4-broMo-2-phenylthiazole
- Product Name
- 4-broMo-2-phenylthiazole
- CAS No.
- 141305-40-0
- Chemical Name
- 4-broMo-2-phenylthiazole
- Synonyms
- 4-broMo-2-phenylthiazole;Thiazole,4-bromo-2-phenyl-;4-bromo-2-phenyl-1,3-thiazole
- CBNumber
- CB02598497
- Molecular Formula
- C9H6BrNS
- Formula Weight
- 240.12
- MOL File
- 141305-40-0.mol
4-broMo-2-phenylthiazole Property
- Melting point:
- 65-67 °C
- Boiling point:
- 335.6±34.0 °C(Predicted)
- Density
- 1.563±0.06 g/cm3(Predicted)
- storage temp.
- Store at room temperature
- pka
- -0.34±0.10(Predicted)
- Appearance
- Off-white to light yellow Solid
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310Immediately call a POISON CENTER or doctor/physician.
N-Bromosuccinimide Price
- Product number
- Y7505
- Product name
- 4-Bromo-2-phenylthiazole
- Packaging
- 250mg
- Price
- $271
- Updated
- 2021/12/16
- Product number
- FB75289
- Product name
- 4-Bromo-2-phenylthiazole
- Packaging
- 250mg
- Price
- $500
- Updated
- 2021/12/16
- Product number
- Y7505
- Product name
- 4-Bromo-2-phenylthiazole
- Packaging
- 1g
- Price
- $597
- Updated
- 2021/12/16
- Product number
- FB75289
- Product name
- 4-Bromo-2-phenylthiazole
- Packaging
- 500mg
- Price
- $750
- Updated
- 2021/12/16
- Product number
- FB75289
- Product name
- 4-Bromo-2-phenylthiazole
- Packaging
- 1g
- Price
- $1000
- Updated
- 2021/12/16
4-broMo-2-phenylthiazole Chemical Properties,Usage,Production
Synthesis
4175-77-3
98-80-6
141305-40-0
Palladium(II) acetate (0.084 g, 0.38 mmol) was mixed with xantphos (0.220 g, 0.38 mmol) in 25 mL of tetrahydrofuran under nitrogen atmosphere. After stirring for 5 min, the resulting solution was transferred to a round-bottomed flask containing 2,4-dibromothiazole (3.64 g, 15 mmol), phenylboronic acid (1.96 g, 16 mmol) and potassium phosphate (9.55 g, 45 mmol). The reaction mixture was heated at 60 °C for 18 h, subsequently cooled to room temperature, filtered and washed with dichloromethane. The solvent was removed under reduced pressure to afford the crude product, which was purified by silica gel column chromatography using hexane:ethyl acetate as eluent to afford 4-bromo-2-phenylthiazole as a white solid (3 g, 84% yield).1H NMR (400 MHz, CDCl3) δ: 7.95 (dd, J = 3.4 Hz, 8.2 Hz, 2H), 7.47-7.46 (m 3H), 7.23 (s, 1H).LRMS (ESI) calculated value C9H6BrNS [M + H]+: 241.12, measured value: 241.00.
