1-BROMO-4,5-DIFLUORO-2-METHYL-BENZENE

Product Name: 1-BROMO-4,5-DIFLUORO-2-METHYL-BENZENE
CAS No.: 875664-38-3
Chemical Name: 1-BROMO-4,5-DIFLUORO-2-METHYL-BENZENE
Synonyms: 2-BROMO-4,5-DIFLUOROTOLUENE;2-Bromo-4,5-difluorotoluene >4,5-DIFLUORO-2-METHYLBROMOBENZENE;1-BROMO-4,5-DIFLUORO-2-METHYL-BENZENE;1-brommo-4,5-difluoro-2-methyl-benzene;Benzene, 1-bromo-4,5-difluoro-2-methyl-
CBNumber: CB0309873
Molecular Formula: C7H5BrF2
Formula Weight: 207.02
MOL File: 875664-38-3.mol

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1-BROMO-4,5-DIFLUORO-2-METHYL-BENZENE Property

Boiling point:: 183.5±35.0 °C(Predicted)
Density: 1.588±0.06 g/cm3(Predicted)
refractive index: 1.508
storage temp.: Sealed in dry,Room Temperature
form: clear liquid
color: Colorless to Almost colorless
InChIKey: FKEURBCLFHOBDM-UHFFFAOYSA-N
CAS DataBase Reference: 875664-38-3(CAS DataBase Reference)

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Safety

Risk Statements: 20/21/22-36/37/38
Safety Statements: 26-36/37/39
HS Code: 2904990090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H227Combustible liquid

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical

Product number: B4129
Product name: 2-Bromo-4,5-difluorotoluene
Purity: >98.0%(GC)
Packaging: 1g
Price: $34
Updated: 2025/07/31

TCI Chemical

Product number: B4129
Product name: 2-Bromo-4,5-difluorotoluene
Purity: >98.0%(GC)
Packaging: 5g
Price: $107
Updated: 2025/07/31

TRC

Product number: B700515
Product name: 2-Bromo-4,5-difluorotoluene
Packaging: 10mg
Price: $45
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB67410
Product name: 2-Bromo-4,5-difluorotoluene
Packaging: 5G
Price: $100
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB67410
Product name: 2-Bromo-4,5-difluorotoluene
Packaging: 25g
Price: $375
Updated: 2021/12/16

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1-BROMO-4,5-DIFLUORO-2-METHYL-BENZENE Chemical Properties,Usage,Production

Synthesis

2927-34-6

875664-38-3

Step 1: Synthesis of 1-bromo-4,5-difluoro-2-methylbenzene (16). Bromine (Br2) (40 g, 250 mmol) was added slowly and dropwise to a reaction flask containing 3,4-difluorotoluene (15) (27 g, 210 mmol) and iron powder (600 mg, 10 mmol) under ice bath conditions. The reaction mixture was slowly warmed to room temperature with stirring and the reaction was continued for 12 hours. Upon completion of the reaction, the reaction was quenched by the addition of water and the mixture was extracted with ether. The combined organic layers were washed sequentially with sodium thiosulfate solution and saturated brine and dried over anhydrous sodium sulfate (Na2SO4). The ether was removed by concentration under reduced pressure to give the target product 1-bromo-4,5-difluoro-2-methylbenzene (16) (36 g, 83% yield). 1H NMR (400 MHz, DMSO-d6): δ 7.78 (t, 1H), 7.52 (t, 1H), 2.29 (s, 3H).

References

[1] Patent: WO2017/4608, 2017, A1. Location in patent: Paragraph 0133
[2] Patent: US2011/112158, 2011, A1. Location in patent: Page/Page column 9

1-BROMO-4,5-DIFLUORO-2-METHYL-BENZENE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-BROMO-4,5-DIFLUORO-2-METHYL-BENZENE Suppliers

Americas 1 CHINA 87 Europe 1 Germany 6 India 4 Japan 1 The Netherlands 2 United Kingdom 13 United States 17 Global 132

Carbosynth

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Fluorochem Ltd.

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View Lastest Price from 1-BROMO-4,5-DIFLUORO-2-METHYL-BENZENE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: 1-BROMO-4,5-DIFLUORO-2-METHYL-BENZENE 875664-38-3
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

Zhuozhou Wenxi import and Export Co., Ltd

Product: 2-Bromo-4,5-difluorotoluene 875664-38-3
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Career Henan Chemical Co

Product: 1-BROMO-4,5-DIFLUORO-2-METHYL-BENZENE 875664-38-3
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2020-01-10

875664-38-3, 1-BROMO-4,5-DIFLUORO-2-METHYL-BENZENERelated Search:

2-BROMO-3,4,5,6-TETRAFLUOROBENZOTRIFLUORIDE 2-BROMO-4,5-DIFLUOROBENZOIC ACID 2,5-Difluorobenzyl bromide 3,4-Difluorobenzyl bromide 1-BROMO-2,4-DIFLUORO-3-METHYLBENZENE 1-BROMO-4,5-DIFLUORO-2-METHYL-BENZENE 2-Bromo-3,4,5,6-tetrafluorotoluene 2-BROMO-3,4,5,6-TETRAFLUOROBENZOYL CHLORIDE 2-BROMO-3,4,5,6-TETRAFLUOROBENZYLALCOHOL 2-Bromo-3,4,5,6-tetrafluorobenzoic acid 2,3-Difluorobenzyl bromide 2,4-Difluorobenzyl bromide 2,6-Difluorobenzyl bromide 2-BROMO-4,5-DIFLUOROBENZOYL CHLORIDE 6-Bromo-2,3,4-Trifluorobenzoic Acid 2-Bromo-4,5-difluorobenzonitrile 2-Bromo-4,5-difluorophenylacetic acid (2S)-2-(2-BROMO-4,5-DIFLUOROPHENYL)PYRROLIDINE

1-brommo-4,5-difluoro-2-methyl-benzene

4,5-DIFLUORO-2-METHYLBROMOBENZENE

2-BROMO-4,5-DIFLUOROTOLUENE

1-BROMO-4,5-DIFLUORO-2-METHYL-BENZENE

2-Bromo-4,5-difluorotoluene &gt

Benzene, 1-bromo-4,5-difluoro-2-methyl-

875664-38-3

Aromatic Halides (substituted)