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ChemicalBook > CAS DataBase List > (SP)-1-[(R)-tert-Butylphosphinoyl]-2-[(R)-1-(diphenylphosphino)ethyl]ferrocene

(SP)-1-[(R)-tert-Butylphosphinoyl]-2-[(R)-1-(diphenylphosphino)ethyl]ferrocene

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Product Name
(SP)-1-[(R)-tert-Butylphosphinoyl]-2-[(R)-1-(diphenylphosphino)ethyl]ferrocene
CAS No.
1221745-90-9
Chemical Name
(SP)-1-[(R)-tert-Butylphosphinoyl]-2-[(R)-1-(diphenylphosphino)ethyl]ferrocene
Synonyms
phosphinoyL;JoSPOphos SL-J681-1;]-2-[(R)-1-(diphenyL;(SP)-1-[(R)-tert-ButyL;(R)-1-[(R)-tert-Butylphosphinoyl]-2-[(R)-1-(diphenylphosphino)ethyl]ferrocene;(R,S(p), R(SPO)-(1-t-Butylphosphinoyl)-2-[1-(diphenylphosphino)ethyl]ferrocene;(SP)-1-[(R)-tert-Butylphosphinoyl]-2-[(R)-1-(diphenylphosphino)ethyl]ferrocene;(R,S(p),R(SPO)-1-tert-Butylphosphinoyl)-2-[1-(diphenylphosphino)ethyl]-ferrocene;(S)Fc-1-[(R)P-tert-Butylphosphinoyl]-2-[(R)-1- (diphenylphosphino)ethyl]ferrocene;(1R)-1-[(R)-(1,1-Dimethylethyl)phosphinyl]-2-[(1R)-1-(diphenylphosphino)ethyl]ferrocene (acc to CAS)
CBNumber
CB02637956
Molecular Formula
C28H31FeOP2+
Formula Weight
501.337662
MOL File
1221745-90-9.mol
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(SP)-1-[(R)-tert-Butylphosphinoyl]-2-[(R)-1-(diphenylphosphino)ethyl]ferrocene Property

storage temp. 
2-8°C, protect from light, stored under nitrogen
form 
Powder
color 
orange
Stability:
store cold
CAS DataBase Reference
1221745-90-9
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Safety

WGK Germany 
3
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
778745
Product name
(SP)-1-[(R)-tert-Butylphosphinoyl]-2-[(R)-1-(diphenylphosphino)ethyl]ferrocene
Purity
97%
Packaging
100mg
Price
$106
Updated
2021/12/16
Sigma-Aldrich
Product number
778745
Product name
(SP)-1-[(R)-tert-Butylphosphinoyl]-2-[(R)-1-(diphenylphosphino)ethyl]ferrocene
Purity
97%
Packaging
500mg
Price
$365
Updated
2021/12/16
Strem Chemicals
Product number
26-1270
Product name
(R,S(p), R(SPO)-(1-t-Butylphosphinoyl)-2-[1-(diphenylphosphino)ethyl]ferrocene, min. 97% JoSPOphos
Packaging
100mg
Price
$96
Updated
2024/03/01
Strem Chemicals
Product number
26-1270
Product name
(R,S(p), R(SPO)-(1-t-Butylphosphinoyl)-2-[1-(diphenylphosphino)ethyl]ferrocene, min. 97% JoSPOphos
Packaging
500mg
Price
$355
Updated
2024/03/01
Strem Chemicals
Product number
26-1270
Product name
(R,S(p), R(SPO)-(1-t-Butylphosphinoyl)-2-[1-(diphenylphosphino)ethyl]ferrocene, min. 97% JoSPOphos
Packaging
2g
Price
$1207
Updated
2024/03/01
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(SP)-1-[(R)-tert-Butylphosphinoyl]-2-[(R)-1-(diphenylphosphino)ethyl]ferrocene Chemical Properties,Usage,Production

Reaction

  1. Ligands used for the Rh-catalyzed asymmetric hydrogenation of functionalized alkenes.
  2. Ligands used for the Ru-catalyzed asymmetric hydrogenation of β-ketoesters.
  3. Ligands used for the Rh-catalyzed asymmetric hydrogenation of α-ketoesters.
  4. Ligand for the highly selective coupling of benzotriazoles with allenes.

