ChemicalBook > CAS DataBase List > (2R,4R)-5,5-DIMETHYL-2-HYDROXY-4-PHENYL-1,3,2-DIOXAPHOSPHORINAN 2-OXIDE

(2R,4R)-5,5-DIMETHYL-2-HYDROXY-4-PHENYL-1,3,2-DIOXAPHOSPHORINAN 2-OXIDE

Product Name
(2R,4R)-5,5-DIMETHYL-2-HYDROXY-4-PHENYL-1,3,2-DIOXAPHOSPHORINAN 2-OXIDE
CAS No.
98674-80-7
Chemical Name
(2R,4R)-5,5-DIMETHYL-2-HYDROXY-4-PHENYL-1,3,2-DIOXAPHOSPHORINAN 2-OXIDE
Synonyms
(4R)-2-Hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphinane 2-oxide;(2R,4R)-5,5-dimethyl-4-phenyl-N-tosyl-1,2,3-oxathiazolidine-2-oxide;(4r)-2-hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphorinan 2-oxide;(2R,4R)-2-Hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphorinan 2-oxide;(2R,4R)-5,5-DIMETHYL-2-HYDROXY-4-PHENYL-1,3,2-DIOXAPHOSPHORINAN 2-OXIDE;(R)-(-)-2-HYDROXY-5,5-DIMETHYL-4-PHENYL-1,3,2-DIOXAPHOSPHORINANE 2-OXIDE;(4R)-2-Hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphorinan 2-oxide 98%;(R)-(-)-5,5-DIMETHYL-2-HYDROXY 4-PHENYL-1,3,2-DIOXAPHOS-PHORINANE-2-OXIDE;1,3,2-Dioxaphosphorinane, 2-hydroxy-5,5-dimethyl-4-phenyl-, 2-oxide, (4R)-;(R)-(-)-2-HYDROXY-5,5-DIMETHYL-4-PHENYL- 1,3,2-DIOXAPHOSPHORINANE 2-OXID 98%
CBNumber
CB0320573
Molecular Formula
C11H15O4P
Formula Weight
242.21
MOL File
98674-80-7.mol
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(2R,4R)-5,5-DIMETHYL-2-HYDROXY-4-PHENYL-1,3,2-DIOXAPHOSPHORINAN 2-OXIDE Property

Melting point:
224-227 °C (lit.)
Boiling point:
344.4±45.0 °C(Predicted)
Density 
1.27±0.1 g/cm3(Predicted)
storage temp. 
2-8°C
pka
1.28±0.60(Predicted)
optical activity
[α]20/D 62°, c = 0.5 in methanol
BRN 
4294714
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
10-21
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
448427
Product name
(4R)-2-Hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphorinan 2-oxide
Purity
98%
Packaging
1g
Price
$108.6
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
CCH0005123
Product name
(4R)-2-Hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphorinan 2-oxide
Purity
98.00%
Packaging
1G
Price
$742.2
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CCH0005123
Product name
(4R)-2-Hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphorinan 2-oxide
Purity
98.00%
Packaging
5G
Price
$1284.91
Updated
2021/12/16
AHH
Product number
MT-10735
Product name
(2R,4R)-5,5-Dimethyl-2-hydroxy-4-phenyl-1,3,2dioxaphosphorinan2-oxide
Purity
98%
Packaging
10g
Price
$412
Updated
2021/12/16
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(2R,4R)-5,5-DIMETHYL-2-HYDROXY-4-PHENYL-1,3,2-DIOXAPHOSPHORINAN 2-OXIDE Chemical Properties,Usage,Production

Uses

(4R)-2-Hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphorinan 2-oxide can be used:

  • As a reactant in the phosphoalkoxylation of aromatic enones.
  • As a chiral resolving agent in the resolution of amino acids, amines, and amino alcohols.

(2R,4R)-5,5-DIMETHYL-2-HYDROXY-4-PHENYL-1,3,2-DIOXAPHOSPHORINAN 2-OXIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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(2R,4R)-5,5-DIMETHYL-2-HYDROXY-4-PHENYL-1,3,2-DIOXAPHOSPHORINAN 2-OXIDE Suppliers

98674-80-7, (2R,4R)-5,5-DIMETHYL-2-HYDROXY-4-PHENYL-1,3,2-DIOXAPHOSPHORINAN 2-OXIDERelated Search:


  • (R)-(-)-2-HYDROXY-5,5-DIMETHYL-4-PHENYL-1,3,2-DIOXAPHOSPHORINANE 2-OXIDE
  • (R)-(-)-5,5-DIMETHYL-2-HYDROXY 4-PHENYL-1,3,2-DIOXAPHOS-PHORINANE-2-OXIDE
  • (2R,4R)-5,5-DIMETHYL-2-HYDROXY-4-PHENYL-1,3,2-DIOXAPHOSPHORINAN 2-OXIDE
  • (2R,4R)-2-Hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphorinan 2-oxide
  • (R)-(-)-2-HYDROXY-5,5-DIMETHYL-4-PHENYL- 1,3,2-DIOXAPHOSPHORINANE 2-OXID 98%
  • (4r)-2-hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphorinan 2-oxide
  • (R)-(-)-2-Hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphorinane 2-oxide, (2R,4R)-5,5-Dimethyl-2-hydroxy-4-phenyl-1,3,2-dioxaphosphorinan 2-oxide
  • (4R)-2-Hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphorinan 2-oxide 98%
  • (2R,4R)-5,5-dimethyl-4-phenyl-N-tosyl-1,2,3-oxathiazolidine-2-oxide
  • (4R)-2-Hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphinane 2-oxide
  • 1,3,2-Dioxaphosphorinane, 2-hydroxy-5,5-dimethyl-4-phenyl-, 2-oxide, (4R)-
  • 98674-80-7
  • 12782-27-1
  • 4198-33-6
  • Chiral Resolution Reagents
  • Chiral
  • Asymmetric Synthesis
  • Chiral Resolving Reagents
  • chiral