProdList
- 31553
- Advantage
- 55
- Tel
- 571-89925085
- Fax
- 0086-571-89925065
- sales@amadischem.com
- Country
- China
- ProdList
- 131957
- Advantage
- 58
- Tel
- 025-58859352 18068836627
- Fax
- (5)02557626880
- dt3@aikonchem.com
- Country
- China
- ProdList
- 15493
- Advantage
- 58
- Tel
- 13331045123
- Fax
- 86-10-80339217
- 2559355526@qq.com
- Country
- China
- ProdList
- 14193
- Advantage
- 58
- Tel
- 18825257575
- Fax
- 0755-35352037
- 3535203737@qq.com
- Country
- China
- ProdList
- 302
- Advantage
- 58
- Tel
- 0512-66565816 18651107528
- Fax
- 0512-66565816
- Country
- China
- ProdList
- 1040
- Advantage
- 58
- Tel
- 021-54338626 18017892860
- Fax
- 021-54338626
- sales@tubepharm.com
- Country
- China
- ProdList
- 2572
- Advantage
- 58
- Tel
- 4009004166/18616739031 18616739031
- 3007523370@qq.com
- Country
- China
- ProdList
- 52687
- Advantage
- 58
- Tel
- 021-18017654 18017654809
- Fax
- 2271705492
- sales@vigorchem.cn
- Country
- China
- ProdList
- 958
- Advantage
- 58
- Tel
- +86-400-002-6226 +86-13028896684;
- sales@rrkchem.com
- Country
- China
- ProdList
- 57422
- Advantage
- 58
- Tel
- +8618531123677
- faithe@yan-xi.com
- Country
- China
- ProdList
- 5853
- Advantage
- 58
- Tel
- +86-25-58393656
- Fax
- +86-25-58393656
- sales@hengbeichem.cn
- Country
- China
- ProdList
- 6854
- Advantage
- 58
- Tel
- +86-021-67759270 +8617717059219
- Fax
- 021-67759270
- sales@rlavie.com
- Country
- China
- ProdList
- 1030
- Advantage
- 58
- Tel
- +86-0551-65418671 +8618949823763
- Fax
- 0551-65418697
- sales@tnjchem.com
- Country
- China
- ProdList
- 34563
- Advantage
- 58
- Tel
- +86-27-50766799 +8618062016861
- contact@labnetwork.com
- Country
- China
- ProdList
- 19987
- Advantage
- 58
- Tel
- +8617013299288
- dj@sgtlifesciences.com
- Country
- China
- ProdList
- 12373
- Advantage
- 58
- Tel
- +8615990591583 15990591583
- Country
- CHINA
- ProdList
- 2029
- Advantage
- 58
- Tel
- 86-21-51086038
- Fax
- 86-21-51861608
- chemwill_asia@126.com
- Country
- CHINA
- ProdList
- 23912
- Advantage
- 58
- Tel
- 15990591583
- Fax
- qq: 1050376806 mailbox : sales@nbpharmabridge.com
- Country
- China
- ProdList
- 6108
- Advantage
- 58
- Tel
- +86-023-6139-8061 +86-86-13650506873
- sales@chemdad.com
- Country
- China
- ProdList
- 39927
- Advantage
- 58
- Tel
- 021-58461859 15821823057
- service@aiviche.com
- Country
- China
- ProdList
- 49312
- Advantage
- 58
- Tel
- +86-0371-86658258 +8613203830695
- Fax
- 0086-371-86658258
- factory@coreychem.com
- Country
- China
- ProdList
- 29798
- Advantage
- 58
- Tel
- +8613580539051
- joe@yuhengpharm.com
- Country
- CHINA
- ProdList
- 21142
- Advantage
- 58
- Tel
- 0371-0371-53736046 13393710386
- Fax
- QQ:2853979814
- 2853979814@qq.com
- Country
- China
- ProdList
- 9948
- Advantage
- 58
- Tel
- 15727060112
- yutianchun2007@126.com
- Country
- China
- ProdList
- 9814
- Advantage
- 58
- Tel
- 17806220283
- Fax
- QQ/wx：9291866
- info@samelabs.com
- Country
- China
- ProdList
- 569
- Advantage
- 58
- Tel
- 021-58432009 400-005-6266
- Fax
- 021-58436166
- marketing1@energy-chemical.com
- Country
- China
- ProdList
- 44894
- Advantage
- 58
- Tel
- 021-51816796-820 13611835272
- Fax
- 021-5161 3951
- sales2@sunwaypharm.com
- Country
- China
- ProdList
- 44119
- Advantage
- 58
- Tel
- 027-02702759223056 18162699093
- Fax
- 027-59223056
- 1208480011@qq.com
- Country
- China
- ProdList
- 9875
- Advantage
- 58
- Tel
- 027-027-59210159 15377098680
- Fax
- 027-59210159
- 1148280011@qq.com
- Country
- China
- ProdList
- 9835
- Advantage
- 58
- Tel
- 021-61109150
- Fax
- 021-61105897
- sales@tcisct.com
- Country
- China
- ProdList
- 29668
- Advantage
- 58
- Tel
- 400-8210725 4008210725
- malulu@leyan.com
- Country
- China
- ProdList
- 40000
- Advantage
- 58
- Tel
- 13000000000
- Fax
- jinoupharma@163
- jinoupharma@163.com
- Country
- China
- ProdList
- 11721
- Advantage
- 58
- Tel
- 15870833005
- 2232044025@qq.com
- Country
- China
- ProdList
- 8206
- Advantage
- 58
- Tel
- 400-6005915
- sales@picasso-e.com
- Country
- China
- ProdList
- 39653
- Advantage
- 58
- Tel
- 021-80159919 18662931292
- 3404730042@qq.com
- Country
- China
- ProdList
- 4898
- Advantage
- 58
More
Less
View Lastest Price from 9-Azabicyclo[3.3.1]nonan-3-one, 9-(phenylmethyl)- manufacturers
Hebei Yanxi Chemical Co., Ltd.
- Product
- 9-Azabicyclo[3.3.1]nonan-3-one, 9-(phenylmethyl)- 2291-58-9
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 20tons
- Release date
- 2023-10-08
Career Henan Chemical Co
- Product
- 9-Benzyl-3-oxo-9-azabicyc... 2291-58-9
- Price
- US $0.01/KG
- Min. Order
- 500g
- Purity
- 98%; 99%
- Supply Ability
- 500g；1kg； 10kg; 25kg
- Release date
- 2020-01-08