References
[1] Patent: WO2015/191630, 2015, A1. Location in patent: Paragraph 00287
[2] Journal of Organic Chemistry, 2010, vol. 75, # 5, p. 1733 - 1739
[3] Patent: JP2018/140974, 2018, A. Location in patent: Paragraph 0067; 0068
[4] Patent: EP2455371, 2012, A1. Location in patent: Page/Page column 22
[5] Patent: US2013/296271, 2013, A1. Location in patent: Paragraph 0175
4-broMo-2-phenylthiazole Preparation Products And Raw materials
Raw materials
Preparation Products
4-broMo-2-phenylthiazole Suppliers
- Tel
- 021-57171705 13817537615
- Fax
- QQ3095748324
- sales@run-biotech.com
- Country
- China
- ProdList
- 2337
- Advantage
- 58
- Tel
- 027-87465837 19945049750
- Fax
- 027-8777-2287
- sales@finetechnology-ind.com
- Country
- China
- ProdList
- 9637
- Advantage
- 58
- Tel
- 021-60345187 13671753212
- Fax
- 021-34702061
- lzz841106@aliyun.com
- Country
- China
- ProdList
- 10263
- Advantage
- 55
- Tel
- 13817873692
- Fax
- 021-31329586
- mkt@boynerspharm.com
- Country
- China
- ProdList
- 1707
- Advantage
- 55
- Tel
- 400-685-9117
- Fax
- 021-51816740
- market@bepharm.com
- Country
- China
- ProdList
- 15081
- Advantage
- 60
- Tel
- 571-89925085
- Fax
- 0086-571-89925065
- sales@amadischem.com
- Country
- China
- ProdList
- 131957
- Advantage
- 58
- Tel
- 2332782371
- Fax
- QQ: 2332782371
- adobechem@qq.com
- Country
- China
- ProdList
- 7980
- Advantage
- 58
- Tel
- 021-65232103 17602124823
- combiphos@vip.qq.com
- Country
- China
- ProdList
- 30000
- Advantage
- 58
- Tel
- +86-（0）57185586718; +8613336195806
- Fax
- +86-571-85864795
- sales@capot.com
- Country
- China
- ProdList
- 29735
- Advantage
- 60
- Tel
- 025-58859352 18068836627
- Fax
- (5)02557626880
- dt3@aikonchem.com
- Country
- China
- ProdList
- 15493
- Advantage
- 58
- Tel
- 021-61469567 13482353728
- Fax
- 021-61161605
- sales@fdc-chemical.com
- Country
- China
- ProdList
- 9717
- Advantage
- 58
- Tel
- 4009004166/18616739031 18616739031
- 3007523370@qq.com
- Country
- China
- ProdList
- 52687
- Advantage
- 58
- Tel
- 010-82387566 18001021521;
- Fax
- 82387566-801
- sales@mreda.com.cn
- Country
- China
- ProdList
- 10083
- Advantage
- 58
- Tel
- +86-27-8746-5837 +8619945049750
- Fax
- 86 27 87772287
- info@finetechnology-ind.com
- Country
- China
- ProdList
- 9629
- Advantage
- 58
- Tel
- +8613367258412
- Fax
- 18062427325
- ada@ipurechemical.com
- Country
- China
- ProdList
- 10237
- Advantage
- 58
- Tel
- 86 18062405514 18062405514
- ada@ipurechemical.com
- Country
- CHINA
- ProdList
- 3461
- Advantage
- 58
- Tel
- +86-0371-86658258 +8613203830695
- Fax
- 0371-86658258
- laboratory@coreychem.com
- Country
- China
- ProdList
- 30229
- Advantage
- 58
- Tel
- 021-50895067 18616507272
- Fax
- 021-50895067
- tensus@163.com
- Country
- China
- ProdList
- 8073
- Advantage
- 58
- Tel
- 15022315965; 18502259037
- sales_hxd@163.com
- Country
- China
- ProdList
- 509
- Advantage
- 58
- Tel
- 18717800556
- sales@finebiotech.com
- Country
- China
- ProdList
- 2182
- Advantage
- 58
- Tel
- 13000000000
- jnxinhongtai@126.com
- Country
- China
- ProdList
- 19528
- Advantage
