t-Butyl (E)-4-Iodo-2-methyl-2-butenoate
- Product Name
- t-Butyl (E)-4-Iodo-2-methyl-2-butenoate
- CAS No.
- 53689-87-5
- Chemical Name
- t-Butyl (E)-4-Iodo-2-methyl-2-butenoate
- Synonyms
- t-butyl γ-iodotiglate;t-Butyl (E)-4-Iodo-2-methyl-2-butenoate;2-Butenoic acid, 4-iodo-2-methyl-, 1,1-dimethylethyl ester
- CBNumber
- CB03072691
- Molecular Formula
- C9H15IO2
- Formula Weight
- 282.12
- MOL File
- 53689-87-5.mol
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t-Butyl (E)-4-Iodo-2-methyl-2-butenoate Property
- Boiling point:
- 80 °C/0.005 mmHg
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N-Bromosuccinimide Price
American Custom Chemicals Corporation
- Product number
- HCH0141981
- Product name
- T-BUTYL (E)-4-IODO-2-METHYL-2-BUTENOATE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $498.07
- Updated
- 2021/12/16
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t-Butyl (E)-4-Iodo-2-methyl-2-butenoate Chemical Properties,Usage,Production
Reactivity Profile
t-Butyl (E)-4-Iodo-2-methyl-2-butenoate could be used in egioselective annulations; methyl vinyl ketone equivalent.
Synthesis
Treatment of Chloroacetaldehyde with the phosphorane shown in eq 1 followed by halogen exchange with Sodium Iodide/acetone affords t-Butyl (E)-4-Iodo-2-methyl-2-butenoate in 76% overall yield.
References
1. (a) Gawley, R. E. S 1976, 777; (b) Hill, K. H. Ph.D. Thesis, University of Texas, Austin, TX, 1972.
2. (a) Stotter, P. L.; Hill, K. A. TL 1975, 16, 1679. (b) Stotter, P. L.; Hill, K. A. JACS 1974, 96, 6524.
3. Weinstock, J. JOC 1961, 26, 3511.
t-Butyl (E)-4-Iodo-2-methyl-2-butenoate Preparation Products And Raw materials
Raw materials
Preparation Products
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t-Butyl (E)-4-Iodo-2-methyl-2-butenoate Suppliers
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- Country
- China
- ProdList
- 6800
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