Chemical Properties

Orange fine crystal with lumps

(SP)-1-[(R)-tert-Butylphosphinoyl]-2-[(R)-1-(diphenylphosphino)ethyl]ferrocene Preparation Products And Raw materials

Raw materials

Preparation Products

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(SP)-1-[(R)-tert-Butylphosphinoyl]-2-[(R)-1-(diphenylphosphino)ethyl]ferrocene Suppliers

China 15 United States 3 Global 18
Beijing HwrkChemical Technology Co., Ltd
Tel
18515581800 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
9400
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55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
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China
ProdList
44801
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61
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66028182 18626450290
Email
yftan@aikonchem.com
Country
China
ProdList
16679
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50
Shanghai Anyinuo Biomedical Technology Co., Ltd.
Tel
021-34625901 18018851262;
Email
420970979@qq.com
Country
China
ProdList
5894
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58
Shenzhen Polymeri Biochemical Technology Co., Ltd.
Tel
+86-400-002-6226 +86-13028896684;
Email
sales@rrkchem.com
Country
China
ProdList
57422
Advantage
58
career henan chemical co
Tel
+86-0371-86658258 +8613203830695
Fax
0086-371-86658258
Email
factory@coreychem.com
Country
China
ProdList
29798
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58
Beijing Jin Ming Biotechnology Co., Ltd.
Tel
010-60605840 15801484223;
Email
psaitong@jm-bio.com
Country
China
ProdList
29757
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58
Shanghai Haohong Pharmaceutical Co., Ltd.
Tel
400-8210725 4008210725
Email
malulu@leyan.com
Country
China
ProdList
40000
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58
Bide Pharmatech Ltd.
Tel
400-1647117 13681763483
Email
product02@bidepharm.com
Country
China
ProdList
59936
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58
Beijing Solarbio Science & Tecnology Co., Ltd.
Tel
010-50973130 17801761073
Email
Gsiyu@solarbio.com
Country
China
ProdList
50464
Advantage
58
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View Lastest Price from (SP)-1-[(R)-tert-Butylphosphinoyl]-2-[(R)-1-(diphenylphosphino)ethyl]ferrocene manufacturers

Career Henan Chemical Co
Product
(SP)-1-[(R)-tert-Butylphosphinoyl]-2-[(R)-1-(diphenylphosphino)ethyl]ferrocene 1221745-90-9
Price
US $8.86/KG
Min. Order
1KG
Purity
95.0%-99.0%
Supply Ability
1kg-100kg
Release date
2020-03-14

1221745-90-9, (SP)-1-[(R)-tert-Butylphosphinoyl]-2-[(R)-1-(diphenylphosphino)ethyl]ferroceneRelated Search:

(S)-1-{(R)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI-TERT.-BUTYLPHOSPHINE (S)-1-{(R)-2-[DI(2-FURYL)PHOSPHINO]FERROCENYL}ETHYLBIS(2-METHYLPHENYL)PHOSPHINE (R)-1-[(S)-2-[DI(2-FURYL)PHOSPHINO]FERROCENYL]ETHYLDI(3,5-XYLYL)PHOSPHINE (S)-1-{(R)-2-[DI(1-NAPHTHYL)PHOSPHINO]FERROCENYL}ETHYLDI(3,5-XYLYL)PHOSPHINE (S)-1-[(R)-2-(DI-TERT.-BUTYLPHOSPHINO)FERROCENYL]ETHYLDIPHENYLPHOSPHINE (S)-1-[(R)-2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENYL}ETHYLDI-TERT (S)-1-{(R)-2-[BIS[4-(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENYL}-ETHYLDI-TERT.- (S)-1-{(R)-2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENYL}-ETHYLBIS(2- (S)-1-{(R)-2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENYL}-ETHYLDI(3,5 (S)-1-{(R)-2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENYL}ETHYLDICYCLO

  • (SP)-1-[(R)-tert-Butylphosphinoyl]-2-[(R)-1-(diphenylphosphino)ethyl]ferrocene
  • (1R)-1-[(R)-(1,1-Dimethylethyl)phosphinyl]-2-[(1R)-1-(diphenylphosphino)ethyl]ferrocene (acc to CAS)
  • JoSPOphos SL-J681-1
  • (Z)-tert-butyl-[2-[(1R)-1-diphenylphosphanylethyl]cyclopenta-2,4-dien-1-ylidene]-oxidophosphanium:cyclopenta-1,3-diene:iron(2+)
  • (R,S(p),R(SPO)-1-tert-Butylphosphinoyl)-2-[1-(diphenylphosphino)ethyl]-ferrocene
  • (SP)-1-[(R)-tert-ButyL
  • ]-2-[(R)-1-(diphenyL
  • phosphinoyL
  • (S)Fc-1-[(R)P-tert-Butylphosphinoyl]-2-[(R)-1- (diphenylphosphino)ethyl]ferrocene
  • (R)-1-[(R)-tert-Butylphosphinoyl]-2-[(R)-1-(diphenylphosphino)ethyl]ferrocene
  • (R,S(p), R(SPO)-(1-t-Butylphosphinoyl)-2-[1-(diphenylphosphino)ethyl]ferrocene
  • 1221745-90-9