m-Tolidine

Product Name: m-Tolidine
CAS No.: 84-67-3
Chemical Name: m-Tolidine
Synonyms: NZ066;APB-144;M-TOLIDINE;2,2'-Tolidine;m-Tolidine;2,2’-dimethylbenzidine;2,2'-dimethyl benzidine;2,2'-DIMETHYL-4,4'-DIAMINOBIPHENYL;4,4'-Diamino-2,2'-dimethylbiphenyl;2,2'-Dimethyl-4,4'-biphenyldiamine
CBNumber: CB0320487
Molecular Formula: C14H16N2
Formula Weight: 212.29
MOL File: 84-67-3.mol

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m-Tolidine Property

Melting point:: 105-106℃
Boiling point:: 344.4±37.0 °C(Predicted)
Density: 1.106
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: Chloroform (Slightly), Methanol (Slightly)
form: Solid
pka: 4.89±0.10(Predicted)
color: White to Off-White
Stability:: Incompatible with oxidising agents
InChI: InChI=1S/C14H16N2/c1-9-7-11(15)3-5-13(9)14-6-4-12(16)8-10(14)2/h3-8H,15-16H2,1-2H3
InChIKey: QYIMZXITLDTULQ-UHFFFAOYSA-N
SMILES: C1(C2=CC=C(N)C=C2C)=CC=C(N)C=C1C
CAS DataBase Reference: 84-67-3

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Safety

Safety Statements: 24/25
HS Code: 29215900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical

Product number: T3098
Product name: m-Tolidine
Purity: >98.0%(GC)(T)
Packaging: 25g
Price: $109
Updated: 2024/03/01

TRC

Product number: D460113
Product name: 2,2''-Dimethyl-[1,1''-biphenyl]-4,4''-diamine
Packaging: 250mg
Price: $50
Updated: 2021/12/16

AK Scientific

Product number: J96241
Product name: m-Tolidine
Packaging: 10g
Price: $16
Updated: 2021/12/16

AK Scientific

Product number: J96241
Product name: m-Tolidine
Packaging: 100g
Price: $75
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0079700
Product name: 2,2'-DIMETHYL-[1,1'-BIPHENYL]-4,4'-DIAMINE
Purity: 95.00%
Packaging: 5G
Price: $909.56
Updated: 2021/12/16

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m-Tolidine Chemical Properties,Usage,Production

Chemical Properties

m-Tolidine is pink particles and can form prisms when exposed to water. It is soluble in cold water, alcohol, and ether. In the presence of iron(III) chloride, m-Tolidine does not produce any color. It is tetrazotized with nitrite and acid and couples to form dyes.

Uses

2,2''-Dimethyl-[1,1''-biphenyl]-4,4''-diamine (cas# 84-67-3) is a useful reagent for manufacturing cured films and semiconductor devices.

Uses

M-TOLIDINE is used for preparation polyimide and epoxy resin material.

Preparation

M-Tolidine is made by the reduction of m-nitrotoluene with zinc dust and sodium hydroxide solution. The subsequent rearrangement is carried out with hydrochloric acid or sulfuric acid and gives rise to m-tolidine dihydrochloride or m-tolidine sulfate, which are isolated as salts. The free base is diffificult to isolate and is therefore not a commercial product.

Definition

M-Tolidine gives no color in the presence of iron(III) chloride. It is tetrazotized with nitrite and acid and couples to form dyes. M-Tolidine was used in the past for the production of azo dyes.

Chemical Reactivity

M-Tolidine gives no color in the presence of iron(III) chloride. It is tetrazotized with nitrite and acid and couples to form dyes.

m-Tolidine Preparation Products And Raw materials

Raw materials

Preparation Products

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m-Tolidine Suppliers

China 203 India 3 Japan 1 South Korea 1 United States 6 Global 214

TOKYO CHEMICAL INDUSTRY CO., LTD.

