ChemicalBook > CAS DataBase List > 2,4-diMethoxyquinoline

2,4-diMethoxyquinoline

Product Name
2,4-diMethoxyquinoline
CAS No.
40335-00-0
Chemical Name
2,4-diMethoxyquinoline
Synonyms
Yu Borylation Ligand;2,4-diMethoxyquinoline;Quinoline, 2,4-dimethoxy-
CBNumber
CB02703594
Molecular Formula
C11H11NO2
Formula Weight
189.21
MOL File
40335-00-0.mol
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2,4-diMethoxyquinoline Property

Melting point:
82 °C
Boiling point:
272.9±20.0 °C(Predicted)
Density 
1.148±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
form 
powder
pka
4.56±0.50(Predicted)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
ALD00506
Product name
Yu Borylation Ligand
Purity
≥95%
Packaging
250mg
Price
$33.1
Updated
2023/06/20
Ambeed
Product number
A516767
Product name
2,4-Dimethoxyquinoline
Purity
95%
Packaging
1g
Price
$60
Updated
2021/12/16
Crysdot
Product number
CD11128632
Product name
2,4-Dimethoxyquinoline
Purity
95+%
Packaging
5g
Price
$232
Updated
2021/12/16
Ambeed
Product number
A516767
Product name
2,4-Dimethoxyquinoline
Purity
95%
Packaging
5g
Price
$264
Updated
2021/12/16
Chemenu
Product number
CM223344
Product name
2,4-Dimethoxyquinoline
Purity
95%
Packaging
1g
Price
$281
Updated
2021/12/16
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2,4-diMethoxyquinoline Chemical Properties,Usage,Production

Uses

The Yu Borylation Ligand in tandem with bis(pinacolato)diboron (Aldrich 473294) under palladium catalysis can promote direct borylation of C(sp3)-H bonds. Yu and coworkers have displayed this on both alanine-derived amides and cyclopropanes with directing group assistance from the Yu-Wasa Auxiliary (Aldrich 791806).

General Description

Yu Borylation Ligand, also referred to as 2,4-dimethoxyquinoline, has been developed by Professor Jin-Quan Yu and coworkers. 2,4-dimethoxyquinoline can be prepared by reacting 2,4-dichloroquinoline with sodium methoxide.

reaction suitability

reagent type: catalyst
reagent type: ligand
reaction type: C-H Activation

2,4-diMethoxyquinoline Preparation Products And Raw materials

Raw materials

Preparation Products

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2,4-diMethoxyquinoline Suppliers

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40335-00-0, 2,4-diMethoxyquinolineRelated Search:


  • 2,4-diMethoxyquinoline
  • Yu Borylation Ligand
  • Quinoline, 2,4-dimethoxy-
  • 40335-00-0