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1,2,4,5-Tetrakis(4-carboxyphenyl)benzene

Product Name
1,2,4,5-Tetrakis(4-carboxyphenyl)benzene
CAS No.
1078153-58-8
Chemical Name
1,2,4,5-Tetrakis(4-carboxyphenyl)benzene
Synonyms
DK7571;DK7240;H4TCPB;1,2,4,5-Tetrakis(4-carboxyphenyl);1,2,4,5-Tetrakis(4-carboxyphenyl)benzene;4,4',4'',4'''-benzene-1,2,4,5-tetrayl-tetrabenzoic acid;4',5'-Bis(4-carboxyphenyl)-[1,1':2',1''-terphenyl]-4,4''-dicarboxylic acid;1,2,4,5-Tetrakis(4-carboxyphenyl)benzene contains up to 6 wt. % water, >=98%;[1,1':2',1''-Terphenyl]-4,4''-dicarboxylic acid, 4',5'-bis(4-carboxyphenyl)-;1,2,4,5-Tetrakis(4-carboxyphenyl)benzene (This product is unavailable in the U.S.)
CBNumber
CB02662642
Molecular Formula
C34H22O8
Formula Weight
558.53
MOL File
1078153-58-8.mol
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1,2,4,5-Tetrakis(4-carboxyphenyl)benzene Property

Boiling point:
792.8±60.0 °C(Predicted)
Density 
1.393±0.06 g/cm3(Predicted)
Flash point:
85 °C
pka
3.24±0.10(Predicted)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
SIK2110-10
Product name
1,2,4,5-Tetrakis(4-carboxyphenyl)benzene-H4TCPB
Purity
≥97%
Packaging
250MG
Price
$245
Updated
2024/03/01
Sigma-Aldrich
Product number
SIK2110-10
Product name
1,2,4,5-Tetrakis(4-carboxyphenyl)benzene-H4TCPB
Purity
≥97%
Packaging
1G
Price
$698
Updated
2024/03/01
Sigma-Aldrich
Product number
715298
Product name
1,2,4,5-Tetrakis(4-carboxyphenyl)benzene
Purity
contains up to 6 wt. % water, ≥98%
Packaging
1G
Price
$246
Updated
2023/06/20
American Custom Chemicals Corporation
Product number
CHM0114927
Product name
1,2,4,5-TETRAKIS(4-CARBOXYPHENYL)BENZENE
Purity
95.00%
Packaging
1G
Price
$767.07
Updated
2021/12/16
Ambeed
Product number
A1154801
Product name
1,2,4,5-Tetrakis(4-carboxyphenyl)benzene
Purity
98%
Packaging
5g
Price
$327
Updated
2021/12/16
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1,2,4,5-Tetrakis(4-carboxyphenyl)benzene Chemical Properties,Usage,Production

Uses

Selected Applications of MOFs in Sustainable Energy Technologies

General Description

This product has been enhanced for energy efficiency.

Synthesis


a) 100 ml of p-tolylmagnesium bromide (1M in THF, 100 mmol) was added under nitrogen to a flask containing 5g of (9.07 mmol). The mixture was stirred at nitrogen to a flask containing 5g of (9.07 mmol). The mixture was stirred at room temperature for 15 hours (gray suspension). The reaction was poured on ice then 50 ml of 6M HCl was added. The mixture was extracted with THF (3X 200ml). The organics were combined and the solvent was removed via rotary evaporation. The solid was then washed with hexanes and cold acetone. Isolated yield: 2.75g, 70% based on hexabromobenzene. yield: 2.75g, 70% 1H NMR (CDCl3): δ 2.32 (s, 12H), 7.04 (d, 8H), 7.12 (d, 8H), 7.45 (s, 2H). 13C NMR (CDCl3): δ 128.9, 130.0, 133.3, 136.4, 138.4, 139.5 ppm.(b) An amount of 2g from (a) was placed in a 100 ml teflon lined vessel. An amount of 24 ml of water and 6 ml of HNO3 were then added. The vessel was sealed and heated at 180 °C for 24 hrs. The resulting solid was collected by filtration and washed with THF/CHCl3 (7:3). Isolated yield: 1.85g, 75%. yield: 1.85g, 75%

1,2,4,5-Tetrakis(4-carboxyphenyl)benzene Preparation Products And Raw materials

Raw materials

Preparation Products

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1,2,4,5-Tetrakis(4-carboxyphenyl)benzene Suppliers

China 63 Japan 1 United States 5 Global 69
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28398
Advantage
80
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View Lastest Price from 1,2,4,5-Tetrakis(4-carboxyphenyl)benzene manufacturers

Career Henan Chemical Co
Product
1,2,4,5-Tetrakis(4-carboxyphenyl)benzene 1078153-58-8
Price
US $8.66/KG
Min. Order
1KG
Purity
95.0%-99.0%
Supply Ability
1kg-100kg
Release date
2020-03-11
Career Henan Chemical Co
Product
1,2,4,5-Tetrakis(4-carboxyphenyl)benzene 1078153-58-8
Price
US $2.00/KG
Min. Order
1g
Purity
98%min
Supply Ability
ask
Release date
2020-01-08

1078153-58-8, 1,2,4,5-Tetrakis(4-carboxyphenyl)benzeneRelated Search:


  • H4TCPB
  • 1,2,4,5-Tetrakis(4-carboxyphenyl)benzene contains up to 6 wt. % water, >=98%
  • 1,2,4,5-Tetrakis(4-carboxyphenyl)benzene
  • 4',5'-Bis(4-carboxyphenyl)-[1,1':2',1''-terphenyl]-4,4''-dicarboxylic acid
  • 4,4',4'',4'''-benzene-1,2,4,5-tetrayl-tetrabenzoic acid
  • [1,1':2',1''-Terphenyl]-4,4''-dicarboxylic acid, 4',5'-bis(4-carboxyphenyl)-
  • 1,2,4,5-Tetrakis(4-carboxyphenyl)benzene (This product is unavailable in the U.S.)
  • DK7240
  • DK7571
  • 1,2,4,5-Tetrakis(4-carboxyphenyl)
  • 1078153-58-8
  • C34H22O8