Tel: 03-36680489
Fax: 03-3668-0520
Email: Sales-JP@TCIchemicals.com
Country: Japan
ProdList: 28387
Advantage: 80

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View Lastest Price from m-Tolidine manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: 2,2'-Dimethyl-[1,1'-biphenyl] -4,4'-Diamine 84-67-3
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-02-24

Shanghai Daken Advanced Materials Co.,Ltd

Product: 2,2'-Dimethyl-[1,1'-biphenyl]-4,4'-Diamine(M-Tolidine) 84-67-3
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99.00%
Supply Ability: 1500KG/month
Release date: 2021-11-01

Hebei Weibang Biotechnology Co., Ltd

Product: 2,2'-Dimethyl-[1,1'-biphenyl] -4,4'-Diamine 84-67-3
Price: US $30.00-10.00/KG
Min. Order: 50KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-10-24

84-67-3, m-TolidineRelated Search:

2,2'-Bis(trifluoromethyl)benzidine Acid Red 111 o-TOLIDINE DIHYDROCHLORIDE REAGENT (ACS),o-Tolidine2HCl,O-TOLIDINE HYDROCHLORIDE R. G.,O-TOLIDINE HYDROCHLORIDE,O-TOLIDINE DI HCL,O-TOLIDINE DIHYDROCHLORIDE o-Tolidine hydroch DIACETOACET-O-TOLIDINE O-TOLIDINE SULFONE 99% MIXTURE OF &,O-tolidine sulfone, mixture of isomers,O-TOLIDINE SULFONE O-Tolidine o-Tolidine diisocyanate (S)-2,2'-DIMETHYL-1,1'-BINAPHTHYL 2,2'-DIMETHYLBIPHENYL (R)-2,2'-DIMETHYL-1,1'-BINAPHTHYL 4,4'-DIMETHYLBIPHENYL Benzidine 4,4'-DIAMINOBIPHENYL-2,2'-DICARBOXYLIC ACID o-Tolidine-6,6''-disulfonic acid O-TOLIDINE SULFONE O-TOLIDINE SOLUTION [FOR CHLORINE-TEST] o-Tolidine dihydrochoride

2,2'-dimethyl[1,1'-biphenyl]-4,4'-diamine

4-(4-amino-2-methylphenyl)-3-methylbenzenamine

4,4'-Diamino-2,2'-dimethylbiphenyl

2,2'-DIMETHYL-4,4'-DIAMINOBIPHENYL

APB-144

M-TOLIDINE

1’-Biphenyl]-4,4’-diamine,2,2’-dimethyl-[1

2,2’-dimethylbenzidine

2,2'-diMethyl-4,4'-diaMinobiphenyl(M-TB)

2,2'-diMethyl-4,4'-diaMinobiphenyl (M-tolidine

<i>m</i>-Tolidine

2,2'-Dimethyl-[1,1'-biphenyl]-4,4'-Diamine(M-Tolidine)

[1,1'-Biphenyl]-4,4'-diamine,2,2'-dimethyl-

2,2'-dimethyl-[1,1'-Biphenyl]-4,4'-diamine 2,2'-dimethyl benzidine

2,2'-Dimethyl-4,4'-biphenyldiamine

2,2'-Dimethyl-4,4'-diamino-1,1'-biphenyl

2,2'-Tolidine

[4-(4-amino-2-methyl-phenyl)-3-methyl-phenyl]amine

4-(4-amino-2-methylphenyl)-3-methylaniline

4-(4-azanyl-2-methyl-phenyl)-3-methyl-aniline

NZ066

2,2'-DIMETHYL-4,4'-DIAMINOBIPHENYL(M-TOLIDINE/M-TB)

2,2'-Dimethyl-[1,1'-biphenyl] -4,4'-Diamine (M-Tolidine) CAS

2,2'-Dimethyl-[1,1'-biphenyl] -4,4'-Diamine (M-Tolidine)

2,2'-Dimethyl-[1,1'-biphenyl]-4,4'-diamine

2,2'-dimethyl benzidine

4,4'-Diamino-2,2'-dimethylbiphenyl

2,2'-diMethyl-4,4'-diaMinobiphenyl

2,2'-dimethy- 4,4'-diaminobiphenyl

84-67-3

C6H3NH2CH32

Intermediates of Dyes and Pigments

fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis

fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials

84-67-3