- 58
- Tel
- 1701086315
- Fax
- 1701086315@qq.com
- dexuanpharma@126.com
- Country
- China
- ProdList
- 9475
- Advantage
- 58
- Tel
- 021-51816796-820 13611835272
- Fax
- 021-5161 3951
- sales2@sunwaypharm.com
- Country
- China
- ProdList
- 44119
- Advantage
- 58
- Tel
- 0574-87314919 057487319282
- info@nbinno.com
- Country
- China
- ProdList
- 7047
- Advantage
- 58
- Tel
- 400-8210725 4008210725
- malulu@leyan.com
- Country
- China
- ProdList
- 40000
- Advantage
- 58
- Tel
- 400-1647117 13681763483
- product02@bidepharm.com
- Country
- China
- ProdList
- 59936
- Advantage
- 58
- Tel
- 13901585132
- 2261760024@qq.com
- Country
- China
- ProdList
- 4900
- Advantage
- 58
- Tel
- 15652467323
- sales@inno-chem.com.cn
- Country
- China
- ProdList
- 8293
- Advantage
- 58
- Tel
- 1173954148q
- meishipharma@126.com
- Country
- China
- ProdList
- 20033
- Advantage
- 58
- Tel
- 400-0516-021 15300872630
- Fax
- 0516-86287676
- info@bcpharma.com
- Country
- China
- ProdList
- 2743
- Advantage
- 58
- Tel
- 010-50973130 17801761073
- Gsiyu@solarbio.com
- Country
- China
- ProdList
- 50464
- Advantage
- 58
- Tel
- 400-0628126 15697565236;
- sales-team@aobchem.com.cn
- Country
- China
- ProdList
- 50000
- Advantage
- 58
- Tel
- 19929974101 //1144079830; 19929974101
- Fax
- QQ:1144079830
- 1144079830@qq.com
- Country
- China
- ProdList
- 975
- Advantage
- 58
- Tel
- 021-50795510 4000665055
- syeu@accelachem.com
- Country
- China
- ProdList
- 11015
- Advantage
- 58
- Tel
- 15618928656
- 771909552@qq.com
- Country
- China
- ProdList
- 1265
- Advantage
- 58
- Tel
- 029-15596886083 15596886083
- 739383595@qq.com
- Country
- China
- ProdList
- 4073
- Advantage
- 58
- Tel
- 19355912709
- 690231469@qq.com
- Country
- China
- ProdList
- 7593
- Advantage
- 58
- Tel
- 199-2257-5710 13116104906
- 3353442734@qq.com
- Country
- China
- ProdList
- 335
- Advantage
- 58
- Tel
- 15620920485; 15620920485
- 823251269@qq.com
- Country
- China
- ProdList
- 1265
- Advantage
- 58
- Tel
- 51288865780
- sales@biosynth.com
- Country
- China
- ProdList
- 6051
- Advantage
- 58
- Tel
- +86-400-0516-021 +86-15190678838
- Fax
- 0516-86287676
- wuh@bcpharma.com
- Country
- China
- ProdList
- 2732
- Advantage
- 58
- Tel
- +undefined18143011203
- info@chemextension.com
- Country
- China
- ProdList
- 42056
- Advantage
- 58
- Tel
- +86-571-87711850
- market18@leapchem.com
- Country
- China
- ProdList
- 43339
- Advantage
- 58
- Tel
- +86-571-86626709 +86-18157142896
- cbc@coresyn.com
- Country
- China
- ProdList
- 9984
- Advantage
- 58
- Tel
- --
- Fax
- --
- info@zzsrm.com
- Country
- CHINA
- ProdList
- 6650
- Advantage
- 58
- Tel
- --
- Fax
- --
- 15810802415@139.com
- Country
- CHINA
- ProdList
- 6750
- Advantage
- 58
- Tel
- --
- Fax
- --
- shqcsw01@163.com
- Country
- CHINA
- ProdList
- 6821
- Advantage
- 58
- Tel
- --
- Fax
- --
- Country
- CHINA
- ProdList
- 6333
- Advantage
- 58
- Tel
- --
- Fax
- --
- shizezjp@163.com
- Country
- CHINA
- ProdList
- 6174
- Advantage
- 58
- Tel
- --
- Fax
- --
- jingkehuaxue@163.com
- Country
- CHINA
- ProdList
- 6141
- Advantage